Ammoxidation reactor control

Patent metadata

Field	Value
Publication number	US-11078156-B2
Application number	US-201716301882-A
Country	US
Kind code	B2
Filing date	May 4, 2017
Priority date	May 24, 2016
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A process is provided for control of an ammoxidation reactor. More specifically, the process includes controlling an amount of oxygen added to the reactor, steam temperature and linear velocity to minimize reactor temperature deviations.

First claim

What is claimed is:

1. An ammoxidation process comprising:
introducing a flow of reactant stream into an ammoxidation reactor, wherein the reactant stream includes ammonia, an oxygen containing gas, a hydrocarbon selected from the group consisting of propane, propylene, isobutene, and isobutylene, or mixtures thereof;
providing superheated steam to superheat coils disposed in the ammoxidation reactor to provide a reactor operating temperature of about 350° C. to about 480° C., wherein reactor temperature deviations are maintained at about 10° C. or less during changes in a heat transfer area of the superheat coils; and
conveying a reactor effluent to an absorber, wherein the absorber has a pressure of about 35 psig to about 40 psig,
wherein an amount of the oxygen added to the reactor and the steam temperature are controlled to maintain a superficial reactor linear velocity between about 0.5 m/s to 1.5 m/s,
wherein a total available superheat coil area per reactor cross sectional area (ft 2 /ft 2 ) is about 1 to about 7.

2. The process of claim 1 wherein the superficial reactor linear velocity is maintained between about 0.7 m/s to about 1.0 m/s.

3. The process of claim 2 wherein the superficial reactor linear velocity is maintained between about 0.75 m/s to about 0.80 m/s.

4. The process of claim 1 wherein the superheat steam is provided with a temperature of about 355° C. to about 400° C.

5. The process of claim 1 wherein a reactor top pressure is maintained at about 3.8 psig to about 5.0 psig.

6. The process of claim 1 wherein the superheat coil area (ft 2 ) per heat removed by the superheat coils (kcal) per metric ton of acrylonitrile produced is about 275,000 to about 475,000.

7. The process of claim 1 wherein the reactant stream includes propylene.

8. The process of claim 7 wherein a flowrate of propylene to the ammoxidation reactor is effective for providing a ratio of oxygen to propylene of about 2 to about 2.1 and a ratio of ammonia to propylene of about 1 to about 1.5.

9. An ammoxidation process comprising:
introducing a flow of reactant stream into an ammoxidation reactor, wherein the reactant stream includes ammonia, an oxygen containing gas, a hydrocarbon selected from the group consisting of propane, propylene, isobutene, and isobutylene, or mixtures thereof; and
providing steam to coils disposed in the ammoxidation reactor to provide a reactor operating temperature of about 350° C. to about 480° C., wherein reactor temperature deviations are maintained within about 98% of the reactor temperature during changes in a heat transfer area of the coils; and
conveying a reactor effluent to an absorber, wherein the absorber has a pressure of about 35 psig to about 40 psig,
wherein an amount of the oxygen added to the reactor and the steam temperature are controlled and a superficial reactor linear velocity is maintained within about 95% of a target superficial reactor linear velocity of between about 0.5 m/s to about 1.5 m/s and within about 95% of a target reactor temperature,
wherein a total available superheat coil area per reactor cross sectional area (ft 2 /ft 2 ) is about 1 to about 7.

10. The process of claim 9 wherein the superficial reactor linear velocity is maintained within about 98% of the target superficial reactor linear velocity.

11. The process of claim 9 wherein the steam is superheated steam and the coils are superheated coils.

12. The process of claim 11 wherein the superheat steam is provided with a temperature of about 355° C. to about 400° C.

13. The process of claim 9 wherein a reactor pressure is maintained at about 3.8 psig to about 5.0 psig.

14. The process of claim 9 wherein the superheat coil area (ft 2 ) per heat removed by the superheat coils (kcal) per metric ton of acrylonitrile produced is about 275,000 to about 475,000.

15. The process of claim 9 wherein the reactant stream includes propylene.

16. The process of claim 15 wherein a flowrate of propylene to the ammoxidation reactor is effective for providing a ratio of oxygen to propylene of about 2 to about 2.1 and a ratio of ammonia to propylene of about 1 to about 1.5.

17. An ammoxidation process comprising:
introducing a flow of reactant stream into an ammoxidation reactor, wherein the reactant stream includes ammonia, a hydrocarbon selected from the group consisting of propane, propylene, isobutene, and isobutylene, or mixtures thereof, and an oxygen containing gas;
providing superheated steam to superheat coils disposed in the ammoxidation reactor, wherein reactor temperature deviations are maintained at about 10° C. or less during changes in a heat transfer area of the superheat coils; and
conveying a reactor effluent to an absorber, wherein the absorber has a pressure of about 35 psig to about 40 psig,
wherein the process includes controlling superficial reactor linear velocity and reactor operating temperature based on model predictive control to determine simultaneous control actions for manipulated variables in order to optimize at least one set of parameters while controlling at least one set of controlled variables,
wherein the set of manipulated variables includes superheated steam temperature, absorber pressure and amount of lean water to an absorber and the set of controlled variable includes a reactor linear velocity and a reactor temperature,
wherein the process provides a superficial reactor linear velocity of about 0.5 m/s to about 1.5 m/s.

18. The process of claim 17 wherein the process provides a reactor linear velocity of about 0.7 m/s to about 1.0 m/s.

19. The process of claim 18 wherein the process provides a reactor linear velocity of about 0.75 m/s to about 080 m/s.

20. The process of claim 17 wherein the reactor pressure is maintained at about 3.8 psig to about 5.0 psig.

21. The process of claim 17 wherein reactor temperature deviations are maintained at about 5° C. or less during changes in a heat transfer area of the coils.

22. The process of claim 17 wherein the superheat steam has a temperature of about 355° C. to about 400° C.

23. The process of claim 17 wherein a flowrate of propylene to the ammoxidation reactor is effective for providing a ratio of oxygen to propylene of about 2 to about 2.1 and a ratio of ammonia to propylene of about 1 to about 1.5.

Assignees

• Ineos Europe Ag

Inventors

• Shouche Manoj Shrikant
• Mcdonel Timothy Robert
• Couch Jay Robert

Classifications

• C07C253/24

  by ammoxidation of hydrocarbons or substituted hydrocarbons · CPC title

• B01J2208/00017

  Controlling the temperature · CPC title

• B01J8/1827

  the fluidising gas being a reactant · CPC title

• B01J8/24 Primary

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• C07C255/08

  Acrylonitrile; Methacrylonitrile · CPC title