Hydrocarbon conversion

Patent metadata

Field	Value
Publication number	US-11078130-B2
Application number	US-202016750764-A
Country	US
Kind code	B2
Filing date	Jan 23, 2020
Priority date	Aug 31, 2016
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

The invention relates to hydrocarbon conversion, to equipment and materials useful for hydrocarbon conversion, and to processes for carrying out hydrocarbon conversion, e.g., hydrocarbon pyrolysis processes. The hydrocarbon conversion is carried out in a reactor which includes at least one channeled member that comprises refractory and has an open frontal area≤55%. The refractory can include non-oxide ceramic.

First claim

We claim:

1. A reverse-flow reactor, comprising:
(a) a first channeled member having open frontal area (OFA)≤55%, the first channeled member comprising at least one refractory and having opposed first and second apertures and at least one internal channel, wherein
(i) the second aperture is separated from the first aperture by a first flow-path through the channel,
(ii) the refractory includes one or more of a first ceramic comprising at least one compound represented by the formula M n+1 AX n , a second ceramic comprising at least one compound represented by the formula N i B j , and a third ceramic comprising at least one compound represented by the formula P k Q m , and
(iii) M is at least one element selected from Groups 3-6 of the Periodic Table, A is at least one element selected from Groups 13-15 of the Periodic Table; X is carbon and/or nitrogen; N is at least one element selected from Groups 4 and 5 of the Periodic Table; B is boron; P is at least one element selected from Groups 4-10 of the Periodic Table; Q is silicon and/or aluminum; n is 1, 2, or 3; i and k are each a positive integer; j is i+1 or i+2; and m is a positive integer that can be greater than k, less than k, or equal to k;

(b) a second channeled member comprising at least one refractory and having opposed first and second apertures and at least one internal channel, the first and second apertures being separated by a second flow-path through the channel,
(c) a reactor vessel having opposed first and second openings and an internal volume, wherein (i) the internal volume includes the first and second channeled members; (ii) the first opening is adjacent to the first aperture of the first channeled member and the second opening is adjacent to the second aperture of the second channeled member, and (iii) the first and second openings are in fluidic communication through the first and second flow-paths;
(d) at least one feed conduit in fluidic communication with the first opening, at least one reaction product conduit in communication with the second opening, at least one fuel conduit in fluidic communication with the second opening, at least one oxidant conduit in fluidic communication with the second opening, and at least one combustion product conduit in fluidic communication with the first opening;
(e) at least one flow controller for
(i) during time interval t R establishing a flow of feed from the feed conduit into the first opening and a flow of a reaction product from the second opening into the reaction product conduit, and
(ii) during a time interval t H establishing a flow of fuel from the fuel conduit into the second opening, establishing a flow of oxidant from the oxidant conduit into the second opening, and establishing a flow of combustion product from the first opening into the combustion product conduit.

2. The reverse flow reactor of claim 1 , wherein the reactor vessel has the form of an elongated tube of circular, elliptical, or polygonal cross section, and wherein the reverse flow reactor further comprises at least one mixer distributor located in a flow path between the second aperture of the first channeled member and the first aperture of the second channeled member.

3. The reverse flow reactor of claim 1 , wherein M is selected from the group consisting of Sc, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and combinations thereof; A is selected from the group consisting of Al, Si, P, Ga, Ge, As, Cd, In, Sn, Tl, Pb, and combinations thereof; N is selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, and combinations thereof; P is selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, and combinations thereof; and m is ≤k.

4. The reverse flow reactor of claim 1 , wherein the first ceramic comprises one or more of Ti 3 SiC 2 , Ti 2 AlC, Nb 2 AlC, Zr 2 AlC, Ti 2 AlC, V 2 AlC, Cr 2 AlC, Hf 2 InC, Ti 2 SC, V 2 SC, Ti 3 SiC 2 , Ti 3 GeC 2 , Ti 3 SnC 2 , Ti 3 AlC 2 , Ti 2 AlC, Ti 2 AlN, Ti 3 AlC, Ti 3 AlN 2 , (Nb,Zr) 2 AlC, (Ti,V) 2 AlC, (Ti,Nb) 2 AlC, (Ti,Cr) 2 AlC, (Ti,Hf) 2 InC, and (Ti,V) 2 SC, Ti 3 (Si,Ge)C 2 , and Ti 3 (Sn,Al)C 2 , Ti 2 Al(C,N) and Ti 3 Al(C,N) 2 ; the second ceramic comprises ZrB 2 and/or HfB 2 ; and the third ceramic comprises Nb 3 Al, Nb 2 Al, NbAl, NbAl 3 , and MoSi 2 .

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Chun Changmin
• Bhandari Dhaval A
• Barrai Federico

Classifications

• B01J8/0492 Primary

  Feeding reactive fluids (for solid material, see B01J8/0015) · CPC title

• C04B2235/3217

  Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina · CPC title

• B01J2219/00159

  controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling · CPC title

• B01J19/02

  Apparatus characterised by being constructed of material selected for its chemically-resistant properties · CPC title

• C04B35/5618

  based on titanium aluminium carbides · CPC title