Thin glass sheet and system and method for forming the same

Patent metadata

Field	Value
Publication number	US-11078102-B2
Application number	US-201515529226-A
Country	US
Kind code	B2
Filing date	Nov 20, 2015
Priority date	Nov 26, 2014
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A method includes heating a glass preform having a plurality of glass layers and drawing the glass preform in a distal direction to form a drawn glass sheet extending distally from the glass preform and having the plurality of glass layers. The drawn glass sheet is thinner than the glass preform. The drawn glass sheet can be rolled onto a collection spool. At least a portion of a glass layer can be removed from the drawn glass sheet. An exemplary glass sheet includes a first glass layer, a second glass layer adjacent to the first glass layer, and a thickness of at most about 0.1 mm. An exemplary ion exchanged glass sheet includes a thickness of at most about 0.1 mm and a surface layer that is under a compressive stress and extends into an interior of the glass sheet to a depth of layer.

First claim

What is claimed is:

1. A method comprising:
contacting a first glass composition of a first glass layer in a viscous state with a second glass composition of a second glass layer in a viscous state to form a glass preform comprising a plurality of glass layers;
heating a glass preform comprising a first glass layer and a second glass layer adjacent to the first glass layer;
drawing the glass preform in a distal direction to form a drawn glass sheet extending distally from the glass preform and comprising the first glass layer and the second glass layer, a thickness of the drawn glass sheet being less than a thickness of the glass preform, wherein the thickness of the drawn glass sheet is at most 0.1 mm; and
removing at least a portion of the second glass layer from the drawn glass sheet to expose a surface of the first glass layer,
wherein the second glass layer comprises a first cladding layer and a second cladding layer, and the first glass layer comprises a core layer disposed between the first cladding layer and the second cladding layer, and forming an electronic device on a surface of the first glass layer prior to the removing step.

2. A method according to claim 1 further comprising:
pre-heating the glass preform comprising the plurality of glass layers to a first temperature in a preheating zone;
wherein the step of heating said glass preform comprises heating said glass preform-to a second temperature that is greater than the first temperature in a heating zone after the glass preform is advanced in a distal direction from the preheating zone;
rolling the drawn glass sheet onto a collection spool.

3. The method of claim 2 wherein the glass sheet comprises a first glass layer, a second glass layer adjacent to the first glass layer, and a thickness of at most about 0.1 mm.

4. The method of claim 2 , wherein the glass preform comprises a unitary laminate structure comprising the plurality of glass layers.

5. The method of claim 2 , wherein:
a preform thickness ratio of each of the plurality of glass layers comprises a ratio of a thickness of the respective glass layer in the glass preform to the thickness of the glass preform;
a sheet thickness ratio of each of the plurality of glass layers comprises a ratio of the thickness of the respective glass layer in the drawn glass sheet to the thickness of the drawn glass sheet; and
the preform thickness ratio of each of the plurality of glass layers is substantially the same as the sheet thickness ratio of the respective glass layer.

6. The method of claim 2 , wherein the plurality of glass layers comprises a first glass layer and a second glass layer adjacent to the first glass layer.

7. The method of claim 2 , wherein the plurality of glass layers comprises a core layer disposed between a first cladding layer and a second cladding layer, and the method comprises removing at least a portion of the core layer from the drawn glass sheet to separate the first cladding layer and the second cladding layer from each other.

8. The method of claim 2 , wherein:
the plurality of glass layers comprises a core layer disposed between a first cladding layer and a second cladding layer; and
an average coefficient of thermal expansion (CTE) of the core layer is greater than an average CTE of each of the first cladding layer and the second cladding layer.

9. The method of claim 2 , wherein the plurality of glass layers comprises a core layer disposed between a first cladding layer and a second cladding layer, and the method further comprises chemically strengthening the core layer by ion exchange with each of the first cladding layer and the second cladding layer.

10. The method of claim 9 , further comprising removing the first cladding layer and the second cladding layer from the strengthened core layer subsequent to the drawing step and the chemically strengthening step.

11. The method of claim 1 , wherein a degradation rate of the second glass layer in a reagent is greater than a degradation rate of the first glass layer in the reagent, and the removing step comprises contacting the drawn glass sheet with the reagent.

12. The method of claim 1 , wherein the heating the glass preform comprises contacting a first glass composition in a viscous state with a second glass composition in a viscous state to form the glass preform.

13. The method of claim 1 wherein the glass sheet comprises a first glass layer, a second glass layer adjacent to the first glass layer, and a thickness of at most about 0.1 mm.

14. The method of claim 2 , wherein the preheating of the glass preform to the first temperature in the preheating zone comprises heating the glass preform at a preheating rate, wherein the preheating is from about 5° C./min to about 200° C./min.

15. The method of claim 2 , wherein the heating zone is shorter than the preheating zone longitudinally in the distal direction.

16. The method of claim 2 , wherein the second temperature is at least about 100° C. greater than the first temperature.

Assignees

• Corning Inc

Inventors

• Cimo Patrick Joseph
• Ellison Adam James
• Gallagher Michael Thomas
• Post Dennis James
• Vaddi Butchi Reddy
• Venkataraman Natesan

Classifications

• C03B17/02 Primary

  Forming {molten} glass coated with coloured layers; {Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts} · CPC title

• B32B17/06

  comprising glass as the main or only constituent of a layer, next to another layer of a specific {material} · CPC title

• C03C3/087

  containing calcium oxide, e.g. common sheet or container glass · CPC title

• C03C3/097

  containing phosphorus, niobium or tantalum · CPC title

• C03B33/0207

  the sheet being in a substantially vertical plane · CPC title