Module for gas separation, and gas separation method

Patent metadata

Field	Value
Publication number	US-11077405-B2
Application number	US-201716080692-A
Country	US
Kind code	B2
Filing date	Mar 3, 2017
Priority date	Mar 4, 2016
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

Module for gas separation that maintains moisture retention of a gas separation active layer at a uniform level has a composite hollow-fiber membrane configured as the interior of an exterior body and has a porous hollow-fiber support body and a gas separation active layer disposed on the surface of the hollow-fiber support body. The exterior body has a supply port and a discharge port for a first gas passing through the outer side of the composite hollow-fiber membrane, and a supply port and a discharge port for a second gas passing through the inner side of the composite hollow-fiber membrane. The first gas flows through a first space enclosed by the exterior body and the outer side of the composite hollow-fiber membrane and the second gas flows through a second space separated by the composite hollow-fiber membrane and the exterior body. The first space is filled with an absorbing solution.

First claim

The invention claimed is:

1. A module for gas separation having a gas separation membrane disposed in an interior of an exterior body,
wherein the module has a first space enclosed by an outer side of the gas separation membrane and the exterior body and a second space on an inner side of the gas separation membrane, the first space and second space being separated by the gas separation membrane, and the first space is filled with an absorbing solution selected from the group consisting of water, and liquids or ionic liquids including at least one compound selected from the group consisting of amines, amino acids, carbonates, silver salts and copper salts, and
wherein the module has a draft tube between the exterior body and the gas separation membrane.

2. The module for gas separation according to claim 1 , wherein the gas separation membrane is a hollow fiber membrane having a porous hollow fiber support and a gas separation active layer situated on a surface of the hollow fiber support.

3. The module for gas separation according to claim 1 , wherein the exterior body has a supply port and a discharge port for a first gas that passes through the first space, and a supply port and a discharge port for a second gas that passes through the second space.

4. The module for gas separation according to claim 2 , wherein the hollow fiber membrane is a composite hollow fiber membrane having a porous hollow fiber support and a gas separation active layer situated on the surface of the hollow fiber support.

5. The module for gas separation according to claim 3 , wherein the first gas is a mixed gas including the gas component to be separated, and the second gas is a feed gas that is to recover the separated gas.

6. The module for gas separation according to claim 1 , wherein moisture is present in the second space.

7. The module for gas separation according to claim 6 , wherein a moisture content is 0.1% or higher and 5.0% or lower.

8. The module for gas separation according to claim 3 , wherein the discharge port and supply port for the first gas are connected.

9. The module for gas separation according to claim 8 , wherein the absorbing solution circulates through the discharge port and supply port for the first gas.

10. The module for gas separation according to claim 2 , wherein the gas separation active layer is composed mainly of a polymer gel, and the thickness of the layer is 10 nm or greater and 10 μm or smaller.

11. The module for gas separation according to claim 10 , wherein the polymer gel is chitosan.

12. The module for gas separation according to claim 2 , wherein the porous hollow fiber support is composed mainly of polyethersulfone or polyvinylidene fluoride.

13. The module for gas separation according to claim 2 , wherein the module has partitions that adhesively anchor both ends of the hollow fiber membrane to the exterior body while separating the first space and the second space, the partitions being made of an epoxy resin obtained by curing a composition containing a compound with an epoxy group as the base compound and a compound with an acid anhydride group as a curing agent.

14. The module for gas separation according to claim 1 , wherein the absorbing solution includes an aqueous solution including at least one metal salt selected from the group consisting of silver salts and copper salts, and the gas separation layer also contains the same metal salt as the absorbing solution.

15. The module for gas separation according to claim 1 , wherein a percentage of the first space occupied by the absorbing solution is 5 to 99 vol %.

16. The module for gas separation according to claim 14 , wherein the silver salt or copper salt in the absorbing solution filling the first space is 5 wt % to 90 wt % with respect to the total weight of the water.

17. The module for gas separation according to claim 1 , wherein pressure conditions in the first space are 0.1 to 2.5 MPaG.

18. The module for gas separation according to claim 3 , wherein a moisture content of the second gas is 0.1 to 99%.

19. The module for gas separation according to claim 3 , wherein a content of inert gas in the second gas is 0.1 to 99%.

20. A gas separation method in which a module for gas separation according to claim 5 is used to separate the gas to be separated from the mixed gas, the method being carried out under conditions in which a partial pressure of the gas to be separated in the first gas is higher than a partial pressure of the gas to be separated in the second gas.

21. A gas separation method in which moisture in a gas separated by the gas separation method according to claim 20 is separated by dehydrating equipment.

22. The gas separation method according to claim 20 , wherein the first gas is an olefin and/or carbon dioxide.

23. The gas separation method according to claim 22 , wherein the olefin contains any one of ethylene, propylene, isobutene, butene or butadiene.

24. The gas separation method according to claim 22 , wherein the olefin is a bio-olefin.

25. The gas separation method according to claim 21 , wherein, after separation of moisture by the dehydrating equipment, the separated gas has a content of olefin of 99.99% or greater, and a content of paraffin of 0.1 to 100 ppm.

26. The gas separation method according to claim 20 , which produces olefin gas having a propane content of 0.1 to 50 ppm and a purity of 99.995% or greater.

27. An olefin gas having a propane content of 0.1 to 50 ppm and a purity of 99.995% or greater.

28. An olefin gas having an oxygen content of 0.1 to 5 ppm and a purity of 99.995% or greater.

29. An olefin gas having a carbon dioxide content of 0.1 to 5 ppm and a purity of 99.995% or greater.

30. The gas separation method according to claim 22 , wherein the olefin is produced from a fermentation gas.

Assignees

• Asahi Chemical Ind

Inventors

• Mikawa Masato
• Kurishita Yasutaka
• Yamanaka Azusa

Classifications

• B01D63/00

  Apparatus in general for separation processes using semi-permeable membranes · CPC title

• B01D61/00

  Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor (separation of gases or vapours by diffusion B01D53/22) · CPC title

• B01D69/00

  Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor · CPC title

• B01D63/022 Primary

  Encapsulating hollow fibres · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title