Gel polymer electrolytes comprising electrolyte additive

Patent metadata

Field	Value
Publication number	US-11075406-B2
Application number	US-201815918946-A
Country	US
Kind code	B2
Filing date	Mar 12, 2018
Priority date	Nov 7, 2017
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

Systems and methods which provide an aqueous gel polymer electrolyte having one or more additive therein selected to configure the aqueous gel polymer electrolyte, and batteries formed therewith, for improved performance are described. Aqueous gel polymer electrolytes may, for example, have an additive compound including boron (e.g., a borate ion-containing salt) therein to configure batteries formed using the aqueous gel polymer electrolyte to increase the ionic conductivity of the gel polymer electrolyte. The addition of borax in Zinc-ion battery gel electrolytes of embodiments is configured to enhance the dissociation of zinc ions and anions, and subsequently release more mobile zinc ions. Furthermore, the interaction between borax and divalent transition metal (Zn) in electrolyte according to embodiments may enhance the transportation of mobile zinc ions.

First claim

What is claimed is:

1. An aqueous gel polymer electrolyte comprising:
an aqueous electrolyte solvent including at least one of a divalent zinc salt having a concentration of 0.2-3 M or a bivalent manganous salt solution having a concentration of 0.05-0.5 M;
a crosslinked polymer matrix, the crosslinked polymer matrix having a zinc salt solvent dispersed therein, wherein the aqueous electrolyte solvent is introduced into the crosslinked polymer matrix and forms an aqueous gel polymer; and
an electrolyte additive compound configured to increase ionic conductivity of the aqueous gel polymer electrolyte, wherein the electrolyte additive compound comprises sodium tetraborate decahydrate (Na 2 B 4 O 7 .10H 2 O), wherein the electrolyte additive compound is introduced into the aqueous gel polymer and forms the aqueous gel polymer electrolyte.

2. The aqueous gel polymer electrolyte of claim 1 , wherein the aqueous electrolyte solvent comprises at least one bivalent manganous salt, wherein the bivalent manganous salt solution has a concentration of 0.05-0.5 M.

3. The aqueous gel polymer electrolyte of claim 1 , wherein the crosslinked polymer matrix comprises at least one polymer selected from the group consisting of:
polyethylene oxide (PEO);
polypropylene oxide (PPO);
polyvinyl alcohol (PVA);
polyacrylamide (PAM);
polyacrylonitrile (PAN);
polymethyl methacrylate (PMMA);
polyacrylic acid (PAA);
gelatin; and
starch.

4. A rechargeable Zinc-ion battery comprising:
a cathode;
an anode; and
an aqueous gel polymer electrolyte comprising a crosslinked polymer matrix comprising an aqueous gel polymer, an aqueous electrolyte solvent including at least one of a divalent zinc salt and a bivalent manganous salt dispersed in the aqueous gel polymer, and an electrolyte additive compound including boron, wherein the electrolyte additive compound comprises tetraborate decahydrate (Na 2 B 4 O 7 .10H 2 O) and the electrolyte additive compound is configured to increase ionic conductivity of the aqueous gel polymer electrolyte.

5. The rechargeable Zinc-ion battery of claim 4 , wherein the rechargeable Zinc-ion battery is a rechargeable Zn—MnO x battery.

6. The rechargeable Zinc-ion battery of claim 5 , wherein the cathode comprises a current collector coated with a manganese dioxide (MnO 2 ) material and one or more binders.

7. The rechargeable Zinc-ion battery of claim 5 , wherein the anode comprises a current collector coated with a zinc material.

8. The aqueous gel polymer electrolyte of claim 1 , wherein the crosslinked polymer matrix comprises a gel monomer, crosslinking agent, and initiator mixed to form the crosslinked polymer matrix.

9. The aqueous gel polymer electrolyte of claim 1 , wherein the crosslinked polymer matrix comprises gelatin, and wherein the electrolyte additive compound reduces a crystallinity of the gelatin.

10. The aqueous gel polymer electrolyte of claim 1 , wherein the aqueous gel polymer electrolyte is formed via steps including:
mixing gel monomer, crosslinking agent, and initiator with aqueous electrolyte solvent for forming an aqueous gel polymer electrolyte mixture;
including an electrolyte additive compound including boron in the aqueous gel polymer electrolyte mixture to provide the aqueous gel polymer electrolyte having the electrolyte additive compound therein; and
curing the aqueous gel polymer electrolyte having the electrolyte additive compound therein.

11. The aqueous gel polymer electrolyte of claim 10 , wherein the gel monomer, crosslinking agent, and initiator form the crosslinked polymer matrix.

12. The aqueous gel polymer electrolyte of claim 1 , wherein the aqueous gel polymer electrolyte comprises 0.2 w % to 1 wt % tetraborate decahydrate (Na 2 B 4 O 7 .10H 2 O).

Assignees

• Univ City Hong Kong

Inventors

• Zhi Chunyi
• Zhu Minshen
• Tang Zijie

Classifications

• C08J5/20

  Manufacture of shaped structures of ion-exchange resins · CPC title

• H01M10/054 Primary

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01M10/0565 Primary

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• C01B15/12

  containing boron · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title