Lithium-sulfur battery

Patent metadata

Field	Value
Publication number	US-11075400-B2
Application number	US-201716328998-A
Country	US
Kind code	B2
Filing date	Sep 15, 2017
Priority date	Nov 21, 2016
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A lithium-sulfur battery in which a passivation film having a semi-interpenetrating polymer network (semi-IPN) structure is formed on an electrode to improve lifespan characteristics of high-loading lithium-sulfur batteries.

First claim

The invention claimed is:

1. A lithium-sulfur battery, comprising:
a positive electrode;
a negative electrode;
a separator and
an electrolyte interposed between the positive and negative electrodes,
wherein the positive electrode contacts the separator;
wherein a passivation film is disposed directly on the positive electrode coming into contact with the separator;
wherein the passivation film comprises a semi-interpenetrating polymer network (semi-IPN) structure, wherein the semi-IPN structure comprises a linear polymer and a lithium ion-conductive polymer;
further wherein the lithium ion-conductive polymer is crosslinked with a multifunctional cross-linking monomer containing two or more ethylenically unsaturated functional groups; and
wherein the multifunctional cross-linking monomer is used at a content of 5 to 50 parts by weight, based on 100 parts by weight of the lithium ion-conductive polymer.

2. The lithium-sulfur battery of claim 1 , wherein the lithium-sulfur battery is a high-loading lithium-sulfur battery having a sulfur loading amount of 1.0 to 10.0 mAh/cm 2 .

3. The lithium-sulfur battery of claim 1 , wherein the multifunctional cross-linking monomer comprises at least one selected from the group consisting of ethylene glycol diacrylate, tetraethylene glycol diacrylate, polyethylene glycol diacrylate, 1,6-hexanediol diacrylate, 1,4-butanediol diacrylate, neopentyl glycol diacrylate, 1,3-butylene glycol diacrylate, tris(2-hydroxyethyl)isocyanate diacrylate, erythritol diacrylate, pentaerythritol diacrylate, dierythritol diacrylate, dipentaerythritol diacrylate, bis(hydroxymethyl)tricyclodecane diacrylate, bisphenol A diacrylate and derivatives thereof, glycerol triacrylate, erythritol triacrylate, ditrimethylolpropane tetraacrylate, pentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, and tripentaerythritol octaacrylate.

4. The lithium-sulfur battery of claim 1 , wherein the multifunctional cross-linking monomer contains four or more ethylenically unsaturated functional groups.

5. The lithium-sulfur battery of claim 1 , wherein the passivation film comprises the multifunctional cross-linking monomer at a content of 5 to 25 parts by weight, based on 100 parts by weight of the lithium ion-conductive polymer.

6. The lithium-sulfur battery of claim 1 , wherein the lithium ion-conductive polymer comprises at least one selected from the group consisting of polyethylene oxide, polypropylene oxide, polydimethylsiloxane, polyacrylonitrile, polymethyl methacrylate, polyvinyl chloride, polyvinylidene fluoride, polyvinylidene fluoride-co-hexafluoropropylene, polyethyleneimine, polyphenylene terephthalamide, polymethoxy polyethylene glycol methacrylate, and poly(2-methoxy ethyl glycidyl ether).

7. The lithium-sulfur battery of claim 1 , wherein the lithium ion-conductive polymer comprises one or more selected from the group consisting of a cross-linked copolymer, which comprises a repeating unit represented by the following Formula 1 and a repeating unit represented by the following Formula 2; and a polyalkylene glycol and a polyacrylamide as linear polymers:

wherein R 1 and R 2 are the same or different from each other, and each independently hydrogen, or a C1 to C10 alkyl group, and R 3 and R 4 are each independently an alkali metal; and

wherein R 5 to R 8 are the same or different from each other, and each independently hydrogen, a C1 to C30 alkyl group, a C6 to C30 aryl group, or a C1 to C30 alkoxy group.

8. The lithium-sulfur battery of claim 1 , wherein the passivation film further comprises a lithium salt.

9. The lithium-sulfur battery of claim 1 , wherein a second passivation film is formed on the negative electrode coming into contact with the separator.

10. The lithium-sulfur battery of claim 1 , wherein the passivation film has a thickness of 1 to 10 μm.

11. The lithium-sulfur battery of claim 1 , wherein the passivation film comprises one or more inorganic fillers selected from the group consisting of silica, alumina, titania, ceria, zirconia, and manganese oxide.

Assignees

• Lg Chemical Ltd

Inventors

• Koh Dongwook
• Yang Doo Kyung
• Park Intae

Classifications

• H01M50/409

  Separators, membranes or diaphragms characterised by the material · CPC title

• H01M10/058

  Construction or manufacture · CPC title

• H01M4/5815

  Sulfides · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title