Interfacial engineering for stable lithium metal anodes
US-2016013462-A1 · Jan 14, 2016 · US
US11075395B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11075395-B2 |
| Application number | US-201715854177-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 26, 2017 |
| Priority date | Feb 23, 2017 |
| Publication date | Jul 27, 2021 |
| Grant date | Jul 27, 2021 |
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Disclosed is a fuel cell membrane electrode assembly (MEA) embodiment including an anode layer; at least one exchange membrane that is disposed on the anode layer as either a single-layered structure including one exchange membrane or a multi-layered structure including a plurality of exchange membranes, each exchange membrane of the at least one exchange membrane consisting of a film comprising hexagonal boron, and the at least one exchange membrane having a total thickness ranging from 0.3 to 3 nm; an interfacial binding layer that completely covers an exposed surface of one exchange membrane which is obverse to the anode layer and that consists of poly(methylmethacrylate) (PMMA) as a binder material; and a cathode layer formed on the interfacial binding layer. Alternately, a fuel cell membrane electrode embodiment may completely eliminate the interfacial binding layer and both embodiments provide superior fuel cell performance.
Opening claim text (preview).
What is claimed is: 1. A fuel cell membrane electrode assembly (MEA) with a hexagonal boron nitride film as an exchange membrane, the fuel cell MEA, comprising: an anode layer; at least one exchange membrane that is disposed on the anode layer as either a single-layered structure including one exchange membrane or a multi-layered structure including a plurality of exchange membranes, each exchange membrane of the at least one exchange membrane consisting of a film comprising hexagonal boron nitride, and the at least one exchange membrane having a total thickness ranging from 0.3 to 3 nm; an interfacial binding layer that is formed to completely cover an exposed surface of one exchange membrane which is obverse to the anode layer, and that consists of poly(methylmethacrylate) (PMMA) as a binder material; and a cathode layer formed on the interfacial binding layer. 2. The fuel cell MEA of claim 1 , wherein the total thickness of the at least one exchange membrane ranges from 0.3 to 1.7 nm. 3. The fuel cell MEA of claim 1 , wherein the at least one exchange membrane has the single-layered structure and consists of a single film that comprises a monatomic layer of hexagonal boron nitride. 4. The fuel cell MEA of claim 1 , wherein the film comprising hexagonal boron nitride is functionalized by H, O, F, or combinations thereof. 5. The fuel cell MEA according to claim 1 , wherein the at least one exchange membrane has the multi-layered structure and consists of a plurality of films that are laminated to one another, each film of the plurality of films consisting of a monatomic layer of hexagonal boron nitride. 6. The fuel cell MEA of claim 5 , wherein the total thickness of the at least one exchange membrane ranges from 0.3 to 1.7 nm. 7. The fuel cell MEA of claim 1 , wherein the interfacial binding layer has a thickness ranging from 2 to 50 μm. 8. The fuel cell MEA of claim 5 , wherein the interfacial binding layer has a thickness ranging from 2 to 50 μm.
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