Composite cathode active material, and cathode and lithium battery comprising composite cathode active material

Patent metadata

Field	Value
Publication number	US-11075367-B2
Application number	US-201715824829-A
Country	US
Kind code	B2
Filing date	Nov 28, 2017
Priority date	Nov 30, 2016
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A composite cathode active material, a cathode including the composite cathode active material, and a lithium battery including the cathode are provided. The composite cathode active material includes a core including a lithium metal oxide and a coating layer on the core, wherein the lithium metal oxide includes two or more transition metals including nickel (Ni), an amount of Ni within one mole of the two or more transition metals included in the lithium metal oxide is about 0.65 mol or greater, the coating layer includes LiF, and a resistance of the composite cathode active material is lower than that of the core.

First claim

What is claimed is:

1. A composite cathode active material comprising:
a core comprising a lithium metal oxide; and
a coating layer on the core,
wherein the lithium metal oxide includes two or more transition metals including comprising nickel (Ni),
an amount of Ni comprised in one mole of the two or more transition metals is about 0.65 mol or greater, and
the coating layer has a multi-layer structure comprising:
a first coating layer on the core comprising crystalline LiF,
and a second coating layer over the first coating layer and the core, the second coating layer comprising a carbonaceous material.

2. The composite cathode active material of claim 1 , wherein the second coating layer comprises a carbonized heat-treated electrolyte.

3. The composite cathode active material of claim 2 , wherein the carbonaceous material comprises amorphous carbon.

4. The composite cathode active material of claim 1 , wherein the coating layer is discontinuously disposed on the core.

5. The composite cathode active material of claim 1 , wherein the coating layer completely covers the core.

6. The composite cathode active material of claim 1 , wherein a thickness of the coating layer is about 2 nm to about 500 nm.

7. The composite cathode active material of claim 1 , wherein a thickness of the second coating layer is about 1 nm to about 100 nm.

8. The composite cathode active material of claim 1 , wherein the coating layer is a product of a reaction between a lithium metal oxide and a mixed solution comprising alcohol and an electrolyte solution.

9. The composite cathode active material of claim 8 , wherein the electrolyte solution comprises a fluorine-containing lithium salt and a non-aqueous solvent.

10. The composite cathode active material of claim 8 , wherein the coating layer is prepared by mixing the lithium metal oxide and the mixed solution to form a mixture and drying the mixture.

11. The composite cathode active material of claim 8 , wherein the coating layer is prepared by mixing the lithium metal oxide and the mixed solution to form a mixture, drying the mixture, and heat-treating the mixture.

12. The composite cathode active material of claim 11 , wherein the heat-treating is performed at a temperature of 400° C. to about 800° C.

13. The composite cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 1:
Li 1+a [Ni 1−x M x ]O 2−b X b   Formula 1

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35,
M is at least one selected from Al, Co, Mn, Mg, Zn, Fe, Cr, Ga, Mo, W, Ti, Sc, V, Cr, Fe, B, Si, Ga, Ge, As, Zr, Ru, Rh, Pt, Ag, and Sn, and
X is F or S.

14. The composite cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 2:
Li 1+a [N 1−x−y Co x M′ y ]O 2−b X b   Formula 2

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35, 0.01≤y≤0.35, 0.65≤1−x−y≤0.95,
M is at least one selected from Al, Mn, Mg, Zn, Fe, Cr, Ga, Mo, W, Ti, Sc, V, Cr, Fe, B, Si, Ga, Ge, As, Zr, Ru, Rh, Pt, Ag, and Sn, and
X is F or S.

15. The composite cathode active material of claim 1 , wherein the lithium metal oxide is represented by one selected from Formula 3 to Formula 6:
Li 1+a [Ni 1−x−y Co x Mn y ]O 2−b X b   Formula 3

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35, 0.01≤y≤0.35, 0.65≤1−x−y≤0.95, and
X is F or S;
Li 1+a [Ni 1−x−y Co x Al y ]O 2−b X b   Formula 4

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35, 0.01≤y≤0.35, 0.65≤1−x−y≤0.95, and
X is F or S;
Li 1+a [Ni 1−x−y−z Co x Mn y Al z ]O 2−b X b   Formula 5

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35, 0.01≤y≤0.35, 0.01≤y≤0.35, 0.65≤1−x−y−z≤0.95, and
X is F or S;
Li 1+a [Ni 1−x−y−z−v Co x Mn y Al z Mg v ]O 2−b X b   Formula 6

wherein 0≤a≤0.2, 0.01≤b≤0.1, 0.01≤x≤0.35, 0.01≤y≤0.35, 0.01≤y≤0.35, 0.01≤z≤0.35, 0.01≤v≤0.15, 0.65≤1−x−y−z−v≤0.95, and
X is F or S.

16. The composite cathode active material of claim 1 , wherein the core is a secondary particle comprising a plurality of aggregated primary particles.

17. A cathode comprising the composite cathode active material of claim 1 .

18. A lithium battery comprising the cathode of claim 17 .

Assignees

• Samsung Sdi Co Ltd

Inventors

• Song Yumi
• Kwon Seonyoung
• Kim Kihyun
• Kim Soohyeon
• Kim Jinhwa
• Moon Joongho
• Lee Jaeho
• Cho Kwanghwan
• Choi Soonbong
• Hong Mingzi

Classifications

• H01M4/362

  Composites · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C01B32/22

  Intercalation · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title