Scintillator, method of forming the same, and radiation detection apparatus

Patent metadata

Field	Value
Publication number	US-11073626-B2
Application number	US-201816178920-A
Country	US
Kind code	B2
Filing date	Nov 2, 2018
Priority date	Nov 10, 2017
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A scintillator having a columnar crystal structure vapor-deposited on a substrate, wherein each column of the crystal structure contains an alkali halide metal compound as a host material, and further contains, as an additive, a compound of a precious metal as a metal having lower ionization tendency than hydrogen (H), with the additive having a lower melting point than the host material.

First claim

What is claimed is:

1. A scintillator having a columnar crystal structure vapor-deposited on a substrate,
wherein each column of the crystal structure contains:
an alkali halide metal compound as a host material;
an activator agent for forming a trap level in a band gap of the crystal structure so as to improve luminous efficiency of the host material, wherein the activator agent is at least one element selected from the group consisting of thallium (Tl), europium (Eu), and indium (In); and
a compound of a precious metal, which is a metal having a lower ionization tendency than hydrogen (H), as an additive that is different from the activator agent and that has a lower melting point than the host material, wherein the precious metal is at least one element selected from the group consisting of gold (Au), silver (Ag), platinum (Pt), palladium (Pd), rhodium (Rh), iridium (Ir), ruthenium (Ru), osmium (Os), copper (Cu), and mercury (Hg).

2. The scintillator according to claim 1 , wherein the additive is not contained as a granular or powdery impurity in the crystal structure.

3. The scintillator according to claim 1 , wherein the host material is at least one selected from the group consisting of cesium iodide (CsI), sodium iodide (NaI), and potassium iodide (KI).

4. The scintillator according to claim 1 , wherein the host material is cesium iodide (CsI), the activator agent is thallium (Tl), and the precious metal is at least one element selected from the group consisting of gold (Au), silver (Ag), and copper (Cu).

5. The scintillator according to claim 1 , wherein the host material is cesium iodide (CsI), the activator agent is thallium (Tl), and the additive is a copper compound at a content of 10 ppm to 30 ppm, and
wherein when X-ray diffraction is performed for a powder of the scintillator obtained by dissolving the scintillator in water and then vaporizing and drying, at least one selected from the group consisting of CuI, Cs 3 Cu 2 I 5 , and CsCu 2 I 3 is detected as the copper compound.

6. A radiation detection apparatus comprising:
a scintillator defined in claim 1 ; and
a sensor unit in which a plurality of photoelectric conversion elements are arrayed.

7. A scintillator having a columnar crystal structure vapor-deposited on a substrate,
wherein each column of the crystal structure contains:
an alkali halide metal compound as a host material;
an activator agent for forming a trap level in a band gap of the crystal structure so as to improve luminous efficiency of the host material, wherein the activator agent is at least one element selected from the group consisting of thallium (Tl), europium (Eu), and indium (In); and
a compound of a precious metal, which is a metal having a lower ionization tendency than hydrogen (H), as an additive that is different from the activator agent and that has a lower melting point than the host material, at a concentration at which luminance of scintillation light is maintained, wherein the precious metal is at least one element selected from the group consisting of gold (Au), silver (Ag), platinum (Pt), palladium (Pd), rhodium (Rh), iridium (Ir), ruthenium (Ru), osmium (Os), copper (Cu), and mercury (Hg).

8. A method of forming a scintillator, the method comprising:
preparing a substrate; and
forming a scintillator having a columnar crystal structure by vapor-depositing an alkali halide metal compound, an activator agent, and a precious metal, which is a metal having a lower ionization tendency than hydrogen (H), on the substrate,
wherein each column of the crystal structure contains:
the alkali halide metal compound as a host material;
the activator agent for forming a trap level in a band gap of the crystal structure so as to improve luminous efficiency of the host material, wherein the activator agent is at least one element selected from the group consisting of thallium (Tl), europium (Eu), and indium (In); and
a compound of the precious metal as an additive having a lower melting point than the host material, where the additive is different from the activator agent, wherein the precious metal is at least one element selected from the group consisting of gold (Au), silver (Ag), platinum (Pt), palladium (Pd), rhodium (Rh), iridium (Ir), ruthenium (Ru), osmium (Os), copper (Cu), and mercury (Hg).

Assignees

• Canon Kk

Inventors

• Oike Tomoyuki
• Saruta Shoshiro

Classifications

• G21K4/00

  Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens (photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50) · CPC title

• G01T1/2023 Primary

  Selection of materials · CPC title

• C09K11/616

  with alkali or alkaline earth metals · CPC title

• C09K11/58

  containing copper, silver or gold · CPC title

• G01T1/2018

  Scintillation-photodiode combinations · CPC title