Method of making an antimicrobial textile

Patent metadata

Field	Value
Publication number	US-11072884-B2
Application number	US-201816161943-A
Country	US
Kind code	B2
Filing date	Oct 16, 2018
Priority date	Oct 16, 2018
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A method of making an antimicrobial textile comprising TiO2 nanoparticles is described. The TiO2 nanoparticles are immobilized by first treating a textile with a base, and then contacting with TiO2 nanoparticles in a solution of an alcohol and acid. The textile may be subsequently irradiated with UV light prior to use. The antimicrobial textile shows high effectiveness against the growth and proliferation of microorganisms transmitted within indoor environments.

First claim

The invention claimed is:

1. A method of making an antimicrobial textile, the method comprising:
contacting a textile with an inorganic base to produce a treated textile;
rinsing the treated textile to produce a rinsed textile;
submerging, in a coating vessel, at a temperature of at least 75° C. for at least one hour, the rinsed textile in a coating composition consisting of TiO 2 nanoparticles, methanol, and glacial acetic acid to form a coating mixture containing a coated textile, wherein the coating composition is circulated in the coating vessel during the submerging; and
neutralizing the coating mixture to a pH of 6.5-7.5 by adding nitric acid to the coating mixture; then
heating and drying the coated textile at a temperature of 27-50° C.; then
irradiating the coated textile with a UV light to form the antimicrobial textile, wherein the irradiating forms hydrogen bonds between the TiO 2 nanoparticles and surfaces of individual fibrils of the textile,
wherein the coating composition contains the TiO 2 nanoparticles at a concentration of 10-100 ppm by weight, and the TiO 2 nanoparticles are anatase TiO 2 nanoparticles having an average particle diameter of less than 21 nm; and
wherein the textile consists of cotton fibers.

2. The method of claim 1 , wherein the coating composition contains 60-90 wt % of the glacial acetic acid and 10-40 wt % of the methanol relative to a total weight of the coating composition.

3. The method of claim 1 , wherein the textile and the TiO 2 nanoparticles are not contacted with a binding agent, and the solution does not comprise a binding agent.

4. The method of claim 1 , wherein the antimicrobial textile contains the TiO 2 nanoparticles at a weight percentage of 0.01-2.00 wt % relative to a total weight of the antimicrobial textile.

5. The method of claim 1 , wherein the textile consists of cotton fiber.

6. The method of claim 1 , wherein the antimicrobial textile comprises fibers having a surface area in which 15-40% of the surface area is covered by TiO 2 nanoparticles.

7. The method of claim 1 , wherein the antimicrobial textile has an antimicrobial activity at least 100 times greater than a second textile that was treated with an essentially identical method that did not have TiO 2 nanoparticles, when the antimicrobial textile and the second textile are contacted with similar bacteria and/or fungal cells and a growth medium.

8. The method of claim 7 , wherein the antimicrobial activity is at least 1,000 times greater.

9. The method of claim 7 , wherein the antimicrobial textile and the second textile are contacted with similar bacteria, which are gram-positive cocci.

10. The method of claim 7 , wherein the antimicrobial textile and the second textile are contacted with similar fungal cells, which are yeast cells.

11. The method of claim 1 , wherein the antimicrobial textile is a component of a bandage, a cast, a gown, a lab coat, a mask, a shoe covering, a face covering, a curtain, a bedcovering, a carpeting, and/or a head covering.

12. The method of claim 1 , wherein the irradiating forms hydrogen bonds directly between hydroxyl groups of cellulose molecules of the cotton and surfaces of the TiO 2 nanoparticles.

Assignees

• Univ Imam Abdulrahman Bin Faisal

Inventors

• Salama Khaled
• Al Jindan Reem Y

Classifications

• D06M10/001

  Treatment with visible light, infrared or ultraviolet, X-rays · CPC title

• D06M10/08

  Organic compounds · CPC title

• A01N25/34

  Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group · CPC title

• A01N59/16

  Heavy metals; Compounds thereof · CPC title

• A01N31/02

  Acyclic compounds · CPC title