Actinic-ray-curable coating material composition and layered product

Patent metadata

Field	Value
Publication number	US-11072849-B2
Application number	US-201816121028-A
Country	US
Kind code	B2
Filing date	Sep 4, 2018
Priority date	Mar 4, 2016
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

Provided is a coating material composition which is capable of forming an undercoat layer for metallic vapor deposition, the layer being excellent in terms of adhesion to various bases and appearance. The actinic-ray-curable coating material composition according to the present invention comprises one or more resins A, a (meth)acrylate B, and a silane coupling agent C, wherein the resins A comprise a polymer A1 having a hydroxyl group with a hydroxyl value of 20-200 mg-KOH/g and/or an alkyd resin A2, the proportion of the resins A and that of the (meth)acrylate B are 20-60 mass % and 40-80 mass %, respectively, with respect to the total amount, which is taken as 100 mass %, of the resins A and the (meth)acrylate B, and the amount of the silane coupling agent C is 0.3-15 parts by mass per 100 parts by mass of the total amount of the resins A and the (meth)acrylate B.

First claim

The invention claimed is:

1. An actinic-ray-curable coating material composition comprising: a resin A; a (meth)acrylate B; and a silane coupling agent C, wherein
the resin A comprises: a polymer A1 having a hydroxyl group with a hydroxyl value of 80 to 200 mgKOH/g; or the polymer A1 and an alkyd resin A2,
a content of the resin A is 20 to 60 mass % and a content of the (meth)acrylate B is 40 to 80 mass % in terms of 100 mass % of the total amount of the resin A and the (meth)acrylate B,
a content of the silane coupling agent C is 0.3 to 15 parts by mass with respect to 100 parts by mass of the total amount of the resin A and the (meth)acrylate B, and
the polymer A1 contains a constituent unit derived from a monomer represented by the following Formula (1):

in Formula (1), R 1 and R 2 each independently represent H or CH 3 , R 3 and R 4 each independently represent C n H 2n+1 , and n is from 1 to 10.

2. The actinic-ray-curable coating material composition according to claim 1 , wherein the content of the resin A is 30 to 60 mass % and the content of the (meth)acrylate B is 40 to 70 mass % in terms of 100 mass % of the total amount of the resin A and the (meth)acrylate B.

3. The actinic-ray-curable coating material composition according to claim 1 , wherein the resin A comprises the polymer A1 having a mass average molecular weight of 10,000 to 80,000.

4. The actinic-ray-curable coating material composition according to claim 1 , wherein the resin A comprises the polymer A1 containing a constituent unit derived from hydroxyalkyl (meth)acrylate.

5. The actinic-ray-curable coating material composition according to claim 1 , wherein the resin A comprises the alkyd resin A2 that is an oil-modified alkyd resin.

6. The actinic-ray-curable coating material composition according to claim 1 , wherein the (meth)acrylate B contains polyfunctional (meth)acrylate having two to six (meth)acryloyloxy groups.

7. The actinic-ray-curable coating material composition according to claim 6 , wherein the (meth)acrylate B contains at least one kind of (meth)acrylate selected from the group consisting of tricyclodecane dimethanol di(meth)acrylate, bis(2-acryloyloxyethyl)-2-hydroxyethyl isocyanurate, pentaerythritol tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, tris(2-acryloyloxyethyl) isocyanurate, pentaerythritol tetra(meth)acrylate, dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate, and polyester (meth)acrylate.

8. The actinic-ray-curable coating material composition according to claim 1 , wherein the silane coupling agent C has an amino group or a glycidyl group.

9. The actinic-ray-curable coating material composition according to claim 8 , wherein the silane coupling agent C contains at least one kind of silane coupling agent selected from the group consisting of N-(2-aminoethyl)3-aminopropylmethyldimethoxysilane, N-(2-aminoethyl)3-aminopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, and 3-glycidoxypropylmethyl-dimethoxysilane.

10. The actinic-ray-curable coating material composition according to claim 1 , further comprising a photopolymerization initiator D.

11. The actinic-ray-curable coating material composition according to claim 10 , wherein the photopolymerization initiator D is contained in 0.1 to 20 parts by mass with respect to 100 parts by mass of the total amount of the resin A and the (meth)acrylate B.

12. The actinic-ray-curable coating material composition according to claim 1 , wherein the actinic-ray-curable coating material composition is used in an undercoat material for metallic vapor deposition.

13. The actinic-ray-curable coating material composition according to claim 1 , wherein the resin A comprises the polymer A1 having a hydroxyl group with a hydroxyl value of 80 to 200 mgKOH/g.

14. The actinic-ray-curable coating material composition according to claim 1 , wherein the resin A comprises the polymer A1 having a hydroxyl group with a hydroxyl value of 80 to 140 mgKOH/g and the alkyd resin A2.

15. The actinic-ray-curable coating material composition according to claim 1 , wherein the content of the resin A is 40 to 50 mass % and the content of the (meth)acrylate B is 50 to 60 mass % in terms of 100 mass % of the total amount of the resin A and the (meth)acrylate B.

16. A layered product being obtained by stacking a coating layer of an actinic-ray-curable coating material composition and a metallic vapor deposition film on a surface of a resin base material in this order, wherein the actinic-ray-curable coating material composition comprising: a resin A; a (meth)acrylate B; and a silane coupling agent C, wherein
the resin A comprises a polymer A1 having a hydroxyl group with a hydroxyl value of 80 to 200 mgKOH/g and/or an alkyd resin A2,
a content of the resin A is 20 to 60 mass % and a content of the (meth)acrylate B is 40 to 80 mass % in terms of 100 mass % of the total amount of the resin A and the (meth)acrylate B,
a content of the silane coupling agent C is 0.3 to 15 parts by mass with respect to 100 parts by mass of the total amount of the resin A and the (meth)acrylate B, and
the polymer A1 contains a constituent unit derived from a monomer represented by the following Formula (1):

in Formula (1), R 1 and R 2 each independently represent H or CH 3 , R 3 and R 4 each independently represent C n H 2n+1 , and n is from 1 to 10.

17. The layered product according to claim 16 , wherein the layered product is an automotive lamp member.

Assignees

• Mitsubishi Chem Corp

Inventors

• FUKE Yoshimi
• Yagi Masatoshi

Classifications

• C08F257/02

  on to polymers of styrene or alkyl-substituted styrenes · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title

• C09D4/06

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00 · CPC title

• C09D201/06

  containing oxygen atoms {(C09D201/025 takes precedence)} · CPC title