Process and system for processing petroleum feed

Patent metadata

Field	Value
Publication number	US-11072749-B2
Application number	US-202016815056-A
Country	US
Kind code	B2
Filing date	Mar 11, 2020
Priority date	Mar 25, 2019
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A novel process/system for flexibly producing chemicals and fuels from a petroleum feed such as crude comprise a flashing drum, a first cracker (e.g., a fluidized bed pyrolysis cracker or an oxidative cracker), and an olefin-to-gasoline reaction zone. The process/system can also include a steam cracker and a hydrotreater. The process/system can convert crude oil into hydrogen, C2-C4 olefins, gas oil and distillates with various amounts by adjusting the cut point of the bottoms effluent exiting the flashing drum.

First claim

What is claimed is:

1. A process for processing a petroleum feed to produce a plurality of hydrocarbon products, the process comprising:
(I) feeding the petroleum feed to a flashing drum;
(II) obtaining a liquid bottoms effluent comprising bottoms hydrocarbons and a vapor overhead effluent comprising overhead hydrocarbons from the flashing drum, wherein the bottoms hydrocarbons optionally comprise a non-volatile component;
(III) feeding at least a portion of the bottoms effluent to a first cracker through a first inlet on the first cracker;
(IV) converting at least a portion of the bottoms hydrocarbons under a first set of cracking conditions in the first cracker to produce a first cracker product mixture comprising olefins;
(V) feeding at least a portion of the first cracker product mixture into an olefin-to-gasoline (“OTG”) reaction zone;
(VI) converting at least a portion of the first cracker product mixture into gasoline in the presence of an OTG catalyst in the OTG reaction zone; and
(VII) obtaining an OTG product mixture from the OTG reaction zone; wherein the first cracker is a fluidized bed cracker, and the process further comprises:
feeding a plurality of solid particles and a gas stream into the first cracker upstream of the first inlet to form a fluidized bed of the solid particles;
contacting the solid particles with the bottoms hydrocarbons in the first cracker to effect pyrolysis of at least a portion of the bottoms hydrocarbons; and
regenerating a portion of the solid particles;
wherein the first inlet is located in the vicinity of the top of the fluidized bed of the solid particles.

2. The process of claim 1 , wherein the flashing drum is operated at a cutpoint of the liquid bottoms effluent in the range from 371 to 482° C. (700 to 900° F.) at an absolute pressure in the range from 280 to 1850 kilopascal.

3. The process of claim 1 , wherein the first set of cracking conditions comprise a residence time in the first cracker of no greater than 1 second.

4. The process of claim 1 , wherein the first cracker is a fluid coking cracker, and the solid particles are coke particles.

5. The process of claim 1 , wherein the gas stream comprises molecular oxygen and optionally steam.

6. The process of claim 1 , wherein the top of the fluidized bed of the solid particles has a temperature in the range from 593 to 982° C. (1100 to 1800° F.) and an absolute pressure in the range from 100 to 1724 kilopascal (from near atmospheric pressure to 250 psi).

7. The process of claim 1 , further comprising:
recovering from the OTG product mixture in a first product recovery zone to obtain one or more of:
a first gas stream comprising hydrogen, methane, C2-C4 hydrocarbons, CO 2 , and steam;
a first naphtha stream;
a distillate stream; and
a first tar stream.

8. The process of claim 7 , further comprising:
separating the first gas stream to obtain one or more of: a first fuel gas stream comprising methane, a first hydrogen stream, and a first C2-C4 hydrocarbon stream.

9. The process of claim 8 , further comprising:
feeding the first tar stream and hydrogen into a hydrotreater, where the hydrogen is optionally at least partly derived from the first hydrogen stream; and
producing a low-sulfur hydrocarbon fuel product from the hydrotreater.

10. The process of claim 8 , further comprising:
feeding at least a portion of the first C2-C4 hydrocarbon stream to the second product recovery zone.

11. The process of claim 1 , further comprising:
(VIII) feeding the overhead effluent into a second cracker, the second cracker being a steam cracker;
(IX) obtaining a second cracker product mixture from the second cracker; and
(X) recovering from at least a portion of the second cracker product mixture in a second product recovery zone one or more of: one or more light olefins; a second hydrogen stream; a second fuel gas stream comprising methane; a steam cracked naphtha stream; and a second tar stream.

12. The process of claim 11 , further comprising:
feeding the second tar stream and optionally at least a portion of the second hydrogen stream into the hydrotreater.

13. The process of claim 1 , further comprising:
adjusting a cutpoint of the bottoms effluent in the flashing drum to vary the quantities of the overhead effluent and the bottoms effluent, thereby varying the quantities of the plurality of hydrocarbon products produced.

14. The process of claim 1 , wherein the petroleum feed is a crude oil or a mixture thereof.

15. A process for processing a petroleum feed to produce a plurality of hydrocarbon products, the process comprising:
(I) feeding the petroleum feed to a flashing drum;
(II) obtaining a liquid bottoms effluent comprising bottoms hydrocarbons and a vapor overhead effluent comprising overhead hydrocarbons from the flashing drum, wherein the bottoms hydrocarbons optionally comprise a non-volatile component;
(III) feeding at least a portion of the bottoms effluent to a first cracker through a first inlet on the first cracker;
(IV) converting at least a portion of the bottoms hydrocarbons under a first set of cracking conditions in the first cracker to produce a first cracker product mixture comprising olefins;
(V) feeding at least a portion of the first cracker product mixture into an olefin-to-gasoline (“OTG”) reaction zone;
(VI) converting at least a portion of the first cracker product mixture into gasoline in the presence of an OTG catalyst in the OTG reaction zone; and
(VII) obtaining an OTG product mixture from the OTG reaction zone; wherein the first cracker is an oxidative cracker, and the process comprises:
feeding an oxidizing gas stream comprising molecular oxygen and optionally steam into the first cracker through a second inlet upstream of the first inlet; and
oxidizing at least a portion of the bottoms hydrocarbons in an oxidation zone in the first cracker, such that the maximum temperature in the oxidation zone is from 1000 to 1400° C., to effect pyrolysis of at least a portion of the bottoms hydrocarbons.

16. The process of claim 1 , further comprising:
quenching the first cracker product mixture with a quenching stream in a quenching zone before feeding the at least a portion of the first cracker product mixture into the OTG reaction zone to produce a quenched first cracker product mixture.

17. The process of claim 16 , wherein the quenching stream comprises crackable C2 to C4 hydrocarbons.

18. The process of claim 16 , wherein the quenching stream is derived, at least in part, from the vapor overhead effluent obtained from the flashing drum.

19. The process of claim 16 , further comprising:
cooling the first cracker product mixture or the quenched first cracker product mixture by using a heat exchanger in an indirect cooling zone.

20. The process of claim 16 , wherein upon quenching and/or indirect cooling, the first cracker product mixture enters into the OTG reaction zone at a temperature in the range from 260 to 816° C. (500 to 1500° F.).

21. The process of claim 16 , wherein the OTG reaction zone is immediately downstream of the quenching zone or the indirect an indirect cooling zone, and the first cracker, the quenching zone and/or the indirect cooling zone, and the OTG reaction zone are located inside a common vessel.

22. A system for processing a petroleum feed comprising non-volatile components, the reaction system comprising:
(A) a flashing drum comprising an inlet adapted for receiving a petroleum feed, an

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Harandi Mohsen N
• Keusenkothen Paul F

Classifications

• B01J2219/0004

  Processes in series · CPC title

• C10G57/02

  with polymerisation · CPC title

• B01J6/008

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• C10G2400/02

  Gasoline · CPC title