Fine silver particle dispersion

US11072715B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11072715-B2
Application numberUS-201916375095-A
CountryUS
Kind codeB2
Filing dateApr 4, 2019
Priority dateApr 4, 2019
Publication dateJul 27, 2021
Grant dateJul 27, 2021

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

This disclosure relates to a conductive paste comprising a fine silver particle dispersion and a glass frit, wherein the fine silver particle dispersion comprising: (1) 65 to 95.4% by weight of fine silver particles which have average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having primary particle diameter of 100 nm or larger, (2) 4.5 to 34.5% by weight of a solvent, (3) 0.1 to 1.0% by weight of ethyl cellulose having weight average molecular weight of 10,000 to 120,000. Also provided are: a method of manufacturing an electrically conductive thick film comprising steps of: (a) applying said fine silver particle dispersion on a substrate, and (b) heating the applied fine silver particle dispersion at 80 to 1000° C.; and an electrical device comprising a conductive thick film made with the foregoing paste.

First claim

Opening claim text (preview).

What is claimed is: 1. A conductive paste comprising a fine silver particle dispersion and a glass frit, wherein the fine silver particle dispersion comprises: (1) 65 to 95.4% by weight of fine silver particles which have an average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having a primary particle diameter of 100 nm or larger, (2) 4.5 to 34.5% by weight of a solvent, and (3) 0.1 to 1.0% by weight of ethyl cellulose having a weight average molecular weight of 10,000 to 120,000. 2. The conductive paste of claim 1 , wherein the fine silver particles are coated with an organic protective material. 3. The conductive paste of claim 2 , wherein the organic protective material is an amine with carbon number of from 8 to 12. 4. The conductive paste of claim 1 , wherein a boiling point of the solvent is 150 to 350° C. 5. The conductive paste of claim 1 , wherein the solvent is selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol dibutyl ether, diethylene glycol monobutyl ether acetate, terpineol, and any mixture thereof. 6. The conductive paste of claim 1 , wherein the ethyl cellulose has a weight average molecular weight of 30,000 to 105,000. 7. The conductive paste of claim 1 , wherein the ethyl cellulose has a weight average molecular weight of 50,000 to 90,000. 8. The conductive paste of claim 1 , wherein the fine silver particle dispersion comprises 0.3 to 0.9% by weight of the ethyl cellulose. 9. The conductive paste of claim 1 , wherein the fine silver particle dispersion comprises 0.6 to 0.9% by weight of the ethyl cellulose. 10. The conductive paste of claim 1 , wherein the fine silver particles have an average primary particle diameter of 25 to 110 nm. 11. The conductive paste of claim 1 , wherein the fine silver particle dispersion comprises 70 to 87% by weight of the fine silver particles. 12. The conductive paste of claim 1 , wherein the fine silver particles comprise 15% by number or less of silver particles having a primary particle diameter of 100 nm or larger. 13. The conductive paste of claim 1 , wherein an amount of a substance having a weight average molecular weight of 150,000 or more in the fine silver particle dispersion is 0.09% by weight or less. 14. The conductive paste of claim 1 , wherein the fine silver particle dispersion comprises 11.1 to 31.5% by weight of the solvent. 15. The conductive paste of claim 1 , wherein an amount of a substance having a weight average molecular weight of 150,000 or more in the fine silver particle dispersion is 0.05% by weight or less.

Assignees

Inventors

Classifications

  • Silver · CPC title

  • Glass · CPC title

  • C09D5/24Primary

    Electrically-conducting paints {(conductive materials H01B1/00)} · CPC title

  • Additives being defined by their diameter · CPC title

  • C09D101/28Primary

    Alkyl ethers · CPC title

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What does patent US11072715B2 cover?
This disclosure relates to a conductive paste comprising a fine silver particle dispersion and a glass frit, wherein the fine silver particle dispersion comprising: (1) 65 to 95.4% by weight of fine silver particles which have average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having primary particle diameter of 100 nm or larger, (2) 4…
Who is the assignee on this patent?
Du Pont
What technology area does this patent fall under?
Primary CPC classification C09D5/24. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jul 27 2021 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 4 related publications on this page (citations in our corpus or others sharing the same primary CPC).