Composition comprising heterophasic propylene copolymer

Patent metadata

Field	Value
Publication number	US-11072698-B2
Application number	US-201816635666-A
Country	US
Kind code	B2
Filing date	Aug 2, 2018
Priority date	Aug 8, 2017
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

The invention relates to a composition comprising (A) a propylene-based polymer, (B) an elastomer of ethylene and α-olefin comonomer having 4 to 10 carbon atoms and (C) an inorganic filler,wherein (A) the propylene-based polymer has a melt flow index of 60 to 150 dg/min measured according to ASTM D1238 (2.16 kg/230° C.) andwherein (B) the elastomer has a density of 0.840 to 0.865 g/cm3,wherein (B) the elastomer has a melt flow index of 3 to 13 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.,wherein the amount of (B) the elastomer is 2 to 30 wt % based on the total composition,wherein the amount of (C) the inorganic filler is 0.1 to 30 wt % based on the total composition.

First claim

The invention claimed is:

1. A composition comprising
(A) a propylene-based polymer,
(B) an elastomer of ethylene and α-olefin comonomer having 4 to 10 carbon atoms and
(C) an inorganic filler,
wherein (A) the propylene-based polymer has a melt flow index of 60 to 150 dg/min measured according to ASTM D1238 (2.16 kg/230° C.) and
wherein (B) the elastomer has a density of 0.840 to 0.865 g/cm 3 ,
wherein (B) the elastomer has a melt flow index of 3 to 13 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.,
wherein the amount of (B) the elastomer is 2 to 30 wt % based on the total composition,
wherein the amount of (C) the inorganic filler is 0.1 to 30 wt % based on the total composition, and
wherein the elastomer is an ethylene-1-octene copolymer.

2. The composition according to claim 1 , wherein the elastomer has a melt flow index of 4 to 10 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 190° C.

3. The composition according to claim 1 , wherein the elastomer has a density of 0.850 to 0.865 g/cm 3 .

4. The composition according to claim 1 , wherein the propylene-based polymer is a heterophasic propylene copolymer consisting of
(a) a propylene-based matrix,
wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene copolymer consisting of at least 96 wt % of propylene monomer units and at most 4 wt % of ethylene monomer units and/or an α-olefin monomer units having 4 to 10 carbon atoms, based on the total weight of the propylene-based matrix and
wherein the propylene-based matrix is present in an amount of 65 to 95 wt % based on the total heterophasic propylene copolymer and
(b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is an ethylene-propylene copolymer, wherein the ethylene-α olefin copolymer is present in an amount of 35 to 5 wt % based on the total heterophasic propylene copolymer.

5. The composition according to claim 4 , wherein the propylene-based matrix is a propylene homopolymer.

6. The composition according to claim 4 , wherein
the ethylene-α olefin copolymer is present in an amount of 30 to 5 wt %, based on the total heterophasic propylene copolymer and/or
the amount of ethylene monomer units in the ethylene-α-olefin copolymer is in the range of 40 to 65 wt %, based on the ethylene-α-olefin copolymer.

7. The composition of claim 6 , wherein
the ethylene-α olefin copolymer is present in an amount of 25 to 5 wt %, based on the total heterophasic propylene copolymer and/or
the amount of ethylene monomer units in the ethylene-α-olefin copolymer is in the range of 45 to 60 wt %, based on the ethylene-α-olefin copolymer.

8. The composition according to claim 4 , wherein
the propylene-based matrix has a melt flow index of 50 to 300 dg/min, measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C. and/or
the dispersed ethylene-α-olefin copolymer has a melt flow index of 0.1 to 3 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.

9. The composition of claim 8 , wherein the propylene-based matrix has a melt flow index of 100 to 200 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.

10. The composition according to claim 4 , wherein [(MFI of the heterophasic propylene copolymer in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)−(MFI of the composition in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)/[amount of the elastomer in the composition in wt %] is at most 0.7 (dg/min)/wt %.

11. The composition of claim 4 , wherein [(MFI of the heterophasic propylene copolymer in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)−(MFI of the composition in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)/[amount of the elastomer in the composition in wt %] is at most 0.6 (dg/min)/wt %.

12. The composition of claim 4 , wherein [(MFI of the heterophasic propylene copolymer in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)−(MFI of the composition in dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.)/[amount of the elastomer in the composition in wt %] is 0.3 to 0.5 (dg/min)/wt %.

13. The composition according to claim 1 , wherein the amount of the elastomer is 10 to 30 wt % based on the total composition.

14. The composition according to claim 1 , wherein the composition has a melt flow index of at least 20 dg/min measured in accordance with ASTM D1238 using a 2.16 kg weight and at a temperature of 230° C.

15. The composition according to claim 1 , wherein the inorganic filler is selected from the group consisting of calcium carbonate, talc, magnesium carbonate, synthetic carbonates, wollastonite, dolomite, gypsum, kaolinite, aluminum hydroxide, aluminosilicates, mica, natural siliconates, silica containing aggregates, zeolites and mixtures thereof.

16. The composition according to claim 1 , wherein the inorganic filler has a d50 of 1 to 10 μm.

17. A process for the preparation of the composition according to claim 1 , comprising melt mixing (A), (B) and (C).

18. An article comprising the composition of claim 1 .

Assignees

• Sabic Global Technologies Bv

Inventors

• Huang Ting
• Guo Kai
• Fu Yang
• Zhou Ji
• Shen Dake
• Soliman Maria

Classifications

• C08L2666/72

  Fillers; Inorganic pigments; Reinforcing additives · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08L2666/62

  Clay · CPC title