Pesticidally active heterocyclic derivatives with sulphur containing substituents

Patent metadata

Field	Value
Publication number	US-11072608-B2
Application number	US-201916443596-A
Country	US
Kind code	B2
Filing date	Jun 17, 2019
Priority date	Dec 17, 2014
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

Compounds of formula I(I), wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides and can be prepared in a manner known per se.

First claim

The invention claimed is:

1. A compound of formula XV-int

wherein
A represents CH or N;
X is S, SO or SO 2 ,
R 1 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl-C 1 -C 4 alkyl or C 3 -C 6 cycloalkyl mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano and C 1 -C 4 alkyl; or
R 1 is C 3 -C 6 cycloalkyl-C 1 -C 4 alkyl mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano and C 1 -C 4 alkyl; or
R 1 is C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl or C 2 -C 4 alkynyl;
R 2 is halogen, cyano, C 1 -C 6 haloalkyl or C 1 -C 6 haloalkyl substituted by one or two substituents selected from the group consisting of hydroxyl, methoxy and cyano; or
R 2 is C 1 -C 4 haloalkylsulfanyl, C 1 -C 4 haloalkylsulfinyl, C 1 -C 4 haloalkylsulfonyl, O(C 1 -C 4 haloalkyl), or C(O)C 1 -C 4 haloalkyl; or
R 2 is C 3 -C 6 cycloalkyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano and C 1 -C 4 alkyl;
R 3 is hydrogen, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl, C 1 -C 4 alkoxy-C 1 -C 4 alkyl or C 3 -C 6 cycloalkyl; and
Q is a group

wherein R 0002 is cyano.

2. The compound of claim 1 , wherein R 3 is hydrogen or C 1 -C 4 alkyl.

3. The compound of claim 1 , wherein R 3 is C 1 -C 4 alkyl.

4. The compound of claim 1 , wherein R 2 is halogen, cyano, C 1 -C 6 haloalkyl, or C 1 -C 4 haloalkylsulfanyl.

5. The compound of claim 1 , wherein R 2 is C 1 -C 6 haloalkyl.

6. The compound of claim 1 , wherein R 1 is C 1 -C 4 alkyl.

7. The compound of claim 6 , wherein R 3 is hydrogen or C 1 -C 4 alkyl.

8. The compound of claim 7 , wherein R 2 is halogen, cyano, C 1 -C 6 haloalkyl, or C 1 -C 4 haloalkylsulfanyl.

9. The compound of claim 8 , wherein A is N.

10. The compound of claim 9 , wherein R 3 is C 1 -C 4 alkyl.

11. The compound of claim 10 , wherein R 2 is CF 3 or —S—CF 3 .

12. The compound of claim 11 , wherein R 1 is ethyl.

13. The compound of claim 12 , wherein R 3 is hydrogen or methyl.

14. The compound of claim 13 , wherein R 3 is methyl.

15. The compound of claim 14 , wherein X is S or SO 2 .

16. The compound of claim 15 , wherein R 2 is CF 3 .

Assignees

• Syngenta Participations Ag

Inventors

• Hueter Ottmar Franz
• Edmunds Andrew
• Jeanguenat Andre
• Jung Pierre Joseph Marcel
• Buchholz Anke
• Muehlebach Michel

Classifications

• C07D471/04 Primary

  Ortho-condensed systems · CPC title

• A01N43/50

  1,3-Diazoles; Hydrogenated 1,3-diazoles · CPC title

• A01N43/90

  having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system · CPC title