Fatty alcohol aqueous suspension-based anti-filming surface admixture

Patent metadata

Field	Value
Publication number	US-11072561-B2
Application number	US-201615573003-A
Country	US
Kind code	B2
Filing date	May 25, 2016
Priority date	May 27, 2015
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

A composition includes: an ethoxylated fatty alcohol having from 8 to 22 carbon atoms and having an ethoxylation level of from 1 to 10 moles of ethylene oxide per mole of fatty alcohol, —an alkanolamine or a morpholine, or its derivatives or mix of them, and a fatty acid. A hydraulic binder includes the composition. A process prevents the formation of a surface film at the surface of hydraulic binders, wherein the composition is added to the dry hydraulic binder. A process for preparing the composition, includes: melting the ethoxylated fatty alcohol and heating it at a temperature above its melting point, adding water to the melted ethoxylated fatty alcohol and mixing, adding fatty acid to the mixture and mixing, adding alkanolamine or morpholine, or its derivative or mix of them to the mixture obtained and mixing, and adding water.

First claim

The invention claimed is:

1. A composition consisting of:
an ethoxylated fatty alcohol having from 8 to 22 carbon atoms and having an ethoxylation level of from 1 to 10 moles of ethylene oxide per mole of fatty alcohol, and an amount of the ethoxylated fatty alcohol being in a range of from 2% to 30% by weight,
a trialkanolamine, or a morpholine or derivatives thereof, or a mixture containing one or more trialkanolamine(s) and/or morpholine and/or one or more derivative(s) of morpholine, and an amount of the trialkanolamine, or the morpholine or derivatives thereof, or the mixture being in a range of from 0.007% to 3% by weight,
a fatty acid, and an amount of the fatty acid being in a range of from 0.013% to 6% by weight,
an anti-foaming agent,
a biocide, and
optionally water, wherein when the water is present, the composition is an aqueous suspension.

2. The composition according to claim 1 , wherein the trialkanolamine is triethanolamine.

3. The composition according to claim 1 , wherein the fatty acid is stearic acid.

4. The composition according to claim 1 , wherein water is present in a quantity sufficient for 100% by weight.

5. The composition according to claim 1 , wherein the ethoxylated fatty alcohol has from 16 to 18 carbon atoms, and an ethoxylation level of 2 moles of ethylene oxide per mole of fatty alcohol.

6. A method comprising adding the composition according to claim 1 to a hydraulic binder.

7. The method according to claim 6 , wherein the hydraulic binder comprises a calcium salt or Portland cement.

8. The method according to claim 7 , wherein the calcium salt is a calcium sulfate in the form of a hemihydrate or an anhydrite.

9. A method comprising adding the composition according to claim 1 to a hydraulic binder in a sufficient amount to prevent formation of a surface film at a surface of the hydraulic binder.

10. A hydraulic binder, comprising the composition according to claim 1 .

11. The hydraulic binder according to claim 10 , comprising from 0.1 to 5% by weight of the composition.

12. A process for preventing formation of a surface film at a surface of hydraulic binders, comprising adding the composition according to claim 1 to a dry hydraulic binder.

13. The process according to claim 12 , wherein composition is added to the dry hydraulic binder before mixing with any water.

14. A process for preparing the composition according to claim 1 , comprising:
a) melting the ethoxylated fatty alcohol and heating it at a temperature above its melting point,
b) adding water to the melted ethoxylated fatty alcohol obtained from step a), and mixing,
c) adding the fatty acid to the mixture obtained from step b), and mixing,
d1) adding the trialkanolamine, or the morpholine or derivative thereof, or the mixture to the mixture obtained from step c), and mixing,
d2) adding the anti-foaming agent to the mixture obtained from step d1), and mixing,
e) adding water, and
f) adding the biocide thereby obtaining the composition.

15. The composition according to claim 1 , wherein the composition is in the form of a liquid or an aqueous dispersion.

16. The composition according to claim 1 , wherein a density of the composition is from 0.7 to 1.0.

17. The composition according to claim 1 , wherein the trialkanolamine comprises triisopropanolamine and/or triethanolamine, and/or morpholine is present.

18. The composition according to claim 1 , wherein the trialkanolamine comprises triisopropanolamine, or morpholine is present.

19. The composition according to claim 1 , wherein:
the amount of the ethoxylated fatty alcohol is in a range of from 2% to 10% by weight,
the amount of the trialkanolamine, or the morpholine or derivatives thereof, or the mixture is in a range of from 0.007% to 0.67% by weight, and
the amount of the fatty acid is in a range of from 0.013% to 1.33% by weight by weight.

20. The composition according to claim 19 , wherein the amount of the ethoxylated fatty alcohol is in a range of from 2% to 7.5% by weight.

Assignees

• Sika Tech Ag

Inventors

• Rolland Jérôme
• Herr Oliver
• Monge Joachim
• Nigaud Justine
• Ouallet Jean-Jacques

Classifications

• C04B28/04 Primary

  Portland cements · CPC title

• C04B2111/21

  Efflorescence resistance · CPC title

• C04B2111/60

  Flooring materials · CPC title

• C04B40/0039

  Premixtures of ingredients · CPC title

• C04B28/145

  Calcium sulfate hemi-hydrate with a specific crystal form · CPC title