Catalytic conversion of DSO in presence of water

Patent metadata

Field	Value
Publication number	US-11072529-B2
Application number	US-201616344987-A
Country	US
Kind code	B2
Filing date	Oct 27, 2016
Priority date	Oct 27, 2016
Publication date	Jul 27, 2021
Grant date	Jul 27, 2021

Abstract

The present invention relates to a method for the catalytic conversion in vapor phase of disulfide oil into methane and hydrogen sulfide, comprising the step of contacting disulfide oil, eventually in the presence of water, with a supported transition metal catalyst.

First claim

The invention claimed is:

1. A method for the catalytic conversion in vapor phase of disulfide oil into methane and hydrogen sulfide, the method comprising contacting disulfide oil with a supported transition metal catalyst,
wherein contacting disulfide oil with the supported transition metal catalyst is performed in the presence of water.

2. The method according to claim 1 , wherein the supported transition metal catalyst comprises a support chosen from alumina (Al 2 O 3 ), silica, titania (TiO 2 ) or a mixture thereof.

3. The method according to claim 2 , wherein the alumina is alpha-alumina, gamma-alumina, delta-alumina, or theta-alumina.

4. The method according to claim 1 , wherein the supported transition metal catalyst comprises a transition metal, wherein the transition metal is manganese, iron, cobalt, nickel, copper, zinc, molybdenum, ruthenium, rhodium or a mixture thereof.

5. The method according to claim 1 , wherein the content of a transition metal in the supported transition metal catalyst relative to a support is 0.1 wt % to 10 wt %.

6. The method according to claim 5 , wherein the content of a transition metal in the supported transition metal catalyst relative to a support is 2.2 wt % to 2.7 wt %.

7. The method according to claim 1 , wherein the molar ratio of water in the vapor phase comprising disulfide oil to disulfide oil is 0.1 to 10.

8. The method according to claim 1 , wherein contacting disulfide oil with the transition metal catalyst is performed at a temperature from 350° C. to 700° C.

9. The method according to claim 1 , further comprising a step of oxidative regeneration of a spent supported transition metal catalyst.

10. The method according to claim 9 , wherein the oxidative regeneration is performed in the presence of air.

11. The method according to claim 1 , wherein the molar ratio of water in the vapor phase comprising disulfide oil to disulfide oil is 1.4 to 4.

12. The method according to claim 1 , wherein contacting disulfide oil with the transition metal catalyst is performed at a temperature from 540° C. to 560° C.

13. A catalytic conversion unit for the catalytic conversion in vapor phase of disulfide oil into methane and hydrogen sulfide, the catalytic conversion unit comprising a catalytic reactor comprising:
a vapor feed line to feed the catalytic reactor with a vapor phase of disulfide oil,
a gas recover line to recover a gaseous stream comprising methane and H 2 S, and
at least one catalytic bed wherein a supported transition metal catalyst is placed,

wherein the catalytic conversion unit further comprises:
a vapor generator unit for generating the vapor phase of disulfide oil and fluidly connected to the vapor feed line of the catalytic reactor,
a liquid feed line to feed the vapor generator unit with liquid disulfide oil, and a water reactor for providing liquid water or water steam to the catalytic conversion unit through a water line.

14. The catalytic conversion unit according to claim 13 , wherein the water line is fluidly connected to one or more of the liquid feed line, the vapor generator unit, the vapor feed line and the catalytic reactor.

15. The catalytic conversion unit according to claim 13 , wherein the water reactor is fed with the vapor phase of disulfide oil by the vapor feed line and is fluidly connected to the catalytic reactor through a water enriched DSO line.

16. The catalytic conversion unit according to claim 13 , further comprising:
a separation unit fed by the gas recover line of the catalytic reactor for separating methane from hydrogen sulfide of the gaseous stream,
a methane line to recover methane, and
an hydrogen sulfide line to recover hydrogen sulfide.

17. The catalytic conversion unit according to claim 16 , further comprising a sulfur recovery unit fed by the hydrogen sulfide line and having a sulfur exit line for recovering elemental sulfur and a gas exit line for recovering a tail gas stream.

Assignees

• Total Sa

Inventors

• Leroi Catherine
• Weiss Claire
• Cadours Renaud
• Cammarano Claudia
• Hulea Vasile

Classifications

• C10L2290/12

  Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel · CPC title

• C10L3/103

  Sulfur containing contaminants · CPC title

• C01B17/165 Primary

  Preparation from sulfides, oxysulfides or polysulfides · CPC title

• C10L2290/141

  of additive or catalyst · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title