Metal carburization process to produce a uniform, concentrated solid solution of interstitial carbon workpiece and articles made from same

Patent metadata

Field	Value
Publication number	US-11066735-B2
Application number	US-201916654367-A
Country	US
Kind code	B2
Filing date	Oct 16, 2019
Priority date	May 6, 2014
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A carburization method for steel is contemplated, with austenitic stainless steel showing particular promise. The surface is first passivated with an acidic solution and then subjected to low temperature (between ˜350 to 550° C. or between ˜650 to 1,000° F.) carburization in the presence of a concentrated carbon solution (e.g., carbon monoxide, hydrogen gas, and nitrogen gas), followed by a repeated cycle of passivation and carburization under identical conditions but for a comparatively shorter period of time relative to the first cycle. The carburized surface is allowed to cool and cleaned, after which the resulting surface is shown to have ultrahigh tensile strength, increased interatomic bonding strength, and lowered electrical and thermal conductivity. To the extent this method can be employed to completely saturate and penetrate the workpiece (e.g., a foil), the resultant material and article are formed entirely from a novel composition.

First claim

What is claimed is:

1. A process of treating austenitic steel by forming a concentrated solid solution of interstitial carbon throughout the austenitic steel and without any underlying substrate layer so as to improve observed tensile strength, yield strength, and Young's modulus of the treated austenitic steel, the process comprising:
providing an original workpiece formed from austenitic steel having a defined thickness,
activating a surface of the workpiece with an acid-based treatment at an elevated temperature for a selected period of time;
after the activating step, carburizing the workpiece at a temperature of less than 550° C. for a selected period of time to produce a treated workpiece; and
wherein at least one of: the thickness of the workpiece, the acid based-treatment, the elevated temperature for the activating step, the selected period of time for the activating step, the elevated temperature for the carburizing step, and the selected period of time for the carburizing step are selected to ensure any underlying substrate layer is eliminated from the workpiece and wherein the treated workpiece has increased tensile strength, increased yield strength, and larger Young modulus in comparison to the austenitic steel of the original workpiece.

2. The process of claim 1 wherein the selected period of time for each of the activating and the carburizing steps are identical.

3. The process of claim 1 wherein the tensile strength of the treated workpiece is at least 3 times greater in comparison to the original workpiece.

4. The process of claim 1 wherein the yield strength of the treated workpiece is at least 4 times greater in comparison to the original workpiece.

5. The process of claim 1 wherein the Young modulus is at least 1.5 times greater in comparison to the original workpiece.

6. The process of claim 1 wherein the activating and carburizing step are repeated in succession for a first time and a second time so that the treated workpiece is formed after the second time.

7. The process of claim 6 wherein the selected periods of time for the activating and carburizing steps in the second time are reduced in comparison to the first time.

8. The process of claim 7 the selected period of time for each of the activating and the carburizing steps in the second time are identical.

9. The process of claim 1 further comprising cleaning the workpiece: (i) prior to the activation step and/or (ii) after after the carburizing step.

10. A process of producing a surgical or cutting tool, the process comprising:
providing an original workpiece formed from austenitic steel having a defined thickness,
activating a surface of the workpiece with an acid-based treatment at an elevated temperature for a selected period of time;
after the activating step, carburizing the workpiece at a temperature of less than 550° C. for a selected period of time;
after the carburizing step, allowing the workpiece to cool to ambient temperature and forming a surgical or cutting tool from the workpiece; and
wherein at least one of: the thickness of the workpiece, the acid based-treatment, the elevated temperature for the activating step, the selected period of time for the activating step, the elevated temperature for the carburizing step, and the selected period of time for the carburizing step are selected to ensure any underlying substrate layer is eliminated from the workpiece and wherein at least one of a tensile strength, a yield strength, and an Young modulus in the surgical or cutting tool is greater than in comparison to the original workpiece.

11. The process according to claim 10 wherein the surgical or cutting tool is a stent.

Assignees

• Univ Case Western Reserve

Inventors

• Ren Zhe
• Ernst Frank

Classifications

• C23C8/22 Primary

  of ferrous surfaces · CPC title

• C21D8/0257

  with diffusion of elements, e.g. decarburising, nitriding · CPC title

• C21D1/18 Primary

  Hardening (C21D1/02 takes precedence); Quenching with or without subsequent tempering (quenching devices C21D1/62) · CPC title

• C23C8/80

  After-treatment · CPC title

• C23C8/10

  Oxidising · CPC title