Light alkanes to liquid fuels

Patent metadata

Field	Value
Publication number	US-11066608-B2
Application number	US-202017095158-A
Country	US
Kind code	B2
Filing date	Nov 11, 2020
Priority date	Nov 12, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

The present disclosure relates generally processes and systems for converting a C2-C7 light alkanes feed to liquid transportation fuels or value-added chemicals. The feed is contacted with an aromatization catalyst at a temperature and pressure that selectively converts C4 and larger alkanes to an intermediate product comprising monocyclic aromatics and olefins. Following separation of the aromatics and C5+ hydrocarbons from the intermediate product, unconverted C2-C3 alkanes are thermally-cracked to produce olefins that are subsequently oligomerized to produce a liquid transportation fuel blend stock or value-added chemicals.

First claim

We claim:

1. A method for upgrading light hydrocarbons to a liquid transportation fuel or a value-added chemical, comprising:
a) providing a light alkanes feed stream comprising alkanes containing from two to seven carbon atoms, wherein at least 50 wt. % of the light alkanes feed stream comprises alkanes and at least 90 mol. % of the alkanes contain from two to four carbon atoms;
b) contacting the light alkanes feed stream with an aromatization catalyst comprising at least one zeolite that is impregnated with at least one metal, wherein the contacting occurs in an aromatization reactor that is maintained at a temperature and a pressure that selectively facilitates conversion of alkanes containing four or more carbon atoms to olefins and aromatics by the aromatization catalyst, wherein the conversion produces a first effluent comprising light olefins, aromatics, hydrogen and unconverted light alkanes that contain three or less carbon atoms;
c) separating the first effluent in a first separator to produce a first condensed liquid hydrocarbons comprising olefins and aromatics containing at least four carbon atoms, and an uncondensed light hydrocarbons predominantly comprising unconverted alkanes and olefins containing two or three carbon atoms;
d) thermally cracking the uncondensed light hydrocarbons in a cracking reactor to produce a second effluent predominantly comprising olefins containing from two to four carbon atoms, methane and hydrogen;
e) separating the second effluent in a second separator to produce a second condensed liquid hydrocarbons comprising hydrocarbons containing at least five carbon atoms, a light olefin stream comprising olefins contacting from two to four carbon atoms hydrogen, methane and residual alkanes containing two or three carbon atoms;
f) contacting the light olefin stream with an oligomerization catalyst in an oligomerization reactor that is maintained at a temperature and pressure that facilitates the catalytic conversion of the light olefin stream by an oligomerization catalyst to produce a third effluent comprising monocyclic aromatics, alkanes containing at least five carbon atoms, light alkanes containing from one to four carbon atoms and hydrogen;
g) separating the third effluent in a third separator to produce a fuel gas stream comprising light alkanes containing from one to four carbon atoms and hydrogen and a third condensed liquid hydrocarbons comprising alkanes, olefins and aromatics containing at least five carbon atoms that possess the characteristics of at least one of: a liquid transportation fuel component and a value-added chemical intermediate.

2. The method of claim 1 , further comprising separating the fuel gas stream to produce a hydrogen stream and a light olefins and light alkanes stream that is recycled to the thermal cracking reactor.

3. The method of claim 1 , wherein at least 70 wt. % of the light alkanes feed stream comprises alkanes and at least 90 mol % of the alkanes contain from two to four carbon atoms.

4. The method of claim 1 , wherein the temperature and the pressure maintained in the aromatization reactor are suitable to facilitate the conversion of the light alkanes feed stream by the aromatization catalyst to produce of a first effluent comprising at least 15 wt. % of monocyclic aromatics while leaving at least 95 mol % of alkanes containing two or three carbon atoms unreacted.

5. The method of claim 1 , wherein the temperature that is maintained in the aromatization reactor is in the range from 350° C. to 575° C.

6. The method of claim 1 , wherein the temperature that is maintained in the aromatization reactor is in the range from 400° C. to 525° C.

7. The method of claim 1 , wherein the contacting of the light alkanes feed stream with the aromatization catalyst converts at least 85 wt. % of alkanes in the light alkanes feed stream that contain from four to seven carbon atoms to olefins and aromatics.

8. The method of claim 1 , wherein the weight hourly space velocity within the aromatization reactor is in the range from 0.5 hr −1 to 5 hr −1 .

9. The method of claim 1 , wherein the combined partial pressure of alkanes containing from four to seven carbon atoms in the aromatization reactor is in the range from 10 psig to 100 psig.

10. The method of claim 1 , wherein the temperature, pressure and feed rate that are maintained in the oligomerization reactor facilitate catalytic conversion of at least 85 mol % of olefins containing from two to four carbon atoms that are present in the light olefin stream by the oligomerization catalyst.

11. The method of claim 1 , wherein the temperature, pressure and feed rate maintained in the oligomerization reactor facilitate the catalytic conversion of the light olefin stream by the oligomerization catalyst to produce a third effluent comprising at least 70 wt. % of hydrocarbons that contain at least five carbon atoms.

12. The method of claim 1 , wherein the contacting of the light olefin stream with the oligomerization catalyst occurs at a temperature in the range from 100° C. and 450° C.

13. The method of claim 1 , wherein the contacting of the light olefin stream with the oligomerization catalyst occurs at a temperature in the range from 225° C. to 400° C.

14. The method of claim 1 , wherein the contacting of the light olefin stream with the oligomerization catalyst occurs at a pressure in the range from 0 psig to 300 psig.

15. The method of claim 1 , wherein the contacting of the light olefin stream with the oligomerization catalyst occurs at a pressure in the range from 50 psig to 200 psig.

16. The method of claim 1 , wherein the weight hourly space velocity within the oligomerization reactor is in the range of 0.5 hr −1 to 5 hr −1 .

17. The method of claim 1 , wherein the catalyst in the aromatization reactor comprises ZSM-5 zeolite.

18. The method of claim 1 , wherein the catalyst in the oligomerization reactor comprises ZSM-5 zeolite.

19. The method of claim 1 , wherein the light alkanes feed stream comprises a Y-grade fraction of natural gas liquids.

20. The method of claim 1 , further comprising mixing the first condensed liquid hydrocarbons and the second condensed liquid hydrocarbons to produce a final liquid product hydrocarbons comprising hydrocarbon molecules that are characterized by a boiling point in the range of gasoline (40° C. to 193° C.) or diesel (193° C. to 360° C.).

Assignees

• Phillips 66 Co

Inventors

• Yao Jianhua
• Mcdaniel Neal D
• Randolph Bruce B
• Walston Robert M
• Baldridge Anthony O
• Suttil James A
• Kundu Soumen
• Xie Hong
• Lusk Steven E

Classifications

• C10G2400/04

  Diesel oil · CPC title

• C10G9/00

  Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils · CPC title

• C10G2300/4012

  Pressure · CPC title

• C10G57/02 Primary

  with polymerisation · CPC title

• C10G2400/02

  Gasoline · CPC title