Curable composition and method for reinforcing shaped structure with use of same

Patent metadata

Field	Value
Publication number	US-11066579-B2
Application number	US-201615569450-A
Country	US
Kind code	B2
Filing date	Apr 26, 2016
Priority date	Apr 28, 2015
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

This curable composition can easily reinforce shaped objects and the reinforced shaped objects have good color developability and excellent texture. The curable composition includes a 2-cyanoacrylic acid ester and a surface conditioner, in which the c content of the surface conditioner is 0.001-10 parts by mass relative to 100 parts by mass of the 2-cyanoacrylic acid ester, and the surface tension of the composition is 28 mN/m or less at 25° C. Preferred surface conditioners are silicone-based and fluorinated surface conditioners. Reinforced shaped objects and a method for reinforcing shaped objects using the curable composition are also provided.

First claim

The invention claimed is:

1. A curable composition consisting essentially of
as a polymerizable monomer, a 2-cyanoacrylic acid ester; and
a surface conditioner,

in which the surface conditioner is contained in an amount of 0.001-10 parts by mass relative to 100 parts by mass of the 2-cyanoacrylic acid ester and the composition has a surface tension of 28 mN/m or less at 25° C.

2. The curable composition according to claim 1 , wherein the surface conditioner is a fluorinated surface conditioner.

3. The curable composition according to claim 2 , wherein the surface conditioner is at least one selected from the group consisting of oligomers containing fluorinated group, hydrophilic group, and lipophilic group and oligomers containing a fluorinated group and a lipophilic group.

4. A curable composition according to claim 1 , wherein the 2-cyanoacrylic acid ester comprises at least one compound selected from
compounds represented by formula (1)

wherein R 1 represents a straight-chain or branched-chain alkyl group having from 1 to 12 carbon atoms, cycloalkyl group, allyl group, or aryl group, and
compounds represented by formula (2):

wherein R 2 represents an alkylene group having from 1 to 4 carbon atoms, and R 3 represents a straight-chain or branched-chain alkyl group having from 1 to 8 carbon atoms.

5. A curable composition according to claim 4 , wherein the 2-cyanoacrylic acid ester comprises at least one compound selected from the compounds represented by formula (1).

6. The curable composition according to claim 1 , wherein the curable composition further consisting essentially of a plasticizer.

7. The curable composition according to claim 1 , wherein the curable composition further consisting essentially of a stabilizer.

8. The curable composition according to claim 1 , wherein the curable composition further consisting essentially of a thickener.

9. The curable composition according to claim 1 , wherein the curable composition further consisting essentially of a hardening accelerator.

10. The curable composition according to claim 1 , wherein the curable composition further consisting essentially of at least one selected from the group consisting of a plasticizer, a stabilizer, a thickener and a hardening accelerator.

Assignees

• Toagosei Co Ltd

Inventors

• Oikawa Hiroshige
• Ando Yushi

Classifications

• B33Y70/00 Primary

  Materials specially adapted for additive manufacturing · CPC title

• B29C64/00

  Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• C08K5/101

  of monocarboxylic acids · CPC title

• C09D4/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title