Dispersant attached polytetrafluoroethylene particle, composition, layered material, electrophotographic photoreceptor, process cartridge, and image forming apparatus

US11066543B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11066543-B2
Application numberUS-201916567458-A
CountryUS
Kind codeB2
Filing dateSep 11, 2019
Priority dateJun 15, 2018
Publication dateJul 20, 2021
Grant dateJul 20, 2021

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

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A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached has a content of perfluorooctanoic acid of from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle, and a composition contains a polytetrafluoroethylene particle and a dispersant having a fluorine atom in which a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle.

First claim

Opening claim text (preview).

What is claimed is: 1. A dispersant attached polytetrafluoroethylene particle comprising: a polytetrafluoroethylene particle, and a dispersant having a fluorine atom, wherein: the dispersant is attached to a surface of the polytetrafluoroethylene particle, a content of perfluorooctanoic acid is from 0.01 ppb to 25 ppb with respect to the dispersant attached polytetrafluoroethylene particle, and the dispersant is a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) and a structural unit represented by the following formula (FB): wherein, in the formulae (FA) and (FB): each of R F1 , R F2 , R F3 and R F4 independently represents a hydrogen atom or an alkyl group; X F1 represents an alkylene chain, a halogen-substituted alkylene chain, —S—, —O—, —NH— or a single bond; Y F1 represents an alkylene chain, a halogen-substituted alkylene chain, —C fx H 2fx-1 (OH))— or a single bond; Q F1 represents —O— or —NH—; each of fl, fm and fn independently represents an integer of 1 or more; each of fp, fq, fr and fs independently represents 0 or an integer of 1 or more; ft represents an integer of 1 to 7; and fx represents an integer of 1 or more. 2. The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein the dispersant attached polytetrafluoroethylene particle has an average particle diameter of from 0.2 μm to 4.5 μm. 3. The dispersant attached polytetrafluoroethylene particle as claimed in claim 1 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluoroethylene particle. 4. The dispersant attached polytetrafluoroethylene particle as claimed in claim 3 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 5. A composition comprising the dispersant attached polytetrafluoroethylene particle as claimed in claim 1 . 6. The composition as claimed in claim 5 , wherein an average particle diameter of the dispersant attached polytetrafluoroethylene particle is from 0.2 μm to 4.5 μm. 7. The composition as claimed in claim 5 , wherein the composition is in a liquid state or in a solid state. 8. The composition as claimed in claim 5 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluoroethylene particle. 9. The composition as claimed in claim 8 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 10. A layered material comprising the dispersant attached polytetrafluoroethylene particle as claimed in claim 1 . 11. The layered material as claimed in claim 10 , wherein an average particle diameter of the dispersant attached polytetrafluoroethylene particle is from 0.2 μm to 4.5 μm. 12. The layered material as claimed in claim 10 , wherein a content of the dispersant having a fluorine atom is from 0.5% by weight to 10% by weight with respect to the polytetrafluoroethylene particle. 13. The layered material as claimed in claim 12 , wherein the content of the dispersant having a fluorine atom is from 1% by weight to 7% by weight with respect to the polytetrafluoroethylene particle. 14. An electrophotographic photoreceptor comprising a conductive substrate and a photosensitive layer, wherein an outermost surface layer of the electrophotographic photoreceptor is a layer comprising the layered material as claimed in claim 10 . 15. The electrophotographic photoreceptor as claimed in claim 14 , wherein the outermost surface layer is a surface protective layer having a crosslinked structure. 16. A process cartridge comprising the electrophotographic photoreceptor as claimed in claim 15 , wherein the process cartridge is detachably attached to an image forming apparatus. 17. An image forming apparatus comprising: the electrophotographic photoreceptor as claimed in claim 15 , a charging unit that charges a surface of the electrophotographic photoreceptor, an electrostatic latent image forming unit that forms an electrostatic latent image on the charged surface of the electrophotographic photoreceptor, a developing unit that develops the electrostatic latent image formed on the surface of the electrophotographic photoreceptor using a developer containing a toner to form a toner image, and a transfer unit that transfers the toner image to a surface of a recording medium. 18. A process cartridge comprising the electrophotographic photoreceptor as claimed in claim 14 , wherein the process cartridge is detachably attached to an image forming apparatus. 19. An image forming apparatus comprising: the electrophotographic photoreceptor as claimed in claim 14 , a charging unit that charges a surface of the electrophotographic photoreceptor, an electrostatic latent image forming unit that forms an electrostatic latent image on the charged surface of the electrophotographic photoreceptor, a developing unit that develops the electrostatic latent image formed on the surface of the electrophotographic photoreceptor using a developer containing a toner to form a toner image, and a transfer unit that transfers the toner image to a surface of a recording medium. 20. A dispersant attached polytetrafluoroethylene particle comprising: a polytetrafluoroethylene particle, and a dispersant having a fluorine atom, wherein: the dispersant is attached to a surface of the polytetrafluoroethylene particle, a content of perfluorooctanoic acid is from 0 ppb to 25 ppb with respect to the dispersant attached polytetrafluoroethylene particle, and the dispersant is a fluorinated alkyl group-containing polymer having a structural unit represented by the following formula (FA) and a structural unit represented by the following formula (FB): wherein, in the formulae (FA) and (FB): each of R F1 , R F2 , R F3 and R F4 independently represents a hydrogen atom or an alkyl group; X F1 represents an alkylene chain, a halogen-substituted alkylene chain, —S—, —O—, —NH— or a single bond; Y F1 represents an alkylene chain, a halogen-substituted alkylene chain, —C fx H 2fx-1 (OH))— or a single bond; Q F1 represents —O— or —NH—; each of fl, fm and fn independently represents an integer of 1 or more; each of fp, fq, fr and fs independently represents 0 or an integer of 1 or more; ft represents an integer of 1 to 7; and fx represents an integer of 1 or more.

Assignees

Inventors

Classifications

  • Organic compounds containing halogen · CPC title

  • Homopolymers or copolymers of tetrafluoroethene · CPC title

  • Homopolymers or copolymers or tetrafluoroethene · CPC title

  • C08L33/14Primary

    of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

  • Halogenated polymers · CPC title

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What does patent US11066543B2 cover?
A dispersant attached polytetrafluoroethylene particle on whose surface a dispersant having a fluorine atom is attached has a content of perfluorooctanoic acid of from 0 ppb to 25 ppb with respect to the polytetrafluoroethylene particle, and a composition contains a polytetrafluoroethylene particle and a dispersant having a fluorine atom in which a content of perfluorooctanoic acid is from 0 pp…
Who is the assignee on this patent?
Fujifilm Business Innovation Corp
What technology area does this patent fall under?
Primary CPC classification C08L33/14. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Jul 20 2021 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).