Polylactic acid particles and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-11066527-B2
Application number	US-201816491726-A
Country	US
Kind code	B2
Filing date	Mar 9, 2018
Priority date	Mar 9, 2017
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

The present invention provides polylactic acid particles, which are formed in a continuous matrix phase from a polylactic acid resin and have a particle diameter of 1 to 100 μm. In a differential scanning calorimetry (DSC) curve of the polylactic acid particles, derived from the analysis by DSC using a temperature rise of 10° C./min, a peak of the cold crystallization temperature (Tcc) is shown at a temperature between the glass transition temperature (Tg) and the melting point (Tm). The polylactic acid particles have an aspect ratio of more than or equal to 1.00 and less than 1.05 and a roundness of 0.95 to 1.00. The polylactic acid particles have a flow time of 20 to 30 seconds.

First claim

The invention claimed is:

1. Polylactic acid particles which are formed into a continuous matrix phase from a polylactic acid resin and have a particle diameter of 1 to 100 μm,
wherein the polylactic acid particles have a flow time of 20 to 30 seconds.

2. The polylactic acid particles according to claim 1 , wherein the impurity content of the polylactic acid particles is 50 ppm or less.

3. The polylactic acid particles according to claim 1 , wherein the polylactic acid particles have a peak of cold crystallization temperature (T cc ) at a temperature between a glass transition temperature (T g ) and a melting point (T m ) in a differential scanning calorimetry (DSC) curve derived from temperature rise analysis of 10° C./min by the DSC.

4. The polylactic acid particles according to claim 1 , wherein the polylactic acid particles have an aspect ratio of 1.00 or more and less than 1.05, calculated by Formula 1 below, and a roundness of 0.95 to 1.00, calculated by Formula 2 below:
Aspect ratio=major axis/minor axis,  [Formula 1]

Roundness=4×area/(π×major axis{circumflex over ( )}2).  [Formula 2]

5. The polylactic acid particles according to claim 1 , wherein the polylactic acid particles have a compression degree of 10 to 15%, calculated by Formula 3 below:
Compression degree=(compressed bulk density−relaxed bulk density)/compressed bulk density×100.  [Formula 3]

6. The polylactic acid particles according to claim 5 , wherein the polylactic acid particles have a compressed bulk density of 0.525 to 0.6 g/cm 3 .

7. A method for manufacturing the polylactic acid particles of claim 1 comprising:
supplying a polylactic acid resin to an extruder and extruding the polylactic acid resin to form an extruded polylactic acid resin;
supplying the extruded polylactic acid resin and air to a nozzle, bringing the extruded polylactic acid resin into contact with the air to granulate the extruded polylactic acid resin, and then discharging granulated polylactic acid resins to form polylactic acid particles; and
supplying the discharged polylactic acid particles to a cooling unit to cool the polylactic acid particles, and then collecting the cooled polylactic acid particles,
wherein based on a cross section of the nozzle, the air is supplied to a center and an outer portion, and the extruded polylactic acid resin is supplied between the center and the outer portion, and
a ratio of cross-sectional areas of the air supplied to the outer portion and the extruded polylactic acid resin supplied between the central portion and the outer portion is 4:1 to 6:1 based on the cross section of the nozzle.

8. The method for manufacturing the polylactic acid particles according to claim 7 , wherein in the supplying the extruded polylactic acid resin and the air to the nozzle, the extruded polylactic acid resin supplied to the nozzle has a melt viscosity of 1 to 10 Pa·s.

9. The method for manufacturing the polylactic acid particles according to claim 7 , wherein an inside of the nozzle is maintained at 250 to 350° C.

10. The method for manufacturing the polylactic acid particles according to claim 9 , wherein a distal end of the nozzle is maintained at a temperature calculated by Formula 4 below:
Distal end temperature=glass transition temperature( T g )+(decomposition temperature( T d )−glass transition temperature( T g ))× A   [Formula 4]

wherein the glass transition temperature and the decomposition temperature are values for polylactic acid, and A is 0.5 to 1.5.

Assignees

• Lg Hausys Ltd

Inventors

• Kang Kyoung Min
• Kang Sung Yong
• Lee Hee-Jung
• Kim Min Gyung
• Park Chang-Young
• Lim Jae Ho
• Choi Jun Ho
• Song Jae Han
• Go Yu Jin

Classifications

• C08L75/04

  Polyurethanes · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08L23/12

  Polypropene · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C08L23/06

  Polyethylene · CPC title