Purification and liquefaction of biogas by combination of a crystallization system with a liquefaction exchanger

Patent metadata

Field	Value
Publication number	US-11066347-B2
Application number	US-202016840036-A
Country	US
Kind code	B2
Filing date	Apr 3, 2020
Priority date	Apr 4, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

Plant and process for the production of liquid methane from a feed gas stream comprising at least methane and carbon dioxide. A feed gas stream is injected into a CO 2 crystallizer in countercurrent fashion against a stream of predominantly liquid methane, thereby crystallizing amounts of carbon dioxide from the feed gas stream. Gaseous methane recovered from the CO 2 crystallizer is liquefied at a liquefaction exchanger.

First claim

The invention claimed is:

1. A process for production of liquid methane from biogas that comprises methane, water, and carbon dioxide, said process comprising the steps of:
condensing amounts of water from a biogas feed stream by lowering a temperature of the biogas feed gas stream in a condensing exchanger to a temperature of between −57° C. and −75° C.;
recovering a water-depleted feed gas stream from the condensing exchanger having a water content lower than that of the raw feed gas stream;
injecting the water-depleted feed gas stream into a bottom portion of a CO 2 crystallizer system;
feeding a stream predominantly comprising liquid methane into a top portion of the CO 2 crystallizer countercurrentwise to the injected feed gas stream, thereby crystallizing amounts of CO 2 contained in the injected water-depleted feed gas stream;
recovering gaseous methane from the upper portion of the CO 2 crystallizer;
liquefying the recovered gaseous methane with liquefaction exchanger, a cooling power of the liquefaction exchanger being supplied by a refrigerant;
recovering a stream of liquid methane at an outlet of the liquefaction exchanger; and
filtering solid CO 2 particles from the recovered stream of liquid methane to produce a CO 2 -depleted stream of liquid methane having a CO 2 content of between 2 ppm and 1000 ppm.

2. A plant for the production of liquid methane from a feed gas stream comprising at least methane and carbon dioxide, said plant comprising, in the direction of circulation of the gas stream:
a continuously operating system for the crystallization of carbon dioxide in which a stream predominantly comprising liquid methane is circulated countercurrentwise to the feed gas stream, thereby producing a methane-enriched gas stream; and
a liquefaction exchanger adapted and configured to liquefy the produced methane-enriched gas stream exiting from the crystallization system.

3. The plant of claim 2 , further comprising, upstream of the crystallization system, at least two heat exchangers adapted and configured to bring the feed gas stream to a temperature of between −50° C. and −85° C.

4. The plant of claim 3 , wherein the at least two exchangers are arranged in parallel and each following a cycle comprising a production stage and a regeneration stage, with, at each moment of the cycle, an exchanger in the production stage and an exchanger in the regeneration stage.

5. The plant of claim 3 , further comprising, upstream of the at least two heat exchangers a water condensation exchanger adapted and configured to bring the feed gas stream to a temperature of between 0° C. and 20° C.

6. The plant of claim 2 , further comprising:
a pipe connected to a bottom of the crystallization system; and
a filter disposed in the pipe adapted and configured to separate liquid and solid phases, thereby enabling recovery of CO 2 crystals.

7. A process for production of liquid methane from a feed gas stream that comprises methane and carbon dioxide using the plant of claim 2 , said process comprising the steps of:
continuous crystallization of carbon dioxide contained in the feed gas stream by injection of the feed gas stream into the continuously operating system for the crystallization of carbon dioxide in which a stream predominantly comprising liquid methane is circulated countercurrentwise to the feed gas stream;
recovering gaseous methane in an upper part of the continuously operating system for the crystallization of carbon dioxide;
liquefying the recovered gaseous methane with the liquefaction exchanger; and
recovering liquid methane at an outlet of the liquefaction exchanger.

8. The process of claim 7 , wherein the feed gas stream further comprises water and said process further comprises, before the crystallization stage, the steps of:
reducing a concentration of the water in the feed gas stream to produce a water-depleted feed stream by lowering a temperature of the feed gas stream to a temperature of between −57° C. and −75° C.; and
recovering the water-depleted feed gas stream.

9. The process of claim 8 , wherein the temperature of the feed gas stream is lowered in a first step during which the temperature of the feed gas stream is lowered to a temperature of between 0° C. and 10° C. and in a second step during which the temperature of the feed gas stream is lowered to a temperature of between −57° C. and −75° C.

10. The process of claim 7 , wherein, during said continuous crystallization, a ratio of a flow rate of the feed gas stream to a flow rate of the countercurrentwise liquid methane stream is such that solid CO 2 particles formed during said continuous crystallization are entrained towards the lower bottom of the continuously operating system for the crystallization of carbon dioxide.

11. The process of claim 9 , further comprising the steps of:
recovering a mixture of liquid methane and solid CO 2 particles at the lower bottom of the crystallization system; and
separating the solid CO 2 particles from the liquid methane in the recovered mixture, thereby producing a stream of recovered liquid methane downstream of said separation that has a carbon dioxide content of between 2 ppm and 1000 ppm.

12. The process of claim 11 , further comprising the step of recycling the stream of recovered liquid methane in the continuously operating system for the crystallization of carbon dioxide.

13. The process of claim 11 further comprising the step of recycling the stream of recovered liquid methane in the liquefaction exchanger.

14. The process of claim 11 , wherein the separated solid CO 2 particles are used to contribute cold to a cooling cycle of the liquefaction exchanger.

15. The process of claim 7 , wherein the stream of recovered liquid methane is partially returned to the continuously operating system for the crystallization of carbon dioxide.

16. The process of claim 7 , wherein the feed gas stream is biogas.

17. The process of claim 7 , wherein the feed gas stream is at a pressure of between atmospheric pressure and 20 bar.

Assignees

• Air Liquide

Inventors

• Trueba Antonio
• Tovar Ramos Jorge Ernesto
• Crayssac Frederic
• Valentin Solene
• Andrich Marine

Classifications

• Y02E50/30

  Fuel from waste, e.g. synthetic alcohol or diesel · CPC title

• Y02C20/40

  of CO2 · CPC title

• F25J1/0052

  by vaporising a liquid refrigerant stream · CPC title

• F25J2205/20

  using solidification of components · CPC title

• C10L2290/06

  Heat exchange, direct or indirect · CPC title