Processes for increasing an octane value of a gasoline component

Patent metadata

Field	Value
Publication number	US-11066345-B2
Application number	US-201916454526-A
Country	US
Kind code	B2
Filing date	Jun 27, 2019
Priority date	Jun 27, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

Processes for increasing an octane value of a gasoline component by dehydrogenating a stream comprising C7 hydrocarbons and methylcyclohexane in a first dehydrogenation zone to form an intermediate dehydrogenation effluent, and then dehydrogenating the intermediate dehydrogenation effluent in a second dehydrogenation zone to form a C7 dehydrogenation effluent. The C7 dehydrogenation effluent has an increased olefins content compared to an olefins content of the intermediate dehydrogenation effluent. The first dehydrogenation zone is operated under conditions to convert methylcyclohexane to toluene and minimize cracking reactions. The intermediate dehydrogenation effluent may be heated before being passed to the second dehydrogenation zone.

First claim

What is claimed is:

1. A process for increasing an octane value of a gasoline component, the process comprising:
separating a naphtha feed in a naphtha splitter into a stream comprising C6 and lighter boiling hydrocarbons, a C7 stream comprising C7 hydrocarbons including C7 paraffins and methylcyclohexane, and a heavy stream comprising C8 hydrocarbons;
dehydrogenating at least a portion of the stream comprising C7 hydrocarbons in a first dehydrogenation zone to form an intermediate dehydrogenation effluent comprising the C7 paraffins and toluene, the first dehydrogenation zone comprising a catalyst and operated under conditions to convert methylcyclohexane to toluene and minimize cracking reactions;
dehydrogenating the intermediate dehydrogenation effluent in a second dehydrogenation zone to form a C7 dehydrogenation effluent, the C7 dehydrogenation zone comprising a catalyst and the C7 dehydrogenation effluent comprising C7 olefins, wherein the C7 dehydrogenation effluent has an increased olefins content compared to an olefins content of the intermediate dehydrogenation effluent; and,
blending the C7 dehydrogenation effluent as a gasoline component in a gasoline pool.

2. The process of claim 1 further comprising:
heating the intermediate dehydrogenation effluent before dehydrogenating the intermediate dehydrogenation effluent in the second dehydrogenation zone.

3. The process of claim 1 wherein the first dehydrogenation zone has a lower inlet temperature than the second dehydrogenation zone.

4. The process of claim 1 wherein the first dehydrogenation zone is operated with an inlet temperature of between about 400 to 450° C. (752 to 842° F.) and the second dehydrogenation zone is operated with an inlet temperature of about 550° C. (1022° F.).

5. The process of claim 1 wherein the second dehydrogenation zone is operated to convert between 15 to 25 wt % of the C7 paraffins to olefins.

6. The process of claim 1 wherein the C7 dehydrogenation effluent comprises mono-olefins.

7. The process of claim 1 further comprising:
isomerizing the stream comprising C7 hydrocarbons, in an isomerization zone comprising a catalyst and operated under conditions to isomerize the C7 hydrocarbons, to provide a C7 isomerized effluent,
wherein the C7 isomerized effluent comprises the at least a portion of the stream comprising C7 hydrocarbons dehydrogenated in the first dehydrogenation zone.

8. The process of claim 1 wherein the catalyst in the first dehydrogenation zone and the catalyst in the second dehydrogenation zone are the same.

9. The process of claim 1 further comprising:
isomerizing at least a portion of the stream comprising C6 and lighter boiling hydrocarbons, in a C6 isomerization zone at isomerization conditions, to form a C6 isomerization effluent;
reforming the heavy stream, in a reforming zone under reforming conditions, to form a reformate stream; and,
blending the C6 isomerization effluent and the reformate stream with the C7 dehydrogenation effluent in the gasoline pool.

10. The process of claim 1 further comprising at least one of:
sensing at least one parameter of the process and generating a signal or data from the sensing;
generating and transmitting a signal; and
generating and transmitting data.

11. A process for increasing an octane value of a gasoline component, the process comprising:
separating a naphtha feed in a naphtha splitter into a stream comprising C6 and lighter boiling hydrocarbons, a C7 stream comprising C7 hydrocarbons including C7 paraffins and methylcyclohexane, and a heavy stream comprising C8 hydrocarbons;
isomerizing the stream comprising C7 hydrocarbons in an isomerization zone to provide a C7 isomerized effluent, the isomerization zone comprising a catalyst and operated under conditions to isomerize the C7 hydrocarbons;
dehydrogenating the C7 isomerized effluent in a first dehydrogenation zone to form an intermediate dehydrogenation effluent comprising the C7 paraffins and toluene, the first dehydrogenation zone comprising a catalyst and operated under conditions to convert methylcyclohexane to toluene and minimize cracking reactions;
dehydrogenating the intermediate dehydrogenation effluent in a second dehydrogenation zone to form a C7 dehydrogenation effluent, the second dehydrogenation zone comprising a catalyst and the C7 dehydrogenation effluent comprising C7 olefins, wherein the C7 dehydrogenation effluent has an increased olefins content compared to an olefins content of the intermediate dehydrogenation effluent; and,
blending the C7 dehydrogenation effluent as a gasoline component in a gasoline pool.

12. The process of claim 11 further comprising:
heating the intermediate dehydrogenation effluent before dehydrogenating the intermediate dehydrogenation effluent in the second dehydrogenation zone.

13. The process of claim 12 wherein the first dehydrogenation zone has a lower inlet temperature than the second dehydrogenation zone.

14. The process of claim 12 wherein the first dehydrogenation zone is operated with an inlet temperature of between about 400 to 450° C. (752 to 842° F.) and the second dehydrogenation zone is operated with an inlet temperature of about 550° C. (1022° F.).

15. The process of claim 12 wherein the second dehydrogenation zone is operated to covert between 15 to 25 wt % of the C7 paraffins to olefins.

16. The process of claim 12 wherein the C7 dehydrogenation effluent comprises mono-olefins.

17. The process of claim 12 wherein the catalyst in the first dehydrogenation zone and the catalyst in the second dehydrogenation zone are the same.

18. The process of claim 12 further comprising at least one of:
sensing at least one parameter of the process and generating a signal or data from the sensing;
generating and transmitting a signal; and
generating and transmitting data.

19. A process for increasing an octane value of a gasoline component, the process comprising:
separating a naphtha feed in a naphtha splitter into a stream comprising C6 and lighter boiling hydrocarbons, a C7 stream comprising C7 hydrocarbons including C7 paraffins and methylcyclohexane, and a heavy stream comprising C8 hydrocarbons;
isomerizing at least a portion of the stream comprising C6 and lighter boiling hydrocarbons, in a C6 isomerization zone at isomerization conditions, to form a C6 isomerization effluent;
isomerizing the stream comprising C7 hydrocarbons, in an isomerization zone comprising a catalyst and operated under conditions to isomerize the C7 hydrocarbons, to form a C7 isomerized effluent comprising isomerized C7 paraffins;
dehydrogenating the C7 isomerized effluent in a first dehydrogenation zone to form an intermediate dehydrogenation effluent comprising the isomerized C7 paraffins and toluene, the first dehydrogenation zone comprising a catalyst and operated under conditions to convert methylcyclohexane to toluene and minimize cracking reactions;
heating the intermediate dehydrogenation effluent and then dehydrogenating the intermediate dehydrogenation effluent in a second dehydrogenation zone to form a C7 dehydrogenation effluent, the second dehydrogenation zone comprising a catalyst, the C7 dehydrogenation effluent comprising C7 olefins, wherein the C7 dehydrogenation effluent has an increased olefins content compared to an olefins content of the intermediate dehydrogenation effluent;
reforming the heavy stream, in a reforming zone under reforming conditions, to form a reformate stream; and,
blending the C6 isomerization effluent, the C7 dehydrogen

Assignees

• Uop Llc

Inventors

• Penninger Michael W
• Lapinski Mark P
• Werba Gregory R
• Lafyatis David S

Classifications

• C10G2400/02

  Gasoline · CPC title

• C07C5/2206

  Catalytic processes not covered by C07C5/23 - C07C5/31 · CPC title

• C10L2270/023

  for gasoline engines · CPC title

• C10G59/02

  plural serial stages only · CPC title

• C10G2400/22

  Higher olefins · CPC title