Methods for removing anions from water

Patent metadata

Field	Value
Publication number	US-11066313-B1
Application number	US-202016961829-A
Country	US
Kind code	B1
Filing date	Feb 3, 2020
Priority date	Feb 1, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

Methods are disclosed for treating water containing a target anion to remove the target anion. The methods can include preparing a treatment composition solution that contains a metal treatment agent, adjusting the treatment composition solution to a first pH that is alkaline and then to a second pH that is acidic, and contacting the treatment composition solution with the water that contains the target anion.

First claim

The invention claimed is:

1. A method of treating water that contains a target anion, the method comprising:
providing a treatment composition solution containing a metal treatment agent;
increasing the pH of the treatment composition solution with a pH adjusting agent to a first pH that is greater than 8.3, and then decreasing the pH of the treatment composition solution to a second pH that is less than 4.5; and
contacting the treatment composition solution with the water that contains the target anion such that the target anion precipitates.

2. The method of claim 1 , wherein the metal treatment agent includes at least one selected from the group consisting of ferric salt, ferrous salt, stannous salt, and aluminum salt.

3. The method of claim 1 , wherein the treatment composition solution is contacted with the water that includes the target anion after the treatment composition solution is set to the first pH, and before the pH of the treatment composition solution is adjusted to the second pH.

4. The method of claim 1 , wherein the treatment composition solution is contacted with the water that includes the target anion after the pH of the treatment composition solution is adjusted to the second pH.

5. The method of claim 1 , wherein the treatment composition solution is contacted with the water that includes the target anion before the treatment composition solution is set to the first pH.

6. The method of claim 1 , wherein the step of adjusting the pH of the treatment composition solution to the second pH occurs within 72 hours of the step of setting the pH of the treatment composition solution to the first pH.

7. The method of claim 1 , wherein the first pH is in a range of from 8.5 to 10, and the second pH is in a range of from 2 to less than 4.5.

8. The method of claim 1 , wherein the target anion is at least one selected from the group consisting of a chromate, a molybdate, a thallium-containing anion, a mercury-containing anion, a zinc-containing anion, a copper-containing anion, and a selenium-containing anion.

9. The method of claim 1 , wherein the step of increasing the pH of the treatment composition solution includes adding the pH adjusting agent to the treatment composition solution.

10. A method of treating water that contains selenate, the method comprising:
providing a treatment composition solution containing a metal treatment agent;
increasing the pH of the treatment composition solution with a pH adjusting agent to a first pH that is in a range of from 8.3 to 10, and then decreasing the pH of the treatment composition solution to a second pH that is in a range of from 2 to 6; and
contacting the treatment composition solution with the water that contains selenate, and wherein the metal treatment agent reduces less than 5 wt. % of the selenate.

11. The method of claim 10 , wherein the method is effective to remove at least 85% of the selenate contained in the water.

12. The method of claim 10 , wherein the water includes at least 50 ppb selenate before it is treated.

13. The method of claim 10 , wherein the water includes less than 25 ppb selenate after it is treated.

14. The method of claim 10 , further comprising a step of precipitating, removing, or isolating sulfate ions that are present in the water.

15. The method of claim 10 , wherein the metal treatment agent includes at least one of ferric salt, aluminum salt, and stannic salt.

16. The method of claim 10 , wherein the metal treatment agent includes a ferric salt.

17. The method of claim 10 , wherein the metal treatment agent that is contacted with the water is provided in a weight ratio, relative to the amount of selenate, that is in a range of from 100:1 to 1,000:1.

18. A method of treating water that contains a multivalent target anion, the method comprising:
providing a treatment composition solution containing a metal treatment agent that is a soluble salt of a multivalent cation;
increasing the pH of the treatment composition solution with a pH adjusting agent so that the pH is in the range of 8.3 to 10 and causing at least 80 wt. % of the metal treatment agent to precipitate, and then controlling the pH of the treatment composition solution so that the pH is acidic and so that the precipitated metal treatment agent becomes sufficiently positively charged that the treatment composition solution exhibits a positive measured colloidal surface charge as measured by a Mütek™ PCD-04 Particle Charge Detector, and so that at least 80 wt. % of the metal treatment agent is maintained as a precipitate; and
contacting the treatment composition solution with the water that contains the multivalent target anion, and wherein the multivalent target anion adsorbs onto the positively charged precipitated metal treatment agent.

19. The method of claim 18 , wherein the pH of the treatment composition solution is controlled at the alkaline pH so that at least 95 wt. % of the metal treatment agent precipitates.

20. The method of claim 18 , wherein the pH of the treatment composition solution is controlled at the acidic pH so that at least 95 wt. % of the metal treatment agent is maintained as the precipitate.

21. The method of claim 18 , wherein the treatment composition solution is contacted with the water that contains the multivalent target anion (i) after the metal treatment agent precipitates, and before the precipitated metal treatment agent becomes sufficiently positively charged that the treatment composition solution exhibits the positive measured colloidal surface charge; (ii) after the precipitated metal treatment agent becomes sufficiently positively charged that the treatment composition solution exhibits the positive measured colloidal surface charge; or (iii) before the metal treatment agent precipitates.

Assignees

• Chemtreat Inc

Inventors

• Djukanovic Vladimir
• Seymour Nicholas
• Henderson William
• Weres Oleh

Classifications

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title

• B01J20/0229

  Compounds of Fe · CPC title

• B01J20/0251

  Compounds of Si, Ge, Sn, Pb (B01J20/10 takes precedence) · CPC title

• C02F2103/365

  from petrochemical industry (e.g. refineries) · CPC title

• B01J8/00

  Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes · CPC title