Preparation of metal diboride and boron-doped powders

Patent metadata

Field	Value
Publication number	US-11066308-B2
Application number	US-201916268224-A
Country	US
Kind code	B2
Filing date	Feb 5, 2019
Priority date	Feb 5, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A method for producing a metal boride powder includes producing a bonding gas stream from a first powder in a first fluidizing bed reactor, delivering the bonding gas stream to a second fluidized bed reactor through a conduit fluidly connecting the first and second fluidized bed reactors, fluidizing a second powder in the second fluidized bed reactor, mixing the second powder with the bonding gas stream such that a metal boride or boron-doped powder is formed.

First claim

The invention claimed is:

1. A method for producing a powder for use in high temperature ceramic applications, the method comprising:
producing a boriding gas stream from a first powder in a first fluidizing bed reactor;
delivering the boriding gas stream to a second fluidized bed reactor through a conduit fluidly connecting the first and second fluidized bed reactors, the second fluidized bed reactor containing a second powder selected from the group consisting of metal oxides, metal hydroxides, and alloys;
fluidizing the second powder in the second fluidized bed reactor; and
mixing the second powder with the boriding gas stream such that a metal boride powder or boron-doped powder is formed.

2. The method of claim 1 , and further comprising fluidizing the first powder in a first chamber of the fluidized bed reactor, wherein the first power comprises boron carbide.

3. The method of claim 2 , and further comprising fluidizing the first powder with an inert gas delivered to the first reactor.

4. The method of claim 2 , and further comprising heating the first chamber to a temperature ranging from approximately 600 to 1500 degrees Celsius to promote decomposition of the boron carbide and formation of the boriding gas stream.

5. The method of claim 4 , wherein the first powder has a particle size ranging from approximately 10 microns to 1.4 millimeters.

6. The method of claim 4 , and further comprising sampling a first exhaust gas from the first fluidized bed reactor to detect the formation of the boriding gas stream.

7. The method of claim 6 , and further comprising:
delivering the first exhaust gas to an exhaust vent thereby bypassing the second reactor when the presence of the boriding gas stream is not detected; and
delivering the first exhaust gas to the second reactor when the presence of the boriding gas stream is detected.

8. The method of claim 4 , and further comprising delivering a mixture of the boriding gas stream and an inert gas to the second fluidizing bed reactor to fluidize the second powder.

9. The method of claim 8 , and further comprising recycling the boriding gas stream from an exhaust outlet of the second fluidizing bed reactor to an inlet of the second fluidizing bed reactor.

10. The method of claim 8 , and further comprising heating a second chamber of the second fluidizing bed reactor to a temperature within the range of 500 to 850 degrees Celsius.

11. The method of claim 9 , and further comprising sampling an exhaust gas from the second fluidized bed reactor to detect a product formed in the reaction of the boriding gas stream and the second powder.

12. The method of claim 9 , and further comprising:
discontinuing supply of the boriding gas stream to the second fluidized bed reactor;
cooling the second fluidized bed reactor; and
purging the second fluidized bed reactor with an inert gas.

Assignees

• United Technologies Corp

Inventors

• Mcgee Randolph Carlton

Classifications

• C01B35/04 Primary

  Metal borides · CPC title

• C01P2006/32

  Thermal properties · CPC title

• C01P2006/40

  Electric properties · CPC title