Method of operating a syngas plant for a wide range of hydrogen and co co-production

Patent metadata

Field	Value
Publication number	US-11066300-B2
Application number	US-201916705531-A
Country	US
Kind code	B2
Filing date	Dec 6, 2019
Priority date	Dec 6, 2019
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A method for achieving a gas with a variable hydrogen to carbon monoxide ratio in a system including splitting a warm raw syngas stream into a first portion and a second portion, the second portioning having a portion flowrate. Sending the first portion of the warm raw syngas stream a carbon monoxide separator, thereby producing a first hydrogen enriched stream and a carbon monoxide rich stream. Sending the second portion of the warm raw syngas stream to a water/gas shift reactor, thereby producing a shifted syngas stream. Combining the first hydrogen enriched stream and the second hydrogen enriched stream and sending the combined stream to a hydrogen separator, thereby producing a product hydrogen stream having a hydrogen flowrate, and varying the hydrogen flowrate by increasing the portion flowrate.

First claim

What is claimed is:

1. A method for achieving a gas with a variable hydrogen to carbon monoxide ratio in a system comprising:
a warm raw syngas stream, a first syngas cooler,
a second syngas cooler,
a water/gas shift reactor,
an acid gas scrubber,
a temperature swing adsorber
a carbon monoxide separator, and
a hydrogen separator,

the method comprising:
splitting the warm raw syngas stream into a first portion and a second portion, the second portion having a hydrogen portion flowrate, and the warm raw syngas stream having a total syngas flow rate,
sending the first portion of the warm raw syngas stream to the first syngas cooler, then to the acid gas scrubber, temperature swing adsorber, and carbon monoxide separator, thereby producing a first hydrogen enriched stream and a carbon monoxide rich stream having a carbon monoxide portion flowrate,
sending the second portion of the warm raw syngas stream to the water/gas shift reactor, thereby producing a shifted syngas stream, then sending the shifted syngas stream to the second syngas cooler, thereby producing a second hydrogen enriched stream,
combining the first hydrogen enriched stream and the second hydrogen enriched stream and sending the combined stream to the hydrogen separator, thereby producing a product hydrogen stream having a hydrogen flowrate,
varying the hydrogen flowrate by varying the second portion flowrate, while maintaining a constant total syngas flow rate.

2. The method of claim 1 , further comprising:
removing at least a portion of the carbon monoxide rich stream,
varying the hydrogen flowrate by combining the carbon monoxide rich portion with the second portion of the warm raw syngas stream.

3. The method of claim 1 , wherein at a predetermined portion flowrate,
sending a portion of the shifted syngas stream to the first syngas cooler, thereby producing a cooled portion,
combining the cooled portion with the second hydrogen enriched stream, thereby producing a combined stream,
sending the combined stream to the hydrogen separator, thereby producing the product hydrogen stream having the hydrogen flowrate.

4. The method of claim 3 , wherein the predetermined flowrate is 100%.

Assignees

• Air Liquide

Inventors

• Poh Heon-Yong
• Roesch Alexander
• Stroffolino Iv Joseph T

Classifications

• C01B2203/0415

  Purification by absorption in liquids · CPC title

• C01B3/52 Primary

  by contacting with liquids; Regeneration of used liquids · CPC title

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• C01B2203/0872

  Methods of cooling · CPC title