Dye sublimation ink thermal inkjet printing method

Patent metadata

Field	Value
Publication number	US-11065871-B2
Application number	US-201716647868-A
Country	US
Kind code	B2
Filing date	Nov 8, 2017
Priority date	Nov 8, 2017
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A printing method includes selecting a dye sublimation ink, having: a disperse dye colorant dispersion; a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof; a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof; an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and a balance of water. An operating energy that includes a margin over a turn-on energy (TOE) for a thermal inkjet printhead is applied to a heating resistor of the printhead, wherein the margin ranges from about 10% to about 25% over the TOE. The dye sublimation ink is printed from the thermal inkjet printhead i) directly onto a textile substrate, or ii) onto a transfer medium to form an image thereon; and the image is transferred onto the textile substrate.

First claim

What is claimed is:

1. A printing method, comprising:
selecting a dye sublimation ink, including:
a disperse dye colorant dispersion;
a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof;
a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof;
an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and
a balance of water;

applying to a heating resistor of a thermal inkjet printhead an operating energy that includes a margin over a turn-on energy (TOE) for the printhead, wherein the margin ranges from about 10% to about 25% over the TOE; and
thermal inkjet printing, from the thermal inkjet printhead, the dye sublimation ink:
i) directly onto a textile substrate; or
ii) onto a transfer medium to form an image on the transfer medium; and
transferring the image from the transfer medium onto the textile substrate.

2. The printing method as defined in claim 1 wherein the thermal inkjet printing is performed using a jetting condition selected from the group consisting of:
a voltage ranging from about 18 V to about 30 V;
a pulse train ranging from about 1.3 μs to about 2.6 μs;
the operating energy ranging from about 0.9 μJ to about 1.1 μJ;
an ink chamber warming temperature within a range from about 35° C. to about 70° C.; and
combinations thereof.

3. The printing method as defined in claim 1 wherein the primary solvent is present in an amount ranging from about 10 wt% to about 22 wt% based on a total weight of the ink, and wherein the dye sublimation ink further includes a secondary solvent present in an amount ranging from 0 wt% to about 7 wt% based on the total The weight of the ink, wherein a disperse dye in the disperse dye colorant dispersion is more soluble in the secondary solvent than in the primary solvent.

4. The printing method as defined in claim 3 wherein the disperse dye colorant dispersion is present in an amount ranging from about 1 wt% actives to about 7 wt% actives based on a total weight of the ink.

5. The printing method as defined in claim 4 wherein the dye sublimation ink includes:
the chelating agent present in an amount greater than 0 wt% actives and less than 0.1 wt% actives based on the total weight of the ink; and
the surfactant, wherein the surfactant is oleth-3-phosphate present in an amount ranging from about 0.1 wt% to about 0.75 wt% based on the total weight of the ink.

6. The printing method as defined in claim 5 wherein the chelating agent is selected from the group consisting of methylglycinediacetic acid, trisodium salt; 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate; ethylenediaminetetraacetic acid; hexamethylenediamine tetra(methylene phosphonic acid), potassium salt; and combinations thereof.

7. The printing method as defined in claim 1 wherein the primary solvent includes a combination of glycerol and ethoxylated glycerol.

8. The printing method as defined in claim 7 wherein the glycerol is present in an amount ranging from about 12 wt% to about 16 wt% based on the total weight of the ink, and wherein the ethoxylated glycerol is present in an amount ranging from greater than 0 wt% to about 5 wt% based on the total weight of the ink.

9. The printing method as defined in claim 1 wherein the disperse dye colorant dispersion has i) a mean particle size ranging from about 50 nm to about 200 nm, and ii) from about 10 wt% dye solids to about 20 wt% dye solids and from about 4 wt% to about 7 wt% dispersant solids, based on a total weight of the colorant dispersion.

10. The printing method as defined in claim 1 wherein the disperse dye colorant dispersion is selected from the group consisting of a black disperse dye colorant dispersion, a cyan disperse dye colorant dispersion, a magenta disperse dye colorant dispersion, and a yellow disperse dye colorant dispersion.

11. The printing method as defined in claim 3 wherein the secondary solvent is selected from the group consisting of 1,2-propanediol, 1,3-propanediol, propylene glycol, 2-pyrrolidone, tetrahydrofuran, diethylene glycol, and combinations thereof.

12. A thermal inkjet printing method, comprising:
selecting a dye sublimation ink, including:
a disperse dye colorant dispersion;
a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof, wherein the primary solvent is present in an amount ranging from about 10 wt% to about 22 wt% based on a total weight of the ink;
a secondary solvent present in an amount ranging from 0 wt% to about 7 wt% based on the total weight of the ink;
a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof;
an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and
a balance of water;

applying to a heating resistor of a thermal inkjet printhead an operating energy that includes a margin over a turn-on energy (TOE) for the printhead, wherein the margin ranges from about 10% to about 20% over the TOE; and
thermal inkjet printing, from the thermal inkjet printhead, the dye sublimation ink:
i) directly onto a textile substrate; or
ii) onto a transfer medium to form an image on the transfer medium; and
transferring the image from the transfer medium onto the textile substrate.

13. The thermal inkjet printing method as defined in claim 12 wherein the thermal inkjet printing is performed using a jetting condition selected from the group consisting of:
a voltage ranging from about 18 V to about 30 V;
a pulse train ranging from about 1.3 μs to about 2.6 μs;
the operating energy ranging from about 0.9 μJ to about 1.06 μJ;
an ink chamber warming temperature within a range from about 35° C. to about 70° C.; and
combinations thereof.

14. A thermal inkjet printing system, comprising:
a thermal inkjet printhead, including:
a base substrate;
an other substrate defined on the base substrate, the other substrate having defined therein at least one ink feed opening and at least one ink chamber, wherein the at least one ink feed opening is in operative and fluid communication with the at least one ink chamber and with an ink channel to supply ink thereto;
a nozzle plate disposed on a portion of the other substrate, the nozzle plate having at least one orifice defined therein, the at least one orifice being in fluid communication with the at least one ink chamber; and
a heating resistor operatively disposed on the base substrate and proximate to, and operatively associated with the at least one ink chamber and the at least one orifice;

wherein the ink chamber contains a dye sublimation ink, including:
a disperse dye colorant dispersion;
a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof;
a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof;
an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and
a balance of water; and

a printhead controller, operatively connected to the heating resistor, to activate an electrical current to pass the electrical current through the heating resistor to apply an operating energy that includes a margin over a turn-on energy (TOE) for the printhe

Assignees

• Hewlett Packard Development Co

Inventors

• Doumaux Howard
• Krause Steven M
• Lindqvist Varna Jayne

Classifications

• B41J2/2107

  characterised by the ink properties (supplying ink in a solid state B41J2/17593) · CPC title

• D06P1/667

  Organo-phosphorus compounds · CPC title

• D06P5/30

  Ink jet printing · CPC title

• B41J2/04598

  Pre-pulse · CPC title

• D06P1/90

  using dyes dissolved in organic solvents or aqueous emulsions thereof {(D06P1/94 takes precedence)} · CPC title