Method for sintering metals, non-oxide ceramics and other oxidation-sensitive materials

Patent metadata

Field	Value
Publication number	US-11065686-B2
Application number	US-201816623809-A
Country	US
Kind code	B2
Filing date	Jun 8, 2018
Priority date	Jul 13, 2017
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A method for sintering metallic and/or non-oxide components includes completely encapsulating, in a metal halide salt, a green body comprising at least one metallic and/or non-oxide powder, and compressing the encapsulated green body so as to be gastight. The method further includes heating, together with a metal halide salt in the presence of oxygen up to sintering temperatures, the compressed, encapsulated green body. The method additionally includes at least partially dissolving, after cooling, the metal halide salt in a liquid so that the sintered component can be removed.

First claim

The invention claimed is:

1. A method for sintering metallic and/or non-oxide ceramic components, the method comprising:
completely encapsulating, in a metal halide salt, a green body comprising at least one metallic and/or non-oxide ceramic powder;
after the encapsulating the green body in the metal halide salt, compressing the encapsulated green body so as to be gastight;
adding the compressed, encapsulated green body directly to a molten metal halide salt bath:
heating, in the presence of oxygen up to sintering temperatures, the compressed, encapsulated green body in the molten metal halide salt bath; and
at least partially dissolving, after cooling, the metal halide salt in a liquid so that a sintered metallic and/or non-oxide ceramic component, formed from the green body, can be removed.

2. The method according to claim 1 , wherein the pressing is carried out uniaxially or cold-isostatically.

3. The method according to claim 1 , wherein the pressing and the encapsulation are carried out at temperatures up to a maximum of 200° C.

4. The method according to claim 1 , wherein the heating takes place at a temperature above a temperature at which the metal halide salt melts.

5. The method according to claim 1 , wherein the heating takes place up to a maximum temperature of 1400° C.

6. The method according to claim 1 , wherein at least one metal halide salt (NZ) is used, wherein N is at least one element from the group (Li, Na, K, Rb, Cs, Mg, Be, Ca, Ba) and Z is at least one element from the group (F, Cl, Br, I) or a mixture thereof.

7. The method according to claim 1 , wherein the liquid in which the metal halide salt is at least partially dissolved is water, an aqueous solution, or a short-chain alcohol.

8. A method for sintering metallic and/or non-oxide ceramic components, the method comprising:
completely encapsulating, in a metal halide salt, a green body comprising at least one metallic and/or non-oxide ceramic powder;
after the encapsulating the green body in the metal halide salt, compressing the encapsulated green body so as to be gastight;
arranging the compressed, encapsulated green body in a metal halide salt bath and then heating, in the presence of oxygen, the compressed, encapsulated green body together with the metal halide salt bath up to temperatures above the melting temperature of the metal halide salt and to sintering temperatures of the green body; and
at least partially dissolving, after cooling, the metal halide salt in a liquid so that a sintered metallic and/or non-oxide ceramic component, formed from the green body, can be removed.

9. The method according to claim 8 , wherein a molten silicate is applied to a surface of the metal halide salt bath.

10. The method according to claim 9 , wherein the molten silicate comprises a sodium silicate, lithium silicate, or potassium silicate.

11. The method according to claim 9 , wherein the heating takes place up to a maximum temperature of 1600° C.

12. The method according to claim 8 , wherein the pressing is carried out uniaxially or cold-isostatically.

13. The method according to claim 8 , wherein the pressing and the encapsulation are carried out at temperatures up to a maximum of 200° C.

14. The method according to claim 8 , wherein the pressing and the encapsulation are carried out at room temperature.

15. The method according to claim 8 , wherein the heating takes place at a temperature above a temperature at which the metal halide salt melts.

16. The method according to claim 8 , wherein the heating takes place up to a maximum temperature of 1400° C.

17. The method according to claim 8 , wherein the metal halide salt and the metal halide salt bath have the same chemical composition.

18. The method according to claim 17 , wherein the metal halide salt and the metal halide salt bath have the chemical composition (NZ), wherein N is at least one element from the group (Li, Na, K, Rb, Cs, Mg, Be, Ca, Ba) and Z is at least one element from the group (F, Cl, Br, I) or a mixture thereof.

19. The method according to claim 8 , wherein the liquid in which the metal halide salt is at least partially dissolved is water, an aqueous solution, or a short-chain alcohol.

20. The method according to claim 1 , wherein the metal halide salt bath is formed from the same chemical composition as the metal halide salt.

Assignees

• Forschungszentrum Juelich Gmbh

Inventors

• Dash Apurv
• Gonzalez Jesus
• Vassen Robert
• Guillon Olivier

Classifications

• B22F2301/205

  Titanium, zirconium or hafnium · CPC title

• C04B2235/3843

  Titanium carbides · CPC title

• C04B2235/608

  Green bodies or pre-forms with well-defined density · CPC title

• C04B35/5615

  based on titanium silicon carbides · CPC title

• C04B2235/6562

  Heating rate · CPC title