Catalyst for producing light aromatics with heavy aromatics, method for preparing the catalyst, and use thereof

Patent metadata

Field	Value
Publication number	US-11065604-B2
Application number	US-201816105293-A
Country	US
Kind code	B2
Filing date	Aug 20, 2018
Priority date	Aug 18, 2017
Publication date	Jul 20, 2021
Grant date	Jul 20, 2021

Abstract

A catalyst for producing light aromatics with heavy aromatics, a method for preparing the catalyst, and a use thereof are disclosed. The catalyst comprises a carrier, component ( 1 ), and component ( 2 ), wherein component ( 1 ) comprises one metal element or more metal elements selected from a group consisting of Pt, Pd, Ir, and Rh, and component ( 2 ) comprises one metal element or more metal elements selected from a group consisting of IA group, IIA group, IIIA group, IVA group, IB group, IIB group, IIIB group, IVB group, VB group, VIB group, VIIB group, La group, and VIII group other than Pt, Pd, Ir, and Rh. The catalyst can be used for producing light aromatics with heavy aromatics, whereby heavy aromatics hydrogenation selectivity and light aromatics yield can be improved.

First claim

The invention claimed is:

1. A catalyst, comprising a carrier, component I, and component II,
wherein component I comprises Pt and Pd, Pt and Ir, Pd and Ir, or a combination of Pt, Pd, and Ir, and component II comprises a combination of W and Mo, a combination of Cu and Zn, a combination of Ag and Zn, a combination of Fe and Ni, a combination of Mg and Sr, a combination of La and Ce, a combination of Ga and Sn, a combination of Zr and Nb, or a combination of Y and Sc, and
wherein the catalyst has a hydrogen desorption temperature higher than 350° C.

2. The catalyst according to claim 1 , wherein component I comprises Pt and Pd.

3. The catalyst according to claim 2 , wherein a weight ratio of Pt to Pd is in the range of 0.1:1 to 5:1.

4. The catalyst according to claim 1 , wherein:
in the combination of W and Mo, a weight ratio of W to Mo is in a range of 0.1:1 to 10:1,
in the combination of Cu and Zn, a weight ratio of Cu to Zn is in a range of 0.1:1 to 10:1,
in the combination of Ag and Zn, a weight ratio of Ag to Zn is in a range of 0.1:1 to 10:1,
in the combination of Fe and Ni, a weight ratio of Fe to Ni is in a range of 0.1:1 to 10:1,
in the combination of Mg and Sr, a weight ratio of Mg to Sr is in a range of 0.1:1 to 10:1,
in the combination of La and Ce, a weight ratio of La to Ce is in a range of 0.1:1 to 10:1,
in the combination of Ga and Sn, a weight ratio of Ga to Sn is in a range of 0.1:1 to 10:1,
in the combination of Zr and Nb, a weight ratio of Zr to Nb is in a range of 0.1:1 to 10:1, and
in the combination of Y and Sc, a weight ratio of Y to Sc is in a range of 0.1:1 to 10:1.

5. The catalyst according to claim 1 , wherein component I accounts for 0.02-3.0 wt % of the catalyst, and component II accounts for 0.01-15 wt % of the catalyst.

6. The catalyst according to claim 1 , wherein a weight ratio of component I to component II is in the range of 0.1:1 to 10:1.

7. The catalyst according to claim 1 , wherein the carrier is a non-acidic or weakly acidic porous carrier.

8. The catalyst according to claim 7 , wherein the carrier is an L acid additive modified carrier.

9. The catalyst according to claim 8 , wherein the L acid additive comprises a chloride-containing compound and a fluorine-containing compound.

10. The catalyst according to claim 9 , wherein the chloride-containing compound comprises at least one selected from a group consisting of AlCl 3 , CuCl 2 , FeCl 3 , SnCl 4 , TiCl 4 , and SbCl 5 , and the fluorine-containing compound comprises at least one selected from a group consisting of BF 3 , NbF 5 , SbF 5 , TaF 5 , and AsF 5 .

11. The catalyst according to claim 10 , wherein the L acid additive comprises AlCl 3 and NbF 5 .

12. The catalyst according to claim 9 , wherein a weight ratio of the chloride-containing compound to the fluorine-containing compound is in the range of 0.1:1 to 10:1.

13. The catalyst according to claim 8 , wherein the L acid additive accounts for 0.01-20 wt % of the catalyst.

14. The catalyst according to claim 8 , wherein the L acid additive comprises at a chloride-containing compound, a fluorine-containing compound, or both.

15. The catalyst according to claim 7 , wherein the carrier comprises at least one member selected from a group consisting of alumina, amorphous silica-alumina, kaolin, and aluminosilicate.

16. The catalyst according to claim 1 , wherein the catalyst has a hydrogen desorption temperature higher than 380° C.

17. A method for preparing the catalyst according to claim 1 , comprising:
step A), loading a salt containing component II into a carrier, and performing drying and calcination to obtain a catalyst precursor; and
step B), loading a salt containing component I into the catalyst precursor prepared in step A), and performing drying and calcination of the catalyst precursor loaded with the salt containing component I.

18. The method according to claim 17 , wherein in step A) and step B), the calcination is performed at a temperature ranging from 400° C. to 600° C.

19. The method according to claim 17 , wherein in step A), the salt containing component II is dissolved in water or an organic solvent, and is loaded into the carrier by precipitation, physical bonding, or dipping; and in step B), the salt containing component I is dissolved in water or an organic solvent, and is loaded into the catalyst precursor by precipitation, physical bonding, or dipping.

20. The catalyst according to claim 19 , wherein the organic solvent used in step A) or step B) is independently selected from the group consisting of alcohols, ketones and hydrocarbons.

21. The catalyst according to claim 19 , wherein the organic solvent used in step A) or step B) is independently selected from the group consisting of ethanol, acetone, cyclohexane, n-heptane, and toluene.

22. A method for producing light aromatics with heavy aromatics, comprising subjecting a raw material containing heavy aromatics to hydrogenation reaction in the presence of the catalyst according to claim 1 .

23. The method according to claim 22 , wherein a reaction temperature is in the range of 100° C. to 500° C., a reaction pressure is in the range of 0.5 MPa to 8.0 MPa, a molar ratio of hydrogen to heavy aromatics is in the range of 1 to 10; and a feed weight airspeed is in the range of 0.5 −1 to 20 −1 .

24. The method according to claim 22 , wherein the heavy aromatics are polycyclic aromatics comprising at least one compound selected from a group consisting of naphthalene, anthracene, phenanthrene, and homologues thereof.

Assignees

• China Petroleum & Chem Corp
• Shanghai Res Inst Petrochemical Tech Sinopec

Inventors

• Li Jingqiu
• Kong Dejin
• Li Huaying
• Yang Deqin
• Tong Weiyi
• Ding Jian
• Hou Min
• Chen Yan
• Chen Xuemei
• Wang Liangkai

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J35/51

  Spheres · CPC title

• C07C15/24

  containing two rings · CPC title

• C07C15/06

  Toluene · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title