Composite particle for electrode

Patent metadata

Field	Value
Publication number	US-11063253-B2
Application number	US-201816206812-A
Country	US
Kind code	B2
Filing date	Nov 30, 2018
Priority date	Nov 30, 2018
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A composite particle for electrode includes a carbon matrix, a plurality of active nanoparticles and a plurality of graphite particles. The active nanoparticles are randomly dispersed in the carbon matrix. Each of the active nanoparticles includes an active material and a protective layer. The protective layer covers the active material, and the protective layer is an oxide, a carbide or a nitride of the active material. The graphite particles are randomly dispersed in the carbon matrix. A volume fraction of the protective layer in each of the active nanoparticles is smaller than 23.0%.

First claim

What is claimed is:

1. A composite particle for electrode, comprising:
a carbon matrix;
a plurality of active nanoparticles randomly dispersed in the carbon matrix, each of the plurality of active nanoparticles comprising an active material and a protective layer, the protective layer covering the active material, wherein the protective layer is an oxide, a carbide or a nitride of the active material; and
a plurality of graphite particles randomly dispersed in the carbon matrix;
wherein a volume of all the active nanoparticles is V1, a volume of the carbon matrix is V2, and a volume of all the graphite particles is V3, the volume ratio is determined as V1:(V2+V3), and the volume ratio is 1:9 to 9:1, and a volume fraction of the protective layer in each of the plurality of active nanoparticles is equal to 10.0%.

2. The composite particle according to claim 1 , wherein an average particle size of the composite particle is from 500.0 nanometers (nm) to 40.0 micrometers (μm).

3. The composite particle according to claim 1 , wherein an average particle size of each of the plurality of active nanoparticles is from 1.0 nm to 500.0 nm.

4. The composite particle according to claim 1 , wherein an average particle size of each of the plurality of graphite particles is from 300.0 nm to 30.0 μm.

5. The composite particle according to claim 1 , wherein a thickness of the protective layer is equal to or smaller than 10.0 nm.

6. The composite particle according to claim 1 , wherein the active material is selected from the group consisting of group IVA elements, silver (Ag), zinc (Zn), aluminum (Al), arsenic (As), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), their metallic compounds, their alloys and combination thereof.

7. The composite particle according to claim 1 , wherein the plurality of active nanoparticles contact the carbon matrix without any gap therebetween.

8. The composite particle according to claim 1 , wherein the protective layer contacts the active material without any gap therebetween.

9. The composite particle according to claim 1 , wherein each of the plurality of active nanoparticles is in a shape of sphere.

10. A battery electrode, comprising the composite particle according to claim 1 .

11. A rechargeable battery, comprising:
a negative electrode comprising the composite particle according to claim 1 ;
a positive electrode; and
a separator disposed between the negative electrode and the positive electrode.

Assignees

• Univ Nat Cheng Kung

Inventors

• Liu Chuan Pu
• Cheng Yin Wei
• Wang Shih An
• Peng Bo Liang
• Chen Chun Hung

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/625 Primary

  Carbon or graphite · CPC title