System for producing dihydrogen, and associated method

Patent metadata

Field	Value
Publication number	US-11060196-B2
Application number	US-201615578197-A
Country	US
Kind code	B2
Filing date	Jun 2, 2016
Priority date	Jun 2, 2015
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

The invention concerns a system (1) for producing dihydrogen comprising: —a high-temperature electrolyser (2) suitable for implementing steam electrolysis at a temperature greater than 500° C. and producing a mixture of steam and dihydrogen; —a dihydrogen compressor (3); —a main water and dihydrogen circuit (10) on which at least an evaporator (11), the high-temperature electrolyser (2), a condenser (E3) and the compressor (3) are arranged in succession, a first heat exchanger (E1) bringing the steam from the evaporator (11) and the mixture of steam and dihydrogen from the high-temperature electrolyser (2) into heat exchange so as to superheat the steam from the evaporator (11); the system being characterised in that—the compressor (3) is a chemical compressor supplied with heat by heat exchange with the condenser (E3); —the condenser (E3) is disposed directly at the outlet of the first exchanger (E1).

First claim

The invention claimed is:

1. A dihydrogen production system ( 1 ) comprising:
a high temperature electrolyser ( 2 ) adapted to implement steam electrolysis at a temperature higher than 500° C. and produce a steam and dihydrogen mixture;
a dihydrogen compressor ( 3 );
a main water and dihydrogen circuit ( 10 ) on which at least one evaporator ( 11 ), the high temperature electrolyser ( 2 ), a condenser (E 3 ) and the compressor ( 3 ) are successively disposed, a first exchanger (E 1 ) operating heat exchange between the steam from the evaporator ( 11 ) and the steam and dihydrogen mixture from the high temperature electrolyser ( 2 ) so as to superheat the steam from the evaporator ( 11 );
the system being characterised in that
the compressor ( 3 ) is a chemical compressor supplied with heat by heat exchange with the condenser (E 3 );
the condenser (E 3 ) is directly disposed at an outlet of the first exchanger (E 1 ).

2. The system according to claim 1 , wherein the first exchanger (E 1 ) is configured such that the steam and dihydrogen mixture exhibits a temperature of at least 200° C. at the outlet.

3. The system according to one of claims 1 and 2 , further comprising a dioxygen circuit ( 21 ) from the high temperature electrolyser ( 2 ), on which a second exchanger (E 2 ) operating heat exchange between the steam from the evaporator ( 11 ) and the dioxygen from the high temperature electrolyser ( 2 ) is disposed so as to superheat the steam from the evaporator ( 11 ).

4. The system according to claim 3 , further comprising a third exchanger (E 4 ) operating heat exchange between the liquid water from the main circuit ( 10 ) upstream of the evaporator ( 11 ) and the dioxygen from the second exchanger (E 2 ) so as to preheat the liquid water entering the evaporator ( 11 ).

5. The system according to claim 1 , further comprising a first superheater ( 12 ) disposed on the main circuit ( 10 ) upstream of the high temperature electrolyser ( 2 ) so as to superheat the steam from the evaporator ( 11 ).

6. The system according to claim 1 , further comprising a fourth exchanger (E 5 ) operating heat exchange between the liquid water from the main circuit ( 10 ) upstream of the evaporator ( 11 ) and the dihydrogen exiting from the condenser (E 3 ) so as to preheat the liquid water entering the evaporator ( 11 ).

7. The system according to claim 6 , wherein the fourth exchanger (E 5 ) is a condenser.

8. The system according to claim 1 , wherein the main circuit ( 10 ) receives the condensates from the condenser (E 3 ).

9. The system according to claim 6 , wherein the main circuit ( 10 ) has a branch ( 14 ) for circulating the condensates from the condenser (E 3 ) and a mixer ( 15 ) for the liquid water mixture from the fourth exchanger (E 5 ) and said condensates.

10. The system according to claim 1 , wherein the chemical compressor ( 3 ) is a metal hydride compressor.

11. The system according to claim 10 , wherein said metal hydrides are rare earth hydrides.

12. The system according to claim 10 , wherein the chemical compressor ( 3 ) has a single reactor.

13. The system according to claim 1 , wherein a purification system ( 31 ) and/or a drying system ( 32 ) are disposed on the main circuit ( 10 ) between the condenser (E 3 ) and the compressor ( 3 ).

14. The system according to claim 1 , comprising a heat circuit ( 30 ) for heat transfer from the condenser (E 3 ) to the compressor ( 3 ).

15. The system according to claim 14 , wherein the fluid of the heat circuit ( 30 ) has a temperature of at least 120° C. at the inlet of the compressor ( 3 ).

16. The system according to claim 14 , wherein the heat circuit ( 30 ) has a second superheater ( 33 ) to superheat the fluid of the circuit ( 30 ) at the outlet of the condenser (E 3 ).

Assignees

• Electricite De France

Inventors

• Colomar David

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• Y02E60/32

  Hydrogen storage · CPC title

• C25B15/02

  Process control or regulation · CPC title

• C25B9/05 Primary

  Pressure cells · CPC title