Method for purifying a gas rich in hydrocarbons

Patent metadata

Field	Value
Publication number	US-11060037-B2
Application number	US-201615746456-A
Country	US
Kind code	B2
Filing date	Jul 12, 2016
Priority date	Jul 23, 2015
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A process for the purification of a gas rich in hydrocarbons and comprising at least 10 ppm by volume of hydrocarbons having at least six carbon atoms nitrogen.

First claim

The invention claimed is:

1. A process for the purification of a gas comprising hydrocarbons and comprising at least 10 ppm by volume of hydrocarbons having at least six carbon atoms, the process comprising the following stages:
Stage a) cooling the gas to a temperature of between −20° C. and −60° C. by heat exchange with at least one coolant in a heat exchanger;
Stage b) purifying from compounds containing at least six carbon atoms of the gas partially liquefied in stage a) in a washing column containing a column top at a highest end and a column vessel at the lowest end, thus forming at the column top, a gas stream containing less than 5 ppm by volume of compounds containing at least six carbon atoms and, at the column vessel, a liquid stream enriched in compounds containing at least six carbon atoms;
Stage c) condensing the gas stream resulting from stage b) in a heat exchanger, thus forming a two-phase stream;
Stage d) separating the two-phase stream resulting from stage c) in a phase-separating pot at a temperature of between −60° C. and −80° C., thus forming a gas stream at the pot top and a liquid stream at the pot vessel;
Stage e) introducing the liquid stream resulting from stage d) into the washing column as washing column top reflux;
Stage f) condensing the gas stream resulting from stage d) by heat exchange in a heat exchanger at a temperature of less than −100° C., thus forming a liquefied gas containing less than 5 ppm by volume of compounds containing at least six carbon atoms.

2. The process of claim 1 , wherein the gas rich in hydrocarbons is natural gas.

3. The process of claim 1 , wherein the hydrocarbons having at least six carbon atoms comprise a predominance of benzene.

4. The process of claim 1 , wherein the coolant is a mixed coolant comprising nitrogen, methane, ethane and butane.

5. The process of claim 1 , wherein at least a portion of the liquid stream formed during stage f) is tapped at a temperature of less than −100° C. and then recycled in the phase-separating pot employed in stage d).

6. The process of claim 1 , wherein the liquid stream formed at the vessel of the phase-separating pot in stage d) is pumped using at least one pump in order to feed the top of the washing column employed in stage b).

7. The process of claim 1 , wherein the at least one coolant is used to cool the gas in stage a) and to condense the gas in stage f).

Assignees

• Air Liquide

Inventors

• Chambron Nicolas
• Costa De Beauregard Pierre
• Paradowski Henri

Classifications

• F25J1/0212

  as a single flow MCR cycle · CPC title

• F25J2220/60

  Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons · CPC title

• F25J2270/18

  External refrigeration with incorporated cascade loop · CPC title

• F25J1/0022

  Hydrocarbons, e.g. natural gas · CPC title

• C10G5/06 Primary

  by cooling or compressing · CPC title