In situ bonding of carbon fibers and nanotubes to polymer matrices

Patent metadata

Field	Value
Publication number	US-11059945-B2
Application number	US-201716319692-A
Country	US
Kind code	B2
Filing date	Jul 21, 2017
Priority date	Jul 22, 2016
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A method for forming a carbon fiber-reinforced polymer matrix composite by distributing carbon fibers or nanotubes into a molten polymer phase comprising one or more molten polymers; and applying a succession of shear strain events to the molten polymer phase so that the molten polymer phase breaks the carbon fibers successively with each event, producing reactive edges on the broken carbon fibers that react with and cross-link the one or more polymers. The composite shows improvements in mechanical properties, such as stiffness, strength and impact energy absorption.

First claim

What is claimed is:

1. A method for forming a carbon fiber-reinforced polymer matrix composite, comprising:
(a) distributing carbon fibers into a molten carbon-containing polymer phase comprising one or more molten carbon-containing polymers;
(b) breaking or cutting the carbon fibers in the presence of the molten carbon-containing polymer phase by
(i) applying a succession of shear strain events to the molten carbon-containing polymer phase so that the molten carbon-containing polymer phase breaks the carbon fibers, or
(ii) mechanically breaking or cutting the carbon fibers in the presence of the molten carbon-containing polymer phase,
thereby producing new fiber ends on the carbon fibers comprising free radicals that react with and directly cross-link by covalent bonding the one or more carbon-containing polymers; and

(c) thoroughly mixing the broken or cut carbon fibers with the molten carbon-containing polymer phase,
wherein the carbon fibers are selected from the group consisting of single-walled carbon nanotubes, multi-walled carbon nanotubes, carbon nanofibers, and micron-sized carbon fibers.

2. The method of claim 1 , wherein at least one of the one or more carbon-containing polymers contains one or more double bonds or one or more tertiary carbons.

3. The method of claim 1 , wherein the molten carbon-containing polymer phase comprises a nylon.

4. The method of claim 3 , wherein the nylon is nylon 66.

5. The method of claim 1 , wherein graphite microparticles are distributed into the molten carbon-containing polymer phase and mechanically exfoliated in addition to the carbon fibers.

6. A method for forming a high-strength carbon fiber-reinforced polymer matrix composite, comprising:
(a) forming the composite of claim 1 into cross-linked polymer particles; and
(b) distributing the cross-linked polymer particles into a non-cross-linked molten host matrix polymer.

7. A carbon fiber-reinforced polymer matrix composite prepared according to the method of claim 1 , consisting essentially of carbon fibers distributed into a molten carbon-containing polymer phase comprising one or more molten carbon-containing polymers, wherein said polymers are cross-linked by direct covalent bonds to the ends of said carbon fibers, and said composite optionally further includes mechanically exfoliated graphene distributed therein.

8. The carbon fiber-reinforced polymer matrix composite of claim 7 , wherein the polymer is nylon 66.

9. A high strength carbon fiber-reinforced polymer matrix composite prepared according to the method of claim 6 , wherein the cross-linked polymer particles consist essentially of carbon fibers distributed into a carbon-containing polymer phase comprising one or more carbon-containing polymers, wherein said polymers are cross-linked by direct covalent bonds to the ends of said carbon fibers, and said composite optionally further includes mechanically exfoliated graphene distributed therein.

10. The method of claim 1 or 6 , wherein the composite shows improved stiffness and strength versus a composite lacking covalent bonding between carbon fibers and polymer.

11. The method of claim 1 or 6 , wherein the composite shows improved impact energy absorption versus a composite lacking covalent bonding between carbon fibers and polymer.

12. The carbon fiber-reinforced polymer matrix composite of any one of claims 6 to 9 , wherein the composite shows improved stiffness and strength versus a composite lacking covalent bonding between carbon fibers and polymer.

13. The carbon fiber-reinforced polymer matrix composite of any one of claims 7 to 9 , wherein the composite shows improved impact energy absorption versus a composite lacking covalent bonding between carbon fibers and polymer.

14. A polymer composite consisting essentially of polymer chains inter-molecularly and directly cross-linked by broken carbon fibers, wherein said polymer-fiber cross-links consist essentially of direct covalent bonds to the ends of said carbon fibers, and said composite optionally further includes mechanically exfoliated graphene distributed therein.

15. An automotive, aircraft or aerospace part formed from the composite of claim 14 .

16. The part of claim 15 , wherein the part is an engine part.

17. Carbon fiber cross-linked polymer particles formed from the composite of claim 14 .

18. A polymer composition comprising a host thermoplastic polymer and the carbon fiber cross-linked polymer particles of claim 17 dispersed therein.

19. An automotive, aircraft or aerospace part formed from the polymer composition of claim 18 .

20. The method of claim 1 , wherein the breaking of carbon fibers occurs through high shear melt processing.

21. The method of claim 1 , wherein the polymer is selected from the group consisting of polyetherketones (PEK), polyphenylene sulfides (PPS), polyethylene sulfide (PES), polyetherimides (PEI), polyvinylidene fluoride (PVDF), polysulfones (PSU), polycarbonates (PC), polyphenylene ethers, aromatic thermoplastic polyesters, aromatic polysulfones, thermoplastic polyimides, liquid crystal polymers, thermosplastic elastomers, polyethylene, polypropylene, polystyrene (PS), acrylics, ultra-high-molecular-weight polyethylene (UHMWPE), polytetrafluoroethylene (PTFE/Teflon®), polyamides (PA), polyphenylene oxide (PPO), polyoxy methylene plastic (POM/Acetal), polyarylether-ketones, polyvinylchloride (PVC), and mixtures thereof.

Assignees

• Univ Rutgers

Inventors

• Nosker Thomas
• Lynch Jennifer K
• Kear Bernard
• Whieb Nofel

Classifications

• H01B1/24 Primary

  the conductive material comprising carbon-silicon compounds, carbon or silicon · CPC title

• C08K3/046

  Carbon nanorods, nanowires, nanoplatelets or nanofibres · CPC title

• C08J2371/00

  Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers · CPC title

• C08J3/201

  Pre-melted polymers · CPC title

• C09K5/14

  Solid materials, e.g. powdery or granular · CPC title