Polymer production method

Patent metadata

Field	Value
Publication number	US-11059912-B2
Application number	US-201716075283-A
Country	US
Kind code	B2
Filing date	Feb 3, 2017
Priority date	Feb 4, 2016
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A polymer production method whereby: a flow reactor comprising a flow path wherein a plurality of liquids can be mixed is used; and a monomer is anionically polymerized in the presence of an initiator. The flow reactor comprises a mixer for mixing two liquids, said mixer comprising either a joint member having a double pipe therein or a static mixer member.

First claim

The invention claimed is:

1. A polymer production method comprising the step of anionically polymerizing a monomer in the presence of an initiator by using a flow reactor having a flow channel capable of mixing a plurality of liquids,
wherein the flow reactor is equipped with a mixer for mixing two liquids, and
the mixer for mixing two liquids comprises a joint member having a double tube at the interior and a static mixer member.

2. The polymer production method of claim 1 ,
the static mixer member comprises a tubular body and an element body inserted at the interior of the tubular body; and
the joint member and the static mixer member are connected in such manner that a double tube side end face of the tubular body is in touching contact with a static mixer member side end face of the double tube.

3. The polymer production method of claim 2 , wherein the static mixer member side end of the double tube is situated at the interior of the joint member.

4. The polymer production method of claim 1 , wherein the joint member has an insertion hole for inserting an inner tube through which flows an initiator solution and, in the inner tube-inserted state, the double tube is formed of, at least near a tip of the inner tube, the inner side of the inner tube and the space defined by an outer wall of the inner tube and an inner wall of the insertion hole.

5. The polymer production method of claim 4 , wherein the joint member has a feed port for introducing a monomer solution, which feed port is connected to the insertion hole.

6. The polymer production method of claim 5 , wherein the insertion hole is formed so as to have, in the vicinity of a connecting portion with the feed port, a diameter that is substantially the same as the inner tube outside diameter, and moreover is formed so as to have, from the place of connection to a tip of the inner tube, a diameter that is larger than the inner tube outside diameter.

7. The polymer production method of claim 4 , wherein the joint member has a hole for connecting to the static mixer member and the feed port is connected to said connecting hole.

8. The polymer production method of claim 1 , wherein the monomer is an aromatic vinyl compound.

9. The polymer production method of claim 1 , wherein the initiator is an alkyllithium.

10. The polymer production method of claim 1 , wherein the polymer has a dispersity of 1.5 or less.

11. A polymer production method comprising the step of anionically polymerizing a monomer in the presence of an initiator by using a flow reactor having a flow channel capable of mixing a plurality of liquids,
wherein the static mixer member comprises a tubular body and an element body inserted at the interior of the tubular body, and
the element body is inserted into the interior of the tubular body in such manner that one end of the element body is substantially flush with the double tube side end face of the tubular body.

12. The polymer production method of claim 11 , wherein the element body has a shape in which a plurality of right-handed twist blades and left-handed twist blades mutually overlap in a twist axis direction.

Assignees

• Nissan Chemical Corp

Inventors

• Tadokoro Shinsuke
• Kozawa Masami

Classifications

• C08F297/02 Primary

  using a catalyst of the anionic type · CPC title

• C08F12/22

  Oxygen · CPC title

• C08F12/08

  Styrene · CPC title

• B01F35/711

  for feeding a mixture of components, i.e. solids in liquid, solids in a gas stream · CPC title

• B01F25/105

  Mixing heads, i.e. compact mixing units or modules, using mixing valves for feeding and mixing at least two components · CPC title