Rare earth cold accumulating material particles, and refrigerator, superconducting magnet, inspection device and cryopump using same

Patent metadata

Field	Value
Publication number	US-11059725-B2
Application number	US-201816182893-A
Country	US
Kind code	B2
Filing date	Nov 7, 2018
Priority date	Sep 25, 2014
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

The present invention provides a rare earth cold accumulating material particle comprising a rare earth oxide or a rare earth oxysulfide, wherein the rare earth cold accumulating material particle is composed of a sintered body; an average crystal grain size of the sintered body is 0.5 to 5 μm; a porosity of the sintered body is 10 to 50 vol. %; and an average pore size of the sintered body is 0.3 to 3 μm. Further, it is preferable that the porosity of the rare earth cold accumulating material particle is 20 to 45 vol. %, and a maximum pore size of the rare earth cold accumulating material particle is 4 m or less. Due to this structure, there can be provided a rare earth cold accumulating material having a high refrigerating capacity and a high strength.

First claim

The invention claimed is:

1. A method for producing a rare earth cold accumulating material particle comprising the steps of:
preparing a rare earth compound powder to be a starting material for the rare earth cold accumulating material particle;
molding the rare earth compound powder as the starting material thereby to obtain a spherically molded body; and
sintering the spherically molded body at a temperature in a range of 1200° C. to 2000° C. to thereby produce a spherical rare earth cold accumulating material particle consisting essentially of a rare earth oxide or a rare earth oxysulfide;
wherein the rare earth cold accumulating material particle is a sintered body;
wherein an average crystal grain size of the sintered body is 0.5 to 5 μm;
wherein a porosity of the sintered body is 10 to 50 vol %;
wherein an average pore size of the sintered body is 0.3 to 3 μm; and
wherein in an arbitrary cross section of the rare earth cold accumulating material particle, a number of pores per a unit area of 10 μm×10 μm is 20 to 70.

2. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein the starting material is formed of a gadolinium oxysulfide (Gd 2 O 2 S) or a gadolinium aluminum oxide (GdAlO 3 ).

3. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein the rare earth compound powder to be used as the starting material has an average particle size of 0.3 to 5 μm.

4. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a sintering aid powder is added to the rare earth compound powder, and a content of the sintering aid powder is set to be 1 part by mass or more and 20 parts by mass or less in relation to 100 parts by mass of the rare earth compound powder.

5. The method for producing a rare earth cold accumulating material particle according to claim 4 , wherein when an average particle size of the sintering aid powder is represented by A (μm), and an average particle size of the rare earth compound powder is represented by B (μm), B/A is regulated so as to fall within a range from 0.7 to 1. 3.

6. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a resin binder is added to the rare earth compound powder so as for the addition amount of the resin binder to be 10 to 50 vol % in relation to 100 vol % of the total amount of the rare earth compound powder and the resin binder.

7. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein the molding step is performed in accordance with at least one method of a tumbling granulation and a die molding.

8. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein an average particle size of the spherically molded body falls within a range from 100 to 500 μm.

9. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a sintering temperature is set to be 1500° C. or higher.

10. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a sintering time is set to 1 hour or more and 48 hours or less.

11. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a rare earth oxide sintered body is subjected to a heat treatment in an oxygen atmosphere.

12. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a rare earth oxysulfide sintered body is subjected to a heat treatment in a sulfur atmosphere including a sulfur oxide.

13. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a surface polishing process is performed to the spherical rare earth cold accumulating material particle.

14. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein a spherical sintered body of the rare earth cold accumulating material particle is subjected to a shape classification.

15. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein the spherical sintered body is subjected to a shape classification so as to select spherical sintered body having an aspect ratio of 2 or less.

16. The method for producing a rare earth cold accumulating material particle according to claim 1 , wherein the shape classification is performed in such a manner that when L represents a perimeter length of a projection image of each of the cold accumulating material particles constituting a group of rare earth cold accumulating material particles composed of the rare earth cold accumulating particles, and A represents the actual area of the projection image, in the group of rare earth cold accumulating material particles, a proportion of the rare earth cold accumulating material particles having a shape factor R being represented by L 2 /4πA and exceeding 1.5 is 5% or less.

Assignees

• Toshiba Kk
• Toshiba Materials Co Ltd

Inventors

• Yamada Katsuhiko
• Fuse Keiichi

Classifications

• H01F6/04

  Cooling · CPC title

• F25B9/14 Primary

  characterised by the cycle used, e.g. Stirling cycle · CPC title

• C01F17/294 Primary

  Oxysulfides · CPC title

• F04B37/08

  by condensing or freezing, e.g. cryogenic pumps · CPC title

• C01F17/206

  oxide or hydroxide being the only anion · CPC title