Method of preparing low-dust and high-insulation aerogel blanket

Patent metadata

Field	Value
Publication number	US-11059262-B2
Application number	US-201715576264-A
Country	US
Kind code	B2
Filing date	Feb 3, 2017
Priority date	Mar 28, 2016
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

The present invention relates to a method of preparing an aerogel blanket in which, a surface of a base material for a blanket is activated and roughness and porosity of the surface of the base material for a blanket are increased to increase adhesion performance of a silica aerogel by inducing etching of a surface of a base material for a blanket using an acidic solution, and mechanical flexibility is increased and the generation of dust is minimized by further performing a gel deformation process of introducing cracks into the aerogel, and a low-dust and high-insulation aerogel blanket prepared according to the present invention.

First claim

The invention claimed is:

1. A method of preparing an aerogel blanket, comprising:
a) preparing a base material for a blanket which is surface-treated with an acidic solution;
b) preparing a silica sol including a water glass solution containing silica in an amount of 5.2 wt % to 20 wt %;
c) impregnating the surface-treated base material for a blanket with the silica sol by immersing the surface-treated base material for a blanket in the silica sol in a reaction container containing the silica sol followed by pressing to a target thickness to remove an excess of silica sol;
d) gelling the silica sol in a state in which the base material for a blanket is impregnated with the silica sol by treating with acetic acid as an acidic catalyst to induce gelation, wherein a molar ratio of the acid catalyst with respect to silicon dioxide in the water glass solution is in the range of 1 to 5;
e) aging the base material impregnated with the gelled silica sol of step d) in the presence of a solution comprising an organic solvent and a basic catalyst selected from the group consisting of sodium hydroxide, potassium hydroxide, trimethylamine, and pyridine at a temperature of 30° C. to 70° C. for 1 to 10 hours;
f) performing a gel deformation process of introducing cracks into the gel;
g) performing a solvent replacement by washing with a monohydric alcohol-based solvent having 1 to 6 carbon atoms;
h) surface-modifying the gel of g) by mixing with a surface modifier comprising a polar solvent and an organosilane compound in a volume ratio of 1 to 10 with respect to the gel for 5 to 6 hours, wherein the polar solvent comprises methanol, ethanol, or isopropyl alcohol, and the organosilane compound comprises trimethylchlorosilane (TMCS), hexamethyldisilazane (HMDS), methyltrimethoxysilane, trimethylethoxysilane, ethyltriethoxysilane, or phenyltriethoxysilane;
i) washing with a nonpolar organic solvent for 2 to 3 hours; and
j) drying at a temperature of 70° C. to 200° C. and a pressure of 1±0.3 atm for 1 hour,
wherein the base material for a blanket is a glass fiber,
wherein the acidic solution in Step a) includes acetic acid (CH 3 COOH), and
wherein the gel deformation process is performed by winding the base material for a blanket impregnated with the silica gel around a cylinder once such that one side comes in contact with the cylinder, and another step of winding once such that another side comes in contact with the cylinder, and the process is repeated once or more after the base material for a blanket is rotated by 90°.

2. The method according to claim 1 , wherein the cylinder has a diameter in a range of 2 to 10 cm.

Assignees

• Lg Chemical Ltd

Inventors

• Oh Kyoung Shil
• Lee Je Kyun
• Bae Dong Sik
• Son Jeong Hun

Classifications

• B01J13/0091 Primary

  Preparation of aerogels, e.g. xerogels · CPC title

• C04B2201/32

  for the thermal conductivity, e.g. K-factors · CPC title

• C04B35/82

  Asbestos; Glass; Fused silica · CPC title

• C04B2235/3427

  Silicates other than clay, e.g. water glass · CPC title

• C04B28/24

  containing alkyl, ammonium or metal silicates; containing silica sols {(reaction mixtures resulting in mineral polymers C04B28/006; polymeric reaction products of alkali metal silicates with isocyanates C08G18/3895)} · CPC title