Compositions for capstock applications

Patent metadata

Field	Value
Publication number	US-11059234-B2
Application number	US-201816171991-A
Country	US
Kind code	B2
Filing date	Oct 26, 2018
Priority date	Sep 12, 2014
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A thermoplastic polymer alloy compositions including a blend of polymers that each contribute beneficial properties to the compositions. The compositions exhibit characteristics desirable for outdoor applications such as weatherability, impact resistance and durability, while offering excellent surface appearance. The compositions are particularly suitable for decking applications and as capstock materials.

First claim

What is claimed is:

1. A thermoplastic composition for capstock, consisting of:
a single halogenated polymer consisting of a polyvinyl chloride polymer in an amount from about 20 to about 40 parts by weight based on 100 total parts by weight of the composition;
an aliphatic thermoplastic polyurethane polymer derived from at least a polyether polyol and a polyisocyanate, the thermoplastic polyurethane polymer present in an amount from about 1 to about 40 parts by weight based on 100 total parts by weight of the composition;
a polyacrylate-styrene-acrylonitrile copolymer in an amount from about 15 to about 35 parts by weight of the composition, wherein acrylate content is from about 30 to about 60 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, wherein the styrene content is from about 25 to about 40 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, wherein the acrylonitrile content is from about 5 to about 30 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer;
a styrene acrylonitrile copolymer in an amount from about 10 to about 40 parts by weigh based on 100 total parts by weight of the composition, wherein the styrene acrylonitrile copolymer has an acrylonitrile content of about 10 to about 50 parts by weight and a styrene content of about 50 to about 90 parts by weight based on 100 parts by weight of the styrene acrylonitrile copolymer; and
optionally, one or more of a colorant, pigment, lubricant, UV stabilizer, light stabilizer, thermal stabilizer, antioxidant, antistatic agent, flame retardant, filler, fiber, processing aid, biocide, surfactant, blowing agent, foaming agent, and wax; and
optionally a mixture of a cross-linked acrylonitrile-styrene copolymer and polystyrene including the polystyrene in an amount of 20 to 30 weight percent and acrylonitrile-styrene copolymer in an amount of about 70 to 80 weight percent based on the total weight of the mixture, the mixture present in an amount from 0.5 to about 2.5 parts by weight based on 100 total parts of the composition; and
optionally an additional styrene-acrylonitrile copolymer having a weight average molecular weight greater than 1 million as measured by gel permeation chromatography utilizing a suitable solvent in compared against polystyrene standards in an amount from 0.1 to about 10 parts by weight based on 100 total parts by weight of the composition.

2. The composition according to claim 1 , wherein the polyacrylate-styrene-acrylonitrile copolymer is a graft copolymer of a styrene acrylonitrile copolymer grafted to a polyacrylate.

3. The composition according to claim 1 , wherein the polyacrylate-styrene-acrylonitrile copolymer is a graft copolymer of a styrene acrylonitrile copolymer grafted to a polybutylacrylate.

4. The composition according to claim 3 , wherein the styrene content is from about 25 to about 30 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, and wherein the acrylonitrile content is from about 10 to about 20 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer.

5. The composition according to claim 2 , wherein the polyvinyl chloride polymer is present in an amount from about 25 to about 35 parts by weight based on 100 total parts by weight of the composition, wherein the polyurethane is present in an amount from about 1 to about 25 parts by weight based on 100 total parts by weight of the composition.

6. The composition according to claim 5 , wherein the styrene acrylonitrile copolymer is present in an amount from about 10 to 30 parts by weight based on 100 total parts by weight of the composition.

7. The composition according to claim 1 , wherein the composition includes the mixture of a cross-linked acrylonitrile-styrene copolymer and polystyrene including the polystyrene in an amount of 20 to 30 weight percent and acrylonitrile-styrene copolymer in an amount of about 70 to 80 weight percent based on the total weight of the mixture, the mixture present in an amount from 0.5 to about 2.5 parts by weight based on 100 total parts of the composition.

8. The composition according to claim 7 , wherein the composition includes the additional styrene-acrylonitrile copolymer having a weight average molecular weight greater than 1 million as measured by gel permeation chromatography utilizing a suitable solvent in compared against polystyrene standards in an amount from 0.1 to about 10 parts by weight based on 100 total parts by weight of the composition.

9. A thermoplastic composition for capstock, consisting of:
a single halogenated polymer consisting of a polyvinyl chloride polymer in an amount from about 20 to about 60 parts by weight based on 100 total parts by weight of the composition;
an aliphatic thermoplastic polyurethane polymer present in an amount from about 1 to about 40 parts by weight based on 100 total parts by weight of the composition;
a polyacrylate-styrene-acrylonitrile copolymer in an amount from about 15 to about 35 parts by weight of the composition, wherein acrylate content is from about 30 to about 60 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, wherein the styrene content is from about 25 to about 40 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, wherein the acrylonitrile content is from about 5 to about 30 parts by weight per 100 parts of the polyacrylate-styrene-acrylonitrile copolymer, wherein the polyacrylate-styrene-acrylonitrile copolymer is a graft copolymer of a styrene acrylonitrile copolymer grafted to a polyacrylate;
a first styrene acrylonitrile copolymer in an amount from about 10 to about 40 parts by weigh based on 100 total parts by weight of the composition, wherein the first styrene acrylonitrile copolymer has an acrylonitrile content of about 10 to about 50 parts by weight and a styrene content of about 50 to about 90 parts by weight based on 100 parts by weight of the styrene acrylonitrile copolymer; a mixture of a cross-linked acrylonitrile-styrene copolymer and polystyrene including the polystyrene in an amount of 20 to 30 weight percent and acrylonitrile-styrene copolymer in an amount of about 70 to 80 weight percent based on the total weight of the mixture, the mixture present in an amount from 0.5 to about 2.5 parts by weight based on 100 total parts of the composition;
a second styrene-acrylonitrile copolymer having a weight average molecular weight greater than 1 million as measured by gel permeation chromatography utilizing a suitable solvent in compared against polystyrene standards in an amount from 0.1 to about 10 parts by weight based on 100 total parts by weight of the composition; and
optionally, one or more of a colorant, pigment, lubricant, UV stabilizer, light stabilizer, thermal stabilizer, antioxidant, antistatic agent, flame retardant, filler, fiber, processing aid, biocide, surfactant, blowing agent, foaming agent, and wax.

10. The composition according to claim 9 , wherein the polyacrylate-styrene-acrylonitrile copolymer is a graft copolymer of a styrene acrylonitrile copolymer grafted to a polybutylacrylate.

11. The composition according to claim 10 , wherein the polyvinyl chloride polymer is present in an amount from about 25 to about 35 parts by weight based on 100 total parts by weight of the composition, wherein the polyurethane is present in an amount from about 1 to about 25 parts by weight based on 100 total parts by weight of the composition.

12. The composition according to claim 11 , wherein the styrene content is from about 25 to about 30 parts by weight per 100 parts of the polyacrylate-styren

Assignees

• Teknor Apex Co

Inventors

• Kahn Ali
• Cox Maryellen
• Ruprecht Roland

Classifications

• B32B27/08 Primary

  of synthetic resin · CPC title

• C08L27/24

  halogenated · CPC title

• C08L27/08

  Homopolymers or copolymers of vinylidene chloride · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title