Method for producing an adsorption agent for treating compressed gas and an adsorption device provided with such an adsorption agent

Patent metadata

Field	Value
Publication number	US-11059029-B2
Application number	US-201615746295-A
Country	US
Kind code	B2
Filing date	Jul 7, 2016
Priority date	Jul 23, 2015
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

A method for manufacturing an adsorption agent for treating compressed gas, which includes the steps of providing a monolithic supporting structure; producing a coating suspension that includes an adsorbent; applying the coating suspension on the supporting structure to form a coating; applying a thermal treatment to the coated supporting structure in order to sinter the coating.

First claim

The invention claimed is:

1. A method for manufacturing an adsorption agent for drying compressed gas, comprising the following steps:
providing a monolithic supporting structure, wherein the monolithic supporting structure contains between 200 and 1200 cells per square inch (CPSI);
choosing an adsorbent based on a treatment for drying the compressed gas from a compressed gas system, wherein the adsorbent is at least a drying agent that adsorbs moisture in the compressed gas from the compressed gas system;
producing a coating suspension that comprises the adsorbent, wherein for the production of the coating suspension the adsorbent is selected which comprises a hydrophilic zeolite;
applying the coating suspension on the supporting structure to form a coating;
applying a thermal treatment to the supporting structure with the coating, in order to sinter the coating;
wherein the applying the coating suspension on the supporting structure comprises the step of flushing or perfusing the supporting structure with the coating suspension;
wherein the perfusion of the supporting structure is done from bottom to top in the opposite direction to gravity;
wherein the perfusion is realised by a pump that pumps the coating suspension upwards through the supporting structure;
wherein coating material is removed after the perfusion of the supporting structure with coating suspension; and
wherein the removal of surplus coating material is realized by reversing the operation direction of the pump.

2. The method according to claim 1 , wherein one or more of the following materials are selected for the monolithic supporting structure: ceramic material, metal foil and a fibre structure.

3. The method according to claim 2 , wherein a ceramic structure that contains cordierite is selected for the monolithic supporting structure.

4. The method according to claim 1 , wherein for the production of the coating suspension one or more of the following materials are selected for an adsorbent: a zeolite, silica gel, activated alumina, activated carbon, metal-organic frameworks, carbon molecular sieve (CMS), an impregnated adsorbent and a hybrid adsorbent.

5. The method according to claim 4 , wherein the adsorbent comprises faujasite zeolite type X.

6. The method according to claim 1 , wherein the step of producing the coating suspension comprises the following sub-steps:
providing a solvent;
adding the adsorbent to the solvent to form a mixture; and
adding a binder material to the mixture.

7. The method according to claim 6 , wherein after the addition of the adsorbent to the solvent and the mixing of the adsorbent with the solvent, the adsorbent particles are reduced in size by wet milling.

8. The method according to claim 7 , wherein the particle size of the adsorbent is reduced in size until D 50 is less than 10 μm.

9. The method according to claim 6 , wherein one or more of the following inorganic binder materials are selected as a binder material:
colloidal silica;
alumina; and/or
clay.

10. The method according to claim 6 , wherein one or more of the following organic binder materials are selected as a binder material:
methyl cellulose;
polymers such as acrylic resins, vinyl resins and similar; and/or
a material of the cellulose group.

11. The method according to claim 1 , wherein a part of the surplus coating material is evacuated from the supporting structure by applying one or more pressure pulses of a purge gas through the channels of the supporting structure.

12. The method according to claim 1 , wherein the heat treatment consists of at least three phases:
increasing the temperature during the first time interval t 1 -t 0 ;
keeping the temperature constantly high at a value above 400° C. during a second time interval t 2 -t 1 ;
decreasing the temperature back to ambient temperature during a third time interval t 3 -t 2 .

13. The method according to claim 12 , wherein the temperature is kept constant during the second time interval t 2 -t 1 .

14. The method according to claim 1 , wherein the step of the production of the coating suspension comprises: the addition of one or more additives.

15. The method according to claim 14 , wherein the additives contain one or more of the following agents:
an additive to affect the acidity (pH value); and
an additive to counteract foam formation.

16. The method according to claim 15 , wherein the additive to affect the acidity consists of hydrogen chloride or ammonia.

17. A gas compressor system comprising:
an air compressor; and
an adsorption device provided with an adsorption agent obtained with the method according to claim 1 .

18. A method for manufacturing an adsorption agent comprising the following steps:
choosing an adsorbent based on a treatment for drying compressed gas, wherein the adsorbent is at least a drying agent that adsorbs moisture in the compressed gas from a compressed gas system;
producing a coating suspension that comprises the adsorbent, wherein the adsorbent comprises a hydrophilic zeolite;
applying the coating suspension to a supporting structure to form a coating; and
sintering the coating by a thermal treatment;
wherein said applying comprises perfusing the supporting structure with the coating suspension, said perfusing is done in the opposite direction to gravity, and said perfusing is realised by a pump that pumps the coating suspension upwards through the supporting structure; and further comprising
removing a portion of the coating material after the perfusing, wherein the removing is realized by reversing the operation direction of the pump.

19. A method for drying a compressed gas from an air compressor comprising the steps of:
manufacturing an adsorption agent according to claim 1 ;
providing the adsorption agent in a drying device comprising at least two vessels;
drying the compressed gas from a compressed air compressor by guiding the compressed gas through the drying device,
wherein a drying efficiency of the drying device is increased at least three folds using the adsorption agent.

Assignees

• Atlas Copco Airpower Nv

Inventors

• Lammers Carlo
• Mullens Steven Hans Rik Wouter

Classifications

• B01D53/0446

  Means for feeding or distributing gases · CPC title

• B01J20/3234

  Inorganic material layers · CPC title

• B01J20/3225

  involving a post-treatment of the coated or impregnated product · CPC title

• B01J20/32

  Impregnating or coating {; Solid sorbent compositions obtained from processes involving impregnating or coating} · CPC title

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title