Metal-air battery

Patent metadata

Field	Value
Publication number	US-11056738-B2
Application number	US-201916676628-A
Country	US
Kind code	B2
Filing date	Nov 7, 2019
Priority date	Nov 9, 2018
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

A metal-air battery including a cathode including a metal; an anode including a composite conductive material; a solid electrolyte layer between the cathode and the anode; and a vapor supplier configured to supply a vapor to the anode and the solid electrolyte layer.

First claim

What is claimed is:

1. A metal-air battery comprising:
a cathode comprising a metal;
an anode comprising a composite conductive material;
a solid electrolyte layer between the cathode and the anode; and
a vapor supplier configured to supply a vapor to the anode and the solid electrolyte layer.

2. The metal-air battery of claim 1 , wherein an electron conductivity of the composite conductive material is greater than or equal to about 10 −9 Siemens per centimeter and less than or equal to about 10 −1 Siemens per centimeter and an ion conductivity of the composite conductive material is greater than or equal to about 10 −9 Siemens per centimeter and less than or equal to about 10 −1 Siemens per centimeter.

3. The metal-air battery of claim 1 , wherein the composite conductive material comprises an inorganic solid compound.

4. The metal-air battery of claim 1 , wherein the composite conductive material comprises lithium titanium oxide, lithium manganese oxide, lithium cobalt oxide, lithium manganese nickel oxide, lithium nickel manganese cobalt oxide, lithium nickel oxide, lithium iron phosphate, lithium iron manganese phosphate, lithium lanthanum titanium oxide, lithium aluminum titanium phosphate, lithium lanthanum manganese oxide, lithium lanthanum ruthenium oxide, a lithium deintercalation product, or a combination thereof.

5. The metal-air battery of claim 1 , wherein the composite conductive material comprises an inorganic material having a Perovskite structure, an anti-Perovskite structure, a layered structure, a spinel structure or NASICON structure.

6. The metal-air battery of claim 1 , wherein the solid electrolyte layer comprises a metal ion conductive material.

7. The metal-air battery of claim 1 , comprising:
a cell module comprising the cathode, the anode, and the solid electrolyte and configured to generate electricity by oxidation of the metal and reduction of oxygen and the vapor; and
an air purifier which is in fluid communication with the vapor supplier and provides a purified air to the vapor supplier.

8. The metal-air battery of claim 7 , further comprising:
a first fluid regulator configured to regulate a flow of the purified air and the vapor from the vapor supplier to the anode and the solid electrolyte layer; and
a second fluid regulator configured to regulate a flow of fluid from the cell module to an outside of the cell module.

9. The metal-air battery of claim 8 , further comprising:
an oxygen concentration measurer configured to measure an oxygen concentration in the cell module;
a vapor concentration measurer configured to measure a vapor concentration in the cell module; and
a controller configured to control opening and closing of the first fluid regulator and the second fluid regulator according to the oxygen concentration and the vapor concentration in the cell module.

10. The metal-air battery of claim 7 , wherein the air purifier provides a vapor condenser configured to remove vapor in an outside air, and an oxygen concentration adjuster configured to remove nitrogen and carbon dioxide in the outside air to control the oxygen concentration in the cell module.

11. The metal-air battery of claim 10 , wherein the vapor condenser is configured to condense vapor in the cell module.

12. The metal-air battery of claim 11 , further comprising:
a pump configured to apply a negative pressure to the cell module to recover the vapor condensed by the vapor condenser from the cell module.

13. The metal-air battery of claim 10 , further comprising:
a third fluid regulator configured to regulate the flow of the purified air from the oxygen concentration adjuster to the cell module; and
a fourth fluid regulator configured to regulate the flow of fluid from the vapor supplier to the anode and the solid electrolyte layer.

14. The metal-air battery of claim 13 , further comprising:
an oxygen concentration measurer configured to measure oxygen concentration in the cell module;
a vapor concentration measurer configured to measure vapor concentration in the cell module; and
a controller configured to control opening and closing of the third fluid regulator and the fourth fluid regulator according to the oxygen concentration and the vapor concentration in the cell module.

15. The metal-air battery of claim 7 , wherein an electron conductivity of the composite conductive material is greater than or equal to about 10 −9 Siemens per centimeter and less than or equal to about 10 −1 Siemens per centimeter and an ion conductivity of the composite conductive material is greater than or equal to about 10 −9 Siemens per centimeter and less than or equal to about 10 −1 Siemens per centimeter.

16. The metal-air battery of claim 7 , wherein the composite conductive material comprises an inorganic solid compound.

17. The metal-air battery of claim 7 , wherein the composite conductive material comprises lithium titanium oxide, lithium manganese oxide, lithium cobalt oxide, lithium manganese nickel oxide, lithium nickel manganese cobalt oxide, lithium nickel oxide, lithium iron phosphate, lithium iron manganese phosphate, lithium lanthanum titanium oxide, lithium aluminum titanium phosphate, lithium lanthanum manganese oxide, lithium lanthanum ruthenium oxide, a lithium deintercalation product thereof, or a combination thereof.

18. The metal-air battery of claim 7 , wherein the composite conductive material comprises an inorganic material having a Perovskite structure, an anti-Perovskite structure, a spinel structure or NASICON structure.

19. The metal-air battery of claim 7 , wherein the solid electrolyte layer comprises a metal ion conductive material.

20. A method of operating metal-air battery of claim 1 , the method comprising:
providing the metal-air battery;
supplying water vapor to the anode;
supplying oxygen to the anode; and
regulating a supply rate of the water vapor according to a charge/discharge rate of the metal-air battery to operate the metal-air battery.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Mokwon
• Lee Heungchan
• Ma Sangbok
• Park Jungock
• Kim Hyunjin
• Choi Wonsung

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/0668

  Removal of carbon monoxide or carbon dioxide · CPC title

• H01M8/04089

  of gaseous reactants · CPC title

• H01M4/8673

  Electrically conductive fillers · CPC title