Method of authenticating an object with X-ray diffraction

Patent metadata

Field	Value
Publication number	US-11054374-B2
Application number	US-201816629716-A
Country	US
Kind code	B2
Filing date	Jul 11, 2018
Priority date	Jul 11, 2017
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

The application concerns a method of authenticating an object, the object comprising an identification substance including at least one amorphous phase, at least one crystalline phase and at least one complex metallic phase. The method includes the steps of: subjecting the identification substance of a candidate object to XRD analysis to determine an XRD signature thereof; comparing the XRD signature of the candidate object to a reference XRD signature, and concluding to the authenticity of the object when its XRD signature substantially matches the reference XRD signature.

First claim

The invention claimed is:

1. A method of authenticating an object, the object comprising an identification substance including at least one amorphous phase, at least one crystalline phase and at least one complex metallic phase, said method comprising:
subjecting the identification substance of a candidate object to X-Ray diffraction, XRD, analysis to determine an XRD signature thereof;
comparing the XRD signature of the candidate object to a reference XRD signature, and concluding to the authenticity of the object when its XRD signature substantially matches the reference XRD signature.

2. The method according to claim 1 , wherein said identification substance is formed as a label or taggant associated with said object or directly applied on said object.

3. The method according to claim 1 , wherein said object is manufactured from said identification substance, at least in part; or said identification substance is in the bulk of or integral with said object.

4. The method as claimed in claim 1 , wherein said identification substance comprises at least one polymer with an amorphous phase, said at least one polymer preferably forming a matrix of said identification substance.

5. The method as claimed in claim 1 , wherein said identification substance comprises a metallic alloy with at least one approximant metallic phase.

6. The method as claimed in claim 1 , wherein said identification substance comprises a metallic alloy with at least one quasi-crystalline phase.

7. The method as claimed in claim 1 , wherein said identification substance comprises a polymer matrix with at least one amorphous phase with embedded particles of a complex metallic alloy comprising at least one crystalline phase and at least one complex metallic phase.

8. The method as claimed in claim 1 , wherein said comparison step comprises comparing angular positions of relevant peaks between the candidate XRD signature and the reference XRD signature.

9. The method as claimed in claim 1 , wherein said comparison step comprises comparing relative intensities of relevant peaks between the candidate XRD signature and the reference XRD signature.

10. The method as claimed in claim 1 , wherein said identification substance comprises a predetermined calibration crystal comprises silicon.

11. A method of authenticating an object, said method comprising the steps of:
a) manufacturing an identification substance including at least one amorphous phase, at least one crystalline phase and at least one complex metallic phase;
b) subjecting an amount of said identification substance to X-Ray diffraction, XRD, analysis to determine an XRD signature thereof and storing the latter as reference XRD signature;
c) associating an amount of said identification substance to an object;
d) subjecting a candidate identification substance associated with an object to be identified to XRD analysis to determine an XRD signature of said identification substance;
e) comparing said XRD signature of said candidate identification substance to said reference XRD signature, and concluding to the authenticity of said object to be identified when its XRD signature substantially matches said reference XRD signature.

12. The method according to claim 11 , wherein a plurality of labels or taggants are manufactured from said identification substance and said labels are applied or tied to objects.

13. The method according to claim 11 , wherein amounts of said identification substance are applied to labels or packaging of objects or are applied directly to objects.

14. The method according to claim 11 , wherein amounts of said identification substance are added to the bulk of objects to be authenticated during object production and/or packaging.

15. The method as claimed in claim 11 , wherein said identification substance comprises at least one polymer with an amorphous phase, said at least one polymer preferably forming a matrix of said identification substance.

16. The method as claimed in claim 11 , wherein said identification substance comprises a metallic alloy with at least one approximant metallic phase.

17. The method as claimed in claim 11 , wherein said identification substance comprises a metallic alloy with at least one quasi-crystalline phase.

18. The method as claimed in claim 11 , wherein said identification substance comprises a polymer matrix with at least one amorphous phase with embedded particles of a complex metallic alloy comprising at least one crystalline phase and at least one complex metallic phase.

19. The method as claimed in claim 11 , wherein said comparison step comprises comparing angular positions of relevant peaks between the candidate XRD signature and the reference XRD signature.

20. The method as claimed in claim 11 , wherein said comparison step comprises comparing relative intensities of relevant peaks between the candidate XRD signature and the reference XRD signature.

21. The method as claimed in claim 11 , wherein said identification substance comprises a predetermined calibration crystal comprising silicon.

22. An authentication method comprising analysing an X-Ray diffraction signature of an identification substance, wherein said identification substance comprises at least one amorphous phase, at least one crystalline phase and at least one complex metallic phase.

Assignees

• Centre Nat Rech Scient

Inventors

• Kenzari Samuel
• Fournée Vincent

Classifications

• G07D7/06

  using wave or particle radiation · CPC title

• B42D25/36

  comprising special materials · CPC title

• G06K7/1099

  scanning using X-rays · CPC title

• B42D25/373

  Metallic materials · CPC title

• G01N33/204

  Structure thereof, e.g. crystal structure · CPC title