Process and apparatus for separating air using a split heat exchanger

Patent metadata

Field	Value
Publication number	US-11054182-B2
Application number	US-201815993993-A
Country	US
Kind code	B2
Filing date	May 31, 2018
Priority date	May 31, 2018
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

Process and apparatus for the separation of a compressed feed air stream to produce an oxygen product using a distillation column having a lower-pressure column and a higher-pressure column, a higher-pressure heat exchanger and a lower-pressure heat exchanger where the gaseous nitrogen expander receives a nitrogen-enriched fraction from a position intermediate the warmer end and the colder end of the higher-pressure heat exchanger.

First claim

The invention claimed is:

1. A process for the separation of a compressed feed air stream to produce an oxygen product and optionally a nitrogen product, the process comprising:
providing a multi-column distillation system comprising a lower-pressure column and a higher-pressure column;
passing a first portion of the compressed feed air stream into a first end of a first heat exchanger section, cooling the first portion of the compressed feed air stream in the first heat exchanger section, and withdrawing the first portion of the compressed feed air stream from a second end of the first heat exchanger section
passing the first portion of the compressed feed air stream withdrawn from the second end of the first heat exchanger section to at least one of the higher-pressure column or the lower-pressure column;
passing a second portion of the compressed feed air stream into a first end of a second heat exchanger section, cooling the second portion of the compressed feed air stream in the second heat exchanger section, and withdrawing the second portion from a second end of the second heat exchanger section
passing the second portion of the compressed feed air stream withdrawn from the second end of the second heat exchanger section to the higher-pressure column;
withdrawing an oxygen-enriched fraction from the higher-pressure column;
passing the oxygen-enriched fraction withdrawn from the higher-pressure column to the lower-pressure column;
withdrawing an oxygen-rich fraction from the lower-pressure column;
passing the oxygen-rich fraction withdrawn from the lower-pressure column to the second end of the first heat exchanger section, heating the oxygen-rich fraction in the first heat exchanger section, and withdrawing the oxygen-rich fraction from the first end of the first heat exchanger section as the oxygen product;
withdrawing a nitrogen-enriched fraction from the higher-pressure column;
passing the nitrogen-enriched fraction withdrawn from the higher-pressure column to the second end of the first heat exchanger section, heating the nitrogen-enriched fraction in the first heat exchanger section, and withdrawing the nitrogen-enriched fraction from a position intermediate the first end and the second end of the first heat exchanger section; and
expanding the nitrogen-enriched fraction withdrawn from the position intermediate the first end and the second end of the first heat exchanger section in an expander to produce work and reduce the pressure of the nitrogen-enriched fraction;
withdrawing a nitrogen-rich byproduct from the lower-pressure column;
passing a first fraction of the nitrogen-rich byproduct withdrawn from the lower-pressure column to a first end of a first subcooler heat exchanger section, heating the first fraction of the nitrogen-rich byproduct in the first subcooler heat exchanger section, and withdrawing the first fraction of the nitrogen-rich byproduct from a second end of the first subcooler heat exchanger section;
passing a first portion of the nitrogen-rich byproduct from the second end of the first subcooler heat exchanger section to the second end of the first heat exchanger section, heating the first portion of the nitrogen-rich byproduct in the first heat exchanger section, and withdrawing the first portion of the nitrogen-rich byproduct from the first end of the first heat exchanger section as a first nitrogen-rich discharge byproduct gas;
passing a second portion of the first fraction of the nitrogen-rich byproduct from the second end of the first subcooler heat exchanger section to the second end of the second heat exchanger section, heating the second portion of the first fraction of the nitrogen-rich byproduct in the second heat exchanger section, and withdrawing the second portion of the first fraction of the nitrogen-rich byproduct from the first end of the second heat exchanger section as a third nitrogen-rich discharge product gas;
wherein passing a second fraction of the nitrogen-rich byproduct withdrawn from the lower-pressure column to a first end of a second subcooler heat exchanger section, heating the second fraction of the nitrogen-rich byproduct in the second subcooler heat exchanger section, and withdrawing the second fraction of the nitrogen-rich byproduct from a second end of the second subcooler heat exchanger section;
wherein passing the second fraction of the nitrogen-rich byproduct from the second end of the second subcooler heat exchanger section to the second end of the second heat exchanger section, heating the second fraction of the nitrogen-rich byproduct in the second heat exchanger section, and withdrawing the second fraction of the nitrogen-rich byproduct from the first end of the second heat exchanger section as a second nitrogen-rich discharge byproduct gas;
wherein the expanded nitrogen-enriched fraction or a first portion thereof is passed to the second end of the second heat exchanger section, heated in the second heat exchanger section, and withdrawn from the first end of the second heat exchanger section; and
wherein the second portion of the first fraction of the nitrogen-rich byproduct passed to the second end of the second heat exchanger section and the expanded nitrogen-enriched fraction or first portion thereof passed to the second end of the second heat exchanger section are blended at a location that is upstream of the second heat exchanger section and downstream of the first and second subcooler heat exchanger sections and subsequently passed together to the second end of the second heat exchanger section.

2. The process according to claim 1 wherein the pressure of the second portion of the compressed feed air stream is less than the pressure of the first portion of the compressed air feed stream.

3. The process according to claim 1
wherein a higher-pressure heat exchanger comprises the first heat exchanger section; and
wherein a lower-pressure heat exchanger comprises the second heat exchanger section, wherein the maximum operating pressure in the lower-pressure heat exchanger is lower than the maximum operating pressure in the higher-pressure heat exchanger.

4. The process according to claim 1 further comprising:
passing a third portion of the compressed feed air stream into the first end of the first heat exchanger section, cooling the third portion of the compressed feed air stream in the first heat exchanger section, and withdrawing the third portion of the compressed air feed stream from a position intermediate the first end and the second end of the first heat exchanger section;
expanding the third portion of the compressed feed air stream withdrawn from the position intermediate the first end and the second end of the first heat exchanger section in a second expander to produce work and reduce the pressure of the third portion of the compressed feed air stream; and
passing the third portion after expanding to at least one of the higher-pressure column or the lower-pressure column.

5. The process according to claim 4 wherein the second portion of the compressed feed air stream withdrawn from the second end of the second heat exchanger section and the third portion after expanding are blended prior to each being passed together to the higher-pressure column.

6. The process according to claim 1 wherein a nitrogen product is produced, the process further comprising:
withdrawing a nitrogen-rich fraction from the higher-pressure column;
passing a first portion of the nitrogen-rich fraction to a reboiler-condenser of the multi-column distillation system, condensing the first portion of the nitrogen-rich fraction in the reboiler-condenser, and withdrawing the first portion of the nitrogen-rich fraction from the reboiler-condenser;
passing a part of the first portion of the nitrogen-rich fraction with

Assignees

• Air Prod & Chem

Inventors

• Zhao Qiao
• Herron Donn Michael

Classifications

• F25J3/04303

  Lachmann expansion, i.e. expanded into oxygen producing or low pressure column · CPC title

• F25J3/04296

  Claude expansion, i.e. expanded into the main or high pressure column · CPC title

• F25J3/04218

  Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores (F25J3/04503 takes precedence) · CPC title

• F25J3/04709 Primary

  as an auxiliary column system in at least a dual pressure main column system · CPC title

• F25J3/0406

  of nitrogen · CPC title