Stretchable, tough, and self-healing elastomer and applications thereof

Patent metadata

Field	Value
Publication number	US-11053390-B2
Application number	US-201816155536-A
Country	US
Kind code	B2
Filing date	Oct 9, 2018
Priority date	Oct 6, 2017
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

Various embodiments are directed to apparatuses and methods involving an elastomer material comprising a flexible polymer backbone with a particular ratio of at least first moieties and second moieties. The first moieties provide a first number of dynamic bonds resulting from interactions between the first moieties and the second moieties provide a second number of dynamic bonds resulting from interactions between the second moieties, the second number of dynamic bonds having a weaker bonding strength than the first number of dynamic bonds. The elastomer material, based on the ratio of the first moieties and second moieties, exhibits autonomous self-healing, a particular toughness, and is stretchable.

First claim

What is claimed is:

1. An elastomer material comprising:
a flexible polymer backbone with a particular ratio of at least first moieties and second moieties, wherein the first moieties are configured to provide a first number of dynamic bonds resulting from interactions between the first moieties; and
the second moieties are configured to provide a second number of dynamic bonds resulting from interactions between the second moieties, the second number of dynamic bonds having a weaker bonding strength than the first number of dynamic bonds, and wherein the elastomer material, at least in part based on the ratio of the first moieties and second moieties, exhibits autonomous self-healing, a particular toughness set as a function of the ratio, and exhibits notch-insensitive stretchability under a strain, wherein the strain is in a range from 150 percent strain to 1200 percent strain.

2. The elastomer material of claim 1 , wherein the elastomer material exhibits a Young's modulus of between 0.1 and 3.0 megapascal (MPa) and stretching of between 1,200 and 3,000 percent without rupturing, and wherein the dynamic bonds include at least one selected from the group consisting of hydrogen bonding, metal-ligand bonding, guest-host interactions, and supramolecular interactions.

3. An elastomer material comprising:
a flexible polymer backbone with a particular ratio of at least first moieties and second moieties, wherein the first moieties are configured to provide a first number of dynamic bonds resulting from interactions between the first moieties; and the second moieties are configured to provide a second number of dynamic bonds resulting from interactions between the second moieties, the second number of dynamic bonds having a weaker bonding strength than the first number of dynamic bonds, and wherein the elastomer material, at least in part based on the ratio of the first moieties and second moieties, exhibits autonomous self-healing, a particular toughness set as a function of the ratio, and exhibits stretchability as characterized by one or a combination of-stretchability of at least 500 percent without rupturing and notch-insensitive stretchability under a strain, wherein the strain is in a range from 150 percent strain to 1200 percent strain, and wherein the flexible polymer backbone is selected from the group consisting of: polydimethylsiloxane (PDMS) polyethyleneoxide (PEO), Perfluoropolyether (PFPE), polybutylene (PB), poly(ethylene-co-1-butylene), poly(butadiene), hydrogenated poly(butadiene), polybutylene, poly(ethylene oxide)-poly(propylene oxide) block copolymer or random copolymer, and poly(hydroxyalkanoate) and the at least first and second moieties are randomly or equally spaced from one another.

4. The elastomer material of claim 1 , wherein the first moieties include 4,4′-methylenebis(phenyl urea) (MPU) and the second moieties include isophorone bisurea (IU).

5. The elastomer material of claim 4 , wherein the particular ratio of MPU moieties to IU moieties is selected from the group consisting of: 0.4 to 0.6, 0.3 to 0.7 and 0.2 to 0.8.

6. The elastomer material of claim 1 , wherein the elastomer material is configured and arranged to stretch up to 3,000 percent and exhibits a Young's modulus of between 0.22 and 1.5 megapascal (MPa).

7. An elastomer material comprising:
a flexible polymer backbone with a particular ratio of at least first moieties and second moieties, wherein the first moieties are configured to provide a first number of dynamic bonds resulting from interactions between the first moieties; and
the second moieties are configured to provide a second number of dynamic bonds resulting from interactions between the second moieties, the second number of dynamic bonds having a weaker bonding strength than the first number of dynamic bonds, and wherein the elastomer material, at least in part based on the ratio of the first moieties and second moieties, exhibits autonomous self-healing, a particular toughness, and is stretchable, and wherein the elastomer material is characterized in that: at least in part based on the ratio of the first moieties and second moieties, the elastomer material exhibits autonomous self-healing, a particular toughness, and notch insensitivity under a strain wherein the strain is in a range from 150 percent strain to 1200 percent strain; or when a strain is applied to the elastomer material, the dynamic bonds of the first number are characterized as being sufficient to block induced crack propagation while the bonds having a weaker bonding strength simultaneously break and dissipate strain energy.

8. The elastomer material of claim 1 , wherein the elastomer material includes a supramolecular network formed as a polymer film configured and arranged to exhibit the autonomous self-healing and notch-insensitive stretchability in a range of 1,200-1,500 percent by self-recoverable energy dissipation in the polymer film.

9. An apparatus comprising:
a polymer film that includes a supramolecular network of elastomer material, the elastomer material having a flexible polymer backbone with a particular ratio of at least first moieties and second moieties,
the first moieties being configured and arranged to provide a first number of dynamic bonds resulting from interactions between the first moieties and the second moieties being configured and arranged to provide a second number of dynamic bonds resulting from interactions between the second moieties, the second number of dynamic bonds having a weaker bonding strength than the first number of dynamic bonds, and
wherein the polymer film exhibits autonomous self-healing, a Young's modulus of between 0.1 and 3.0 megapascal (MPa), and stretchability that is in a range from 1,200 to 3,000 percent without rupturing.

10. The apparatus of claim 9 , wherein the polymer film is colorless and transparent, and the first moieties include 4,4′-methylenebis(phenyl urea) (MPU) and the second moieties include isophorone bisurea (IU), and the flexible polymer backbone is selected from the group consisting of: polydimethylsiloxane (PDMS) polyethyleneoxide (PEO), Perfluoropolyether (PFPE), polybutylene (PB), poly(ethylene-co-1-butylene), poly(butadiene), hydrogenated poly(butadiene), polybutylene, poly(ethylene oxide)-poly(propylene oxide) block copolymer or random copolymer, and poly(hydroxyalkanoate).

11. The apparatus of claim 9 , wherein the polymer film exhibits a Young's modulus of between 0.22 and 1.5 MPa.

12. The apparatus of claim 9 , wherein the polymer film exhibits mechanical properties including the autonomous self-healing, the Young's modulus and the stretchability due to different crosslink strength of the first and second numbers of dynamic bonds.

13. The apparatus of claim 9 , wherein the polymer film exhibits notch-insensitive stretchability and a fracture energy of 15,000 Joule per meter squared (J/m2).

14. The apparatus of claim 9 , wherein the polymer film is configured and arranged to exhibit the autonomous self-healing in a presence of liquid.

15. The apparatus of claim 9 , wherein the polymer film forms part of one of the following: three-dimensional self-healable objects, wearable electronics, robotic applications, self-healable electrode, self-healable capacitive strain sensor, and an array of strain sensors.

16. A method comprising:
selecting a ratio of at least a first moiety and a second moiety based on one or more designated mechanical properties;
forming a viscous solution that includes a flexible polymer and the ratio of the at least first moiety and the second moiety; and
from the viscous solution, forming a po

Assignees

• Univ Leland Stanford Junior

Inventors

• Bao Zhenan
• Kang Jiheong
• Son Donghee

Classifications

• C08G77/458 Primary

  containing polyurethane sequences · CPC title

• C08L2203/16

  used for films · CPC title

• C08G77/452

  containing nitrogen-containing sequences · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• B29C73/16

  Auto-repairing or self-sealing arrangements or agents {(incorporating auto-repairing or self-sealing arrangements or agents on or into tyres B29D30/0685)} · CPC title