Optimized sizing for carbon fiber-sheet molding compound

Patent metadata

Field	Value
Publication number	US-11053364-B2
Application number	US-201716336601-A
Country	US
Kind code	B2
Filing date	Sep 27, 2017
Priority date	Sep 27, 2016
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

There is provided a carbon fiber sheet molding composition including a vinyl ester resin type system. The carbon fiber distribution is random. The carbon fiber length is from about 0.5 inches to two inches. The carbon fiber loading is from about 35% to 65%, and includes epoxy sized carbon fiber and vinyl sized carbon fiber effective to achieve predetermined significant increase in desired mechanical properties.

First claim

What is claimed is:

1. A carbon fiber sheet molding composition, comprising:
from about 35% to 65% by weight of a sheet molding composition (SMC) filled with about 45% to 55% by weight of carbon fiber comprising about a 50/50 mixture of epoxy sized carbon fiber and vinyl ester sized carbon fiber for providing the carbon fiber sheet molding composition with predetermined mechanical properties, wherein the predetermined properties include flexural strength of about 350 to 500 Mpa, flexural modulus of about 25 to 30 Gpa, and a tensile strength of at least 275 Mpa.

2. The carbon fiber sheet molding composition of claim 1 , wherein the flexural strength includes at least 460 Mpa to 500 Mpa.

3. The carbon fiber sheet molding composition of claim 1 , wherein the predetermined mechanical properties also include tensile modulus of about 32 to 40 Gpa.

4. The carbon fiber sheet molding composition of claim 1 , wherein carbon fiber filaments of the carbon fiber are from about 0.5 inch to about 2 inches in length in the sheet molding composition and are distributed randomly.

5. The carbon fiber sheet molding composition of claim 1 , wherein the carbon fiber is found in the carbon fiber sheet molding composition in an amount of 50% by weight.

6. The carbon fiber sheet molding composition of claim 1 , wherein a resin of the sheet molding composition is found in the carbon fiber sheet molding composition in an amount from about 45% to 55% by weight.

7. The carbon fiber sheet molding composition of claim 6 , wherein the resin is manufactured from about 95 parts by weight of a vinyl ester and about 5 parts by weight of a polymeric methylene diphenyl isocyanate.

8. The carbon fiber sheet molding composition of claim 1 , wherein a resin is found in the carbon fiber sheet molding composition in an amount from about 45% to 55% by weight, and wherein the carbon fiber, which is about 1 inch in length carbon fiber, is found in the carbon fiber sheet molding composition in an amount from about 45% to 55% by weight.

9. The carbon fiber sheet molding composition of claim 1 , wherein the carbon fiber is a 50K filament fiber manufactured from a polyacrylonitrile precursor.

10. The carbon fiber sheet molding composition of claim 1 , wherein the carbon fiber is about 25% by weight epoxy sized carbon fiber and about 25% by weight vinyl ester sized carbon fiber.

11. The carbon fiber sheet molding composition of claim 1 , wherein the carbon fiber is a 50K filament fiber manufactured from a polyacrylonitrile precursor having a tensile modulus of at least about 242 Gpa and a tensile strength of at least about 4137 MPa.

12. A carbon fiber sheet molding composition, comprising:
from about 45% to 55% by weight of a sheet molding composition (SMC) filled with about 55% to 45% by weight of a carbon fiber, said carbon fiber comprising about a 50/50 mixture of epoxy sized carbon fiber and vinyl ester sized carbon fiber for providing the carbon fiber sheet molding composition with predetermined mechanical properties, wherein the predetermined mechanical properties include a flexural strength of at least about 460 Mpa, a flexural modulus of about 25 to 30 Gpa, and a tensile strength of at least about 275 Mpa.

13. The carbon fiber sheet molding composition of claim 12 , wherein the carbon fiber mixture is about 25% by weight epoxy sized carbon fiber and about 25% by weight vinyl ester sized carbon fiber.

14. The carbon fiber sheet molding composition of claim 12 , wherein the carbon fiber is a chopped carbon fiber having a length of about 0.5 to 2 inches.

15. A carbon fiber sheet molding composition, comprising:
from about 40% to 60% by weight of a sheet molding composition (SMC) filled with about 60% to 40% by weight of a carbon fiber, said carbon fiber comprising a mixture of from about 20% to 30% by weight of epoxy sized carbon fiber and from about 20% to 30% by weight of vinyl ester sized carbon fiber for providing the carbon fiber sheet molding composition with predetermined mechanical properties, wherein the predetermined mechanical properties include a flexural strength of at least about 460 Mpa and a tensile strength of at least about 275 Mpa.

Assignees

• Magna Exteriors Inc

Inventors

• Laux Joseph J

Classifications

• C08J5/248 Primary

  using pre-treated fibres · CPC title

• D06M15/51

  Unsaturated polymerisable polyesters · CPC title

• C08J5/06

  using pretreated fibrous materials · CPC title

• D06M2101/40

  Fibres of carbon · CPC title

• D06M15/55

  Epoxy resins · CPC title