Diesel oxidizing catalytic converter

Patent metadata

Field	Value
Publication number	US-11052378-B2
Application number	US-201716316239-A
Country	US
Kind code	B2
Filing date	Jul 13, 2017
Priority date	Jul 19, 2016
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

The present invention relates to a diesel oxidizing catalytic converter which comprises a supporting body with a length L which extends between a first end surface a and a second end surface b, and catalytically active material zones A and B of different composition which are arranged on the supporting body, wherein —material zone A comprises palladium or platinum and palladium in a weight ratio Pt:Pd of <1 and, starting from the end surface a, extends to from 20% to 80% of the length L, and —material zone B comprises platinum and palladium in a weight ratio Pt:Pd of <10 and extends to from 80% to 100% of the length L, and wherein material zone B is arranged above material zone A and the weight ratio Pt:Pd in relation to the material zones A and B is from 1.5 to 3.0.

First claim

The invention claimed is:

1. Diesel oxidation catalyst comprising
a carrier body having a length L extending between a first end face a and a second end face b, and
differently composed catalytically active material zones A and B arranged on the carrier body, wherein
material zone A contains palladium or platinum and palladium in a weight ratio Pt:Pd of ≤1 and extends starting from end face a to 20 to 80% of length L, and
material zone B contains platinum and palladium in a weight ratio Pt:Pd of <10 and extends to 80 to 100% of length L, and

wherein material zone B is arranged above material zone A and the weight ratio Pt:Pd relative to the material zones A and B is 1.5 to 3.0.

2. The diesel oxidation catalyst according to claim 1 , further comprising carrier oxides, and wherein in the material zones A and B, palladium or platinum and palladium are present on the carrier oxides.

3. The diesel oxidation catalyst according to claim 2 , wherein the carrier oxides that are present in material zones A and B are identical to or different from one another and are selected from the group consisting of aluminum oxide, doped aluminum oxide, silicon oxide, titanium dioxide and mixed oxides of one or more thereof.

4. The diesel oxidation catalyst according to claim 1 , wherein the material zone A contains an alkaline-earth metal.

5. The diesel oxidation catalyst according to claim 4 , wherein the alkaline-earth metal in material zone A is strontium, barium, or strontium and barium.

6. The diesel oxidation catalyst according to claim 1 , wherein the length of the material zone B is 95% or 100% of the total length L of the carrier body.

7. The diesel oxidation catalyst according to claim 1 , wherein the material zone B contains platinum and palladium in a weight ratio Pt:Pd of 3.0 to <10.

8. The diesel oxidation catalyst according to claim 1 , wherein the material zone B contains platinum and palladium in a weight ratio Pt:Pd of 3.0 to 6.0.

9. The diesel oxidation catalyst according to claim 1 , wherein the length of the material zone A is 50% to 80%.

10. The diesel oxidation catalyst according to claim 1 , wherein the material zone A comprises an alkaline-earth metal selected from the group consisting of strontium, barium, or strontium and barium in an amount of 0.5 to 5% by weight of the material zone A.

11. The diesel oxidation catalyst according to claim 1 , wherein the material zone A includes strontium in an amount of 1 to 3% by weight of the material zone A.

12. The diesel oxidation catalyst according to claim 1 , wherein the material zone A includes barium in an amount of 2.5 to 4.5% by weight of the material zone A.

13. The diesel oxidation catalyst according to claim 1 , wherein the material zone A includes platinum and palladium in a weight ratio Pt:Pd of 1 to 0.15.

14. The diesel oxidation catalyst according to claim 13 , wherein the material zone B contains platinum and palladium in a weight ratio Pt:Pd of 3.0 to 6.0.

15. The diesel oxidation catalyst according to claim 1 , wherein the Pt:Pd ratio in zone A results in more Pd than Pt.

16. The diesel oxidation catalyst according to claim 1 , wherein the weight ratio Pt:Pd relative to the material zones A and B is 1.5 to 2.4.

17. The diesel oxidation catalyst according to claim 1 , wherein both Pt and Pd are present in each of zones A and B.

18. A method for treating diesel exhaust gases wherein the diesel exhaust gas is conducted through a diesel oxidation catalyst according to claim 1 , wherein the diesel exhaust gas flows into the carrier body at end face a and flows out of the carrier body at end face b.

19. A device for purification of exhaust gases from diesel engines comprising a diesel oxidation catalyst according to claim 1 .

20. A device for purification of exhaust gases from diesel engines comprising a diesel oxidation catalyst according to claim 1 , wherein the diesel oxidation catalyst is arranged upstream of a diesel particulate filter and/or a catalyst for the selective catalytic reduction of nitrogen oxides.

Assignees

• Umicore Ag & Co Kg

Inventors

• Hengst Christoph
• Reith Christoph
• Schiffer Michael

Classifications

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01D2255/915

  Catalyst supported on particulate filters · CPC title

• B01D2255/9022

  Two layers · CPC title

• B01D2258/012

  Diesel engines and lean burn gasoline engines · CPC title

• B01J23/44 Primary

  Palladium · CPC title