Membrane permeation treatment with adjustment of the number of membranes used as a function of the pressure of the feed gas flow

Patent metadata

Field	Value
Publication number	US-11052345-B2
Application number	US-201916536307-A
Country	US
Kind code	B2
Filing date	Aug 8, 2019
Priority date	Aug 8, 2018
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO 2 from CH 4 to permeates enriched in CO 2 and retentates enriched in CH 4 , respectively. The at least one valve adjusts the number of membranes combined and connected to the flow of gas entering into at least one of the membrane separation units as a function of the pressure recorded by the pressure measurement device.

First claim

The invention claimed is:

1. A method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide, comprising:
compressing the feed gas flow with a compressor;
receiving the compressed feed gas flow from the compressor at a first membrane separation unit and supplying therefrom a first permeate and a first retentate, the first membrane separation unit comprising a plurality of membranes more permeable to carbon dioxide than methane;
receiving the first retentate at a second membrane separation unit and supplying therefrom a second permeate and a second retentate, the second membrane separation unit comprising a plurality of membranes more permeable to carbon dioxide than methane;
receiving the first permeate at a third membrane separation unit and supplying therefrom a third permeate and a first retentate, the third membrane separation unit comprising a plurality of membranes more permeable to carbon dioxide than methane;
receiving the third retentate at a fourth membrane separation unit and supplying therefrom a fourth permeate and a fourth retentate, the fourth membrane separation unit comprising a plurality of membranes more permeable to carbon dioxide than methane;
measuring a pressure of either the compressed feed gas flow received from the compressor by the first membrane separation unit or a pressure of the second retentate;
comparing the measured pressure with a setpoint pressure and determining a difference therebetween; and
adjusting, through use of at least one valve, a number of the plurality of membranes of at least one of the membrane separation units that receive a flow of gas as a function of the determined difference between the measured pressure and the setpoint pressure so as to keep a methane concentration of the second retentate constant.

2. The method of claim 1 , wherein said step of adjusting comprises, successively:
adding one of the plurality of membranes of the first membrane separation unit to the number of the plurality of membranes of the first membrane separation unit that receive the compressed feed gas flow from the compressor,
adding one of the plurality of membranes of the third membrane separation unit to the number of the plurality of membranes of the third membrane separation unit that receive the first permeate, and
finally adding one of the plurality of membranes of the second membrane separation unit to the number of the plurality of membranes of the second membrane separation unit that receive the first retentate.

3. The method of claim 1 , wherein said step of adjusting comprises, successively:
withdrawing one of the plurality of membranes of the first membrane separation unit from the number of the plurality of membranes of the first membrane separation unit that receive the compressed feed gas flow from the compressor,
withdrawing one of the plurality of membranes of the third membrane separation unit from the number of the plurality of membranes of the third membrane separation unit that receive the first permeate, and
finally withdrawing one of the plurality of membranes of the second membrane separation unit from the number of the plurality of membranes of the second membrane separation unit that receive the first retentate.

4. The method of claim 1 , wherein said steps of measuring, comparing, and adjusting step are carried out automatically by a programmable controller.

5. The method of claim 1 , wherein said step of measuring comprises measuring a pressure of the compressed feed gas flow received from the compressor by the first membrane separation unit and said step of adjusting is performed according to the following rules:
when the measured pressure goes above a previously fixed threshold pressure value S 1 : one of the plurality of the membranes of the first membrane separation unit is added to the number of membranes receiving the flow of gas from the compressor, one of the plurality of the membranes of the third membrane separation unit is added to the number of membranes receiving the first permeate, and one of the plurality of the membranes of the second membrane separation unit is added to the number of membranes receiving the first retentate; and
when the measured pressure goes below a previously fixed threshold pressure value S 2 : one of the plurality of the membranes of the first membrane separation unit is withdrawn to the number of membranes receiving the compressed feed gas flow from the compressor, one of the plurality of the membranes of the third membrane separation unit is withdrawn to the number of membranes receiving the first permeate, and one of the plurality of the membranes of the second membrane separation unit is withdrawn to the number of membranes receiving the first retentate.

6. The method of claim 5 , wherein said steps of measuring step and adjusting step are carried out automatically by a programmable controller.

7. The method of claim 1 , wherein the feed gas flow is biogas.

Assignees

• Air Liquide

Inventors

• Chareyre Jean-Marc
• Grabie Veronique
• Zick Golo

Classifications

• C07C7/144

  using membranes, e.g. selective permeation · CPC title

• C10L2290/60

  Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D53/226 Primary

  in serial connexion · CPC title

• C10L2290/26

  Composting, fermenting or anaerobic digestion fuel components or materials from which fuels are prepared · CPC title