Battery system

Patent metadata

Field	Value
Publication number	US-11050077-B2
Application number	US-201515503563-A
Country	US
Kind code	B2
Filing date	Aug 17, 2015
Priority date	Aug 15, 2014
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

The present invention relates to batteries and more particularly to battery systems. More particularly, the present invention relates to metal-air based battery systems. In an aspect of the present invention, there is provided a battery system, the system comprising (a) a cell comprising a metal anode and a cathode current collector, the metal anode and the cathode current collector separated by a separator; (d) a gas diffusion tank; and (e) an electrolyte between the cathode current collector and the gas diffusion tank, the electrolyte comprising redox molecules.

First claim

The invention claimed is:

1. A battery system, the system comprising:
(a) a cell comprising a metal anode and a current collector, the metal anode and the current collector separated by a separator;
(b) a gas diffusion tank comprising an inlet for receiving oxygen in the gas diffusion tank, wherein the gas diffusion tank is connected to the current collector; and
(c) a connector between the current collector and the gas diffusion tank, the connector structured to allow an electrolyte to flow between the current collector and the gas diffusion tank, the electrolyte comprising redox molecules for reducing the oxygen within the gas diffusion tank in a reduction reaction, reduced oxygen and metal ions in the electrolyte form metal-oxygen products in the gas diffusion tank, and the redox molecules flow back to the current collector after the reduction reaction,
wherein the redox molecules comprise any molecule selected from the group consisting of a quinone derivative, an aromatic amine derivatives, a phenazine derivatives, a phenothiazine derivatives and quinoxaline.

2. The system according to claim 1 , wherein a concentration of the redox molecules in the electrolyte is about 5 mM to 5 M.

3. The system according to claim 1 , wherein the separator selectively allows a passage of the metal ions only.

4. The system according to claim 1 , wherein the separator is any one selected from the group consisting of a lithiated Nafion or its composite membrane, and a lithium ion conductive ceramic membrane.

5. The system according to claim 1 , wherein the metal anode comprises any metal selected from the group consisting of lithium, sodium, potassium, calcium, aluminium, zinc and magnesium.

6. The system according to claim 5 , wherein the metal anode comprises a lithium metal electrode, and wherein the lithium metal electrode is a vinylene carbonate pre-treated lithium foil.

7. The system according to claim 6 , wherein the lithium metal electrode further comprises a PVDF-Nafion composite membrane.

8. The system according to claim 1 , wherein the current collector comprises a porous conducting matrix.

9. The system according to claim 8 , wherein the porous conducting matrix is carbon felt.

10. The system according to claim 1 , further comprising a pump to pump the electrolyte between the current collector and the gas diffusion tank.

11. The system according to claim 1 , wherein a pressure of the oxygen in the gas diffusion tank is 1 atmosphere.

12. The system according to claim 1 , wherein the battery system does not include a catalyst in the cell.

Assignees

• Nat Univ Singapore

Inventors

• Wang Qing
• Zhu Yunguang

Classifications

• H01M50/497

  Ionic conductivity · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title