Hydrogen storage materials containing liquid electrolytes

Patent metadata

Field	Value
Publication number	US-11050075-B1
Application number	US-201815928194-A
Country	US
Kind code	B1
Filing date	Mar 22, 2018
Priority date	Jun 2, 2017
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

In some variations, a hydrogen-storage material formulation comprises: a solid hydrogen-storage material containing at least one metal and hydrogen that is bonded with the metal; and a liquid electrolyte that is ionically conductive for at least one ion derived from the hydrogen-storage material. The liquid electrolyte may be from 5 wt % to about 20 wt % of the hydrogen-storage material formulation, for example. Many materials are possible for both the hydrogen-storage material as well as the liquid electrolyte. The hydrogen-storage material has a higher hydrogen evolution rate in the presence of the liquid electrolyte compared to a hydrogen-storage material without the liquid electrolyte. This is experimentally demonstrated with a destabilized metal hydride, MgH2/Si system, incorporating a LiI—KI—CsI ternary eutectic salt as the liquid electrolyte. Inclusion of the liquid electrolyte gives a ten-fold increase in H2 evolution rate at 250° C., reaching 3.5 wt % hydrogen released in only 7 hours.

First claim

What is claimed is:

1. A hydrogen-storage material formulation comprising:
(a) a solid hydrogen-storage material containing at least one metal and hydrogen that is bonded ionically, covalently, and/or interstitially within said hydrogen-storage material; and
(b) a liquid electrolyte that is ionically conductive for at least one ion derived from said hydrogen-storage material, wherein said liquid electrolyte is compositionally different than said hydrogen-storage material,
wherein said liquid electrolyte is selected such that said liquid electrolyte is characterized by the property that at a temperature equal to the melting point of said liquid electrolyte, said liquid electrolyte does not react with said hydrogen-storage material to release said hydrogen,
wherein said hydrogen-storage material is in the form of a powder, and wherein said liquid electrolyte occupies space within said powder.

2. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte is present in a liquid electrolyte concentration from about 1 wt % to about 50 wt % of said hydrogen-storage material formulation.

3. The hydrogen-storage material formulation of claim 2 , wherein said liquid electrolyte concentration is less than 20 wt % of said hydrogen-storage material formulation.

4. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen is bonded ionically, covalently, and/or interstitially with said at least one metal.

5. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen-storage material further contains a metalloid, and wherein said hydrogen is bonded ionically and/or covalently with said metalloid.

6. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen-storage material is selected from the group consisting of complex metal hydrides, destabilized metal hydrides, metal borohydrides, and combinations thereof.

7. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen-storage material consists of a material selected from the group consisting of MgH 2 , Mg(BH 4 ) 2 , LiH, LiBH 4 , LiAlH 4 , KBH 4 , NaAlH 4 , and combinations thereof.

8. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen-storage material contains at least 3 wt % hydrogen.

9. The hydrogen-storage material formulation of claim 8 , wherein said hydrogen-storage material contains at least 5 wt % hydrogen.

10. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte has an ionic conductivity at 25° C. of at least 10 −6 S/cm for said at least one ion derived from said hydrogen-storage material.

11. The hydrogen-storage material formulation of claim 10 , wherein said liquid electrolyte has an ionic conductivity at 25° C. of at least 10 −3 S/cm for said at least one ion derived from said hydrogen-storage material.

12. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte is characterized by the property that at a temperature equal to the melting point of said liquid electrolyte, said liquid electrolyte does not react with said hydrogen.

13. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte is a non-aqueous liquid electrolyte.

14. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte comprises a solvent and one or more dissolved salts.

15. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte comprises a molten salt.

16. The hydrogen-storage material formulation of claim 15 , wherein said molten salt comprises one or more halogenated alkali metals.

17. The hydrogen-storage material formulation of claim 15 , wherein said liquid electrolyte further comprises one or more additional dissolved salts.

18. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte is ionically conductive for one or more cations selected from the group consisting of Li + , Mg 2+ , Na + , K + , and Ca 2+ .

19. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte is ionically conductive for one or more anions selected from the group consisting of H − , BH 4 − , AlH 4 − , and (AlH 6 ) 3− .

20. The hydrogen-storage material formulation of claim 1 , wherein said liquid electrolyte contains halogen anions.

21. The hydrogen-storage material formulation of claim 1 , wherein said hydrogen-storage material is characterized by a higher hydrogen evolution rate in the presence of said liquid electrolyte compared to an otherwise-equivalent hydrogen-storage material formulation without said liquid electrolyte, as determined by a Sieverts system utilized to measure the rate of said hydrogen evolution with a temperature ramp from 20° C. to 300° C. over a period of 72 hours.

22. A reversible hydrogen-storage material system, said system comprising:
(a) a solid hydrogen-storage material; and
(b) a liquid electrolyte that is ionically conductive for at least one ion derived from said hydrogen-storage material, wherein said liquid electrolyte is compositionally different than said hydrogen-storage material,
wherein said hydrogen-storage material, in a first state, contains at least one metal and hydrogen that is bonded ionically, covalently, and/or interstitially within said hydrogen-storage material,
wherein said hydrogen-storage material, in a second state, contains a dehydrogenated form of said hydrogen-storage material,
wherein said liquid electrolyte is selected such that said liquid electrolyte is characterized by the property that at a temperature equal to the melting point of said liquid electrolyte, said liquid electrolyte does not react with said hydrogen-storage material to release said hydrogen,
wherein said hydrogen-storage material is in the form of a powder, and wherein said liquid electrolyte occupies space within said powder.

23. The reversible hydrogen-storage material system of claim 22 , wherein said liquid electrolyte is present in a liquid electrolyte concentration from about 1 wt % to about 50 wt % on the basis of combined weight of said hydrogen-storage material and said liquid electrolyte.

24. The reversible hydrogen-storage material system of claim 22 , wherein said hydrogen-storage material is selected from the group consisting of complex metal hydrides, destabilized metal hydrides, metal borohydrides, and combinations thereof.

25. The reversible hydrogen-storage material system of claim 22 , wherein said hydrogen-storage material contains at least 3 wt % hydrogen.

26. The reversible hydrogen-storage material system of claim 22 , wherein said liquid electrolyte is characterized by the property that at a temperature equal to the melting point of said liquid electrolyte, said liquid electrolyte does not react with said hydrogen.

Assignees

• Hrl Lab Llc

Inventors

• Vajo John J
• Graetz Jason A
• Ahn Channing
• Addison Dan
• Tan Hongjin
• Uddin Jasim

Classifications

• Y02E60/32

  Hydrogen storage · CPC title

• Y02T90/40

  Application of hydrogen technology to transportation, e.g. using fuel cells · CPC title

• Y02E60/50

  Fuel cells · CPC title

• C01B3/0073

  Slurries; Suspensions · CPC title

• C01B3/0031

  Intermetallic compounds; Metal alloys · CPC title