Conductive material dispersed liquid and lithium secondary battery manufactured using the same

Patent metadata

Field	Value
Publication number	US-11050061-B2
Application number	US-201615741676-A
Country	US
Kind code	B2
Filing date	Oct 28, 2016
Priority date	Oct 28, 2015
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

The present invention provides: a conductive material dispersed liquid containing a conductive material, a dispersant, and a dispersion medium, wherein the conductive material comprises bundle-type carbon nanotubes having a bulk density in a range of 10-50 kg/m3 and a conductivity satisfying the conditions of Equation 1 below, thereby exhibiting excellent dispersibility and conductivity; and a lithium secondary battery, which is manufactured using the conductive material dispersed liquid and thus can exhibit excellent battery functions, especially, excellent output characteristics at low temperatures:−X≤10 log R≤−0.6X  [Equation 1](in Equation 1 above, X is a bulk density of the carbon nanotubes, and R is a powder resistance of the carbon nanotubes under a pressure of 10 to 65 MPa.).

First claim

The invention claimed is:

1. A conductive material dispersed liquid, comprising a conductive material, a nitrile based rubber dispersant, and a dispersion medium, wherein the conductive material includes bundle-type carbon nanotubes having a bulk density in a range of 10 to 50 kg/m 3 and a conductivity satisfying the condition of the following Equation 1,
− X≤ 10 log R≤ −0.6 X   [Equation 1]

wherein in Equation 1 above, X is a bulk density of the carbon nanotubes, and R is a powder resistivity of the carbon nanotubes under a pressure of 10 to 65 MPa.

2. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes have a bulk density in a range of 20 to 35 kg/m 3 and a powder resistivity in a range of 0.001 to 0.01 Ω·cm under a pressure of 10 to 65 MPa.

3. The conductive material dispersed liquid according to claim 1 , wherein a ratio (TD/BD ratio) of a true density (TD) to a bulk density (BD) of the carbon nanotubes is in a range of 70 to 120.

4. The conductive material dispersed liquid according to claim 1 , wherein the true density of the carbon nanotubes is in a range of 1,800 to 2,200 kg/m 3 .

5. The conductive material dispersed liquid according to claim 1 , wherein a BET specific surface area of the carbon nanotubes is in a range of 180 to 300 m 2 /g.

6. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes include a carbon nanotube unit having an average diameter in a range of 10 to 20 nm.

7. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes have an average value in a range of 0.75 to 1.05 and a standard deviation value in a range of 1.3 to 2.0% of a ratio (ID/IG) of a maximum peak intensity (ID) of a D band at 1,360±50 cm −1 to a maximum peak intensity (IG) of a G band at 1,580±50 cm −1 obtained by Raman spectroscopy using a laser having a wavelength of 532 nm.

8. The conductive material dispersed liquid according to claim 1 , wherein the dispersant includes a hydrogenated nitrile butadiene-based rubber.

9. The conductive material dispersed liquid according to claim 1 , wherein the dispersant includes a hydrogenated nitrile butadiene-based rubber containing a structural unit derived from an α,β-unsaturated nitrile at 20 to 65 wt % based on the total weight.

10. The conductive material dispersed liquid according to claim 1 , wherein the dispersant includes a hydrogenated nitrile butadiene-based rubber containing a structural unit derived from a hydrogenated conjugated diene at 1 to 30 wt % based on the total weight.

11. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is included at 1 to 50 parts by weight based on 100 parts by weight of the carbon nanotubes.

12. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is introduced on a surface of the carbon nanotube to form a carbon nanotube-dispersant composite, and a particle size distribution according to the following Equation 3 of the carbon nanotube-dispersant composite is in a range of 2 to 6.5,
Particle size distribution of carbon nanotube−dispersant composite=( D 90 −D 10 )/D 50   [Equation 3]

wherein in Equation 3 above, D 10 , D 50 and D 90 each represent particle sizes on a basis of 10%, 50% and 90% in a particle size distribution of a carbon nanotube-dispersant composite.

13. A composition for forming an electrode of a lithium secondary battery, comprising:
an electrode active material; and
a conductive material dispersed liquid according to claim 1 .

14. A lithium secondary battery, comprising a positive electrode, a negative electrode, a separator and an electrolyte, wherein at least one of the positive electrode and the negative electrode is prepared using the composition for forming an electrode according to claim 13 .

15. A conductive material dispersed liquid, comprising a conductive material, a hydrogenated nitrile butadiene-based rubber dispersant, and a dispersion medium,
wherein the conductive material includes bundle-type carbon nanotubes having a bulk density in a range of 10 to 50 kg/m 3 and a conductivity satisfying the condition of the following Equation 1,
− X≤ 10 log R≤ −0.6 X [Equation 1]

wherein in Equation 1 above, X is a bulk density of the carbon nanotubes, and R is a powder resistivity of the carbon nanotubes under a pressure of 10 to 65 MPa.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Ye Lin
• Seol Jong Heon
• Kang Kyung Yeon
• Choy Sang Hoon
• Woo Ji Hee
• Cho Dong Hyun

Classifications

• H01M4/622

  being polymers · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• H01M4/625 Primary

  Carbon or graphite · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title