Lithiated and passivated lithium ion battery anodes

Patent metadata

Field	Value
Publication number	US-11050049-B2
Application number	US-201916274714-A
Country	US
Kind code	B2
Filing date	Feb 13, 2019
Priority date	Nov 20, 2014
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

An electrode material includes a lithium active material composition. The lithium active material composition includes lithium and an active anode material. The lithium active material composition is coated with a lithium ion conducting passivating material, such that the electrode material is lithiated and pre-passivated. An electrode and a battery are also disclosed. Methods of making an electrode material, electrode and battery that are lithiated and pre-passivated are also disclosed.

First claim

We claim:

1. A method of making an electrode material, comprising the steps of:
reacting Li with a particulate active anode material to form a particulate lithium active material composition, the lithium active material comprising at least one selected from the group consisting of LiC 6 , LiC 12 , LiC 18 , LiC 3 N 4 Li x Si where 0<x<4, LiTi 2 C 3 , and Li x Sn and Li x Sb;
coating the lithium active material composition with a lithium ion conducting passivating material to provide a lithiated and pre-passivated electrode material, the particulate lithium active material composition being completely coated with a lithium ion conducting passivating material having a transference number of from 0.7 to 1.0, the lithium ion conducting passivating material coating being from 1 to 100 nm thick.

2. The method of claim 1 , further comprising the step of applying an outer reflective coating over the passivating coating.

3. A method of making an electrode, comprising the steps of:
reacting Li with a particulate active anode material to form a particulate lithium active material composition, the lithium active material comprising at least one selected from the group consisting of LiC 6 , LiC 12 , LiC 18 , LiC 3 N 4 Li x Si where 0<x<4, LiTi 2 C 3 Li x Sn and Li x Sb;
coating the lithium active material composition with a lithium ion conducting passivating material to provide an electrode material, the particulate lithium active material composition being completely coated with a lithium ion conducting passivating material having a transference number of from 0.7 to 1.0, the lithium ion conducting passivating material coating being from 1 to 100 nm thick;
mixing the electrode material with a binder;
applying the binder and electrode material to a current collector; and,
curing the binder to adhere the electrode material together and to the current collector to form a lithiated and pre-passivated electrode.

4. The method of claim 3 , wherein the binder is cured by the application of UV light, and the lithium ion conducting passivating material is optically transparent.

5. The method of claim 3 , wherein a solvent for the binder is included in the mixing step, and further comprising the step of evaporating the solvent prior to the step of curing the binder.

6. The method of claim 5 , wherein the binder comprises at least one selected from the group consisting of polyvinylidene fluoride (PVDF), ethylene propylene diene terpolymer (EPDM), carboxymethylcellulose, chlorinated PVDF, and polytetrafluoroethylene.

7. The method of claim 5 , wherein the solvent is at least one selected from the group consisting of organic carbonate, ketone, ester, ether and furan.

8. The method of claim 5 , wherein the solvent is at least one selected from the group consisting of cyclohexane, N-methyl-2-pyrrolidone (NMP), ethylene carbonate, dimethyl carbonate, propylene carbonate, and tetrahydrofuran.

9. A method of making a battery, comprising the steps of:
reacting Li with a particulate active anode material to form a particulate lithium active material composition, the lithium active material comprising at least one selected from the group consisting of LiC 6 , LiC 12 , LiC 18 , LiC 3 N 4 Li x Si where 0<x<4, LiTi 2 C 3 Li x Sn and Li x Sb;
coating the lithium active material composition with a lithium ion conducting passivating material to provide an electrode material, the lithium ion conducting passivating material having a transference number of from 0.7 to 1.0, the particulate lithium active material composition being completely coated with the lithium ion conducting passivating material, the lithium ion conducting passivating material coating being from 1 to 100 nm thick;
mixing the electrode material with a binder;
applying the binder and electrode material to a current collector; and,
curing the binder to adhere the electrode material together and to the current collector to form a lithiated and pre-passivated anode electrode; and,
assembling the lithiated and pre-passivated anode with a cathode, a separator, and an electrolyte to form a lithiated and pre-passivated battery.

10. The method of claim 9 , further comprising the step of operating the battery without solid electrolyte interface (SEI) formation cycles.

11. A method of forming an anode, comprising the steps of:
reacting Li with a particulate active anode material to form a particulate lithium active material composition, the lithium active material comprising at least one selected from the group consisting of LiC 6 , LiC 12 , LiC 18 , LiC 3 N 4 Li x Si where 0<x<4, LiTi 2 C 3 Li x Sn and Li x Sb;
coating the particulate lithium active material composition with a lithium ion conducting passivating material having a transference number of from 0.7 to 1.0, the lithium ion conducting passivating material coating being from 1 to 100 nm thick, the particulate lithium active material composition being completely coated with the lithium ion conducting passivating material;
mixing the coated lithium active material composition with a binder; and,
curing the binder to form an anode electrode material.

Assignees

• Ut Battelle Llc

Inventors

• Sacci Robert L
• Dudney Nancy J
• Gill Lance W
• Hagaman Edward W
• Veith Gabriel M

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M4/0445

  Forming after manufacture of the electrode, e.g. first charge, cycling · CPC title

• H01M10/058

  Construction or manufacture · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/139

  Processes of manufacture · CPC title